Remediation and Transformation of Kaolin by Plasma Magmavication

Author(s):  
Josepha D. Celes ◽  
Paul W. Mayne

In situ plasma magmavication is a powerful and expedient technique for melting soil that subsequently cools to form a glassy igneous rock. A nontransferred arc plasma torch provides temperatures exceeding 4000°C that can be positioned within boreholes as a means of ground improvement or for environmental restoration of contaminated soils. The process is similar to in situ vitrification by embedded graphite electrodes, yet the nontransferred arc is a considerably more efficient process. The artificial rock can be left in place or, alternatively, may be exhumed and stored. The effectiveness of plasma remediation on uncontaminated and contaminated kaolin was investigated through a preliminary series of laboratory chamber tests with small dosages of chemical, biological, and nuclear surrogates. It is believed that the process pyrolizes organic contaminants, while locking the inorganic contaminants within the glass matrix. Measurements in compressive strength, stiffness, porosity, and mass density verified the transformation of soil to rock with improved material characteristics.

Author(s):  
Isabel HILBER ◽  
Ana Catarina BASTOS ◽  
Susana LOUREIRO ◽  
Gerhard SOJA ◽  
Aleksandra MARSZ ◽  
...  

This article reviews the different aspects of biochar as source and sink of organic and inorganic contaminants. Biochar can contain organic contaminants such as polycyclic aromatic hydrocarbons or heavy metals. As the distribution coefficients of the biochar especially for contaminants are high, the freely dissolved concentrations are low and with that also the bioavailability. The link between biochar’s inherent contaminants and toxicity to soil meso– and macro–fauna remains unclear, with data being often contradictory and influenced by feedstock and pyrolysis conditions. The biochar’s potential to remediate contaminated soils has mainly been addressed in lab studies, but rarely in the field. This far, results have been contradicting. Many studies reported successful immobilization of contaminants but some not. In summary, the ambivalent face of the biochar with regard to contaminants prevails. In future, long term field studies are needed to properly address the sustainability of biochar in this respect.


Author(s):  
Milan Hrabovsky ◽  
M. Konrad ◽  
Vladimir Kopecky ◽  
J. Hlina ◽  
J. Benes ◽  
...  

2017 ◽  
Vol 58 ◽  
pp. 6.1-6.36 ◽  
Author(s):  
I. Gultepe ◽  
A. J. Heymsfield ◽  
P. R. Field ◽  
D. Axisa

AbstractIce-phase precipitation occurs at Earth’s surface and may include various types of pristine crystals, rimed crystals, freezing droplets, secondary crystals, aggregates, graupel, hail, or combinations of any of these. Formation of ice-phase precipitation is directly related to environmental and cloud meteorological parameters that include available moisture, temperature, and three-dimensional wind speed and turbulence, as well as processes related to nucleation, cooling rate, and microphysics. Cloud microphysical parameters in the numerical models are resolved based on various processes such as nucleation, mixing, collision and coalescence, accretion, riming, secondary ice particle generation, turbulence, and cooling processes. These processes are usually parameterized based on assumed particle size distributions and ice crystal microphysical parameters such as mass, size, and number and mass density. Microphysical algorithms in the numerical models are developed based on their need for applications. Observations of ice-phase precipitation are performed using in situ and remote sensing platforms, including radars and satellite-based systems. Because of the low density of snow particles with small ice water content, their measurements and predictions at the surface can include large uncertainties. Wind and turbulence affecting collection efficiency of the sensors, calibration issues, and sensitivity of ground-based in situ observations of snow are important challenges to assessing the snow precipitation. This chapter’s goals are to provide an overview for accurately measuring and predicting ice-phase precipitation. The processes within and below cloud that affect falling snow, as well as the known sources of error that affect understanding and prediction of these processes, are discussed.


1990 ◽  
Vol 30 (3) ◽  
pp. 281-293
Author(s):  
David J. Wilson ◽  
Ann N. Clarke ◽  
Robert D. Mutch

2017 ◽  
Vol 24 (12) ◽  
pp. 11265-11278 ◽  
Author(s):  
Bérénice Ranc ◽  
Pierre Faure ◽  
Véronique Croze ◽  
Catherine Lorgeoux ◽  
Marie-Odile Simonnot

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