scholarly journals Effects of synthesis conditions on chemical structures and physical properties of copolyesters from lactic acid, ethylene glycol and dimethyl terephthalate

2009 ◽  
Vol 3 (7) ◽  
pp. 458-468 ◽  
Author(s):  
M. Opaprakasit ◽  
A. Petchsuk ◽  
P. Opaprakasit ◽  
S. Chongprakobkit
2013 ◽  
Vol 652-654 ◽  
pp. 459-462
Author(s):  
Ya Tong Guo ◽  
Zhu Zheng ◽  
Zhen Qi Hou ◽  
Jie Du

A series of biodegradable segmented liquid crystalline poly(ester-urethane)s were prepared by solution polymerization of poly(L-lactic acid) (PLLA), mesogenic diol prepolymer poly(butylene terephthaloyldioxy dibenzoates) (MD), and hexamethylene diisocyanate (HDI). The MD content was varied from 0 to 40 mol% so that the effects of the mesogen content on the thermal and physical properties, and hydrolytic degradation were examined respectively. It was found that introducing mesogens units could increase the thermal stability and the elastic properties, while reduced the phase transition temperatures and the hydrolytic degradation rate.


2015 ◽  
Vol 659 ◽  
pp. 570-574 ◽  
Author(s):  
Apinya Musidang ◽  
Nantana Jiratumnukul

UV-curable process is widely used for paints, inks and adhesives due to its rapid curing, low energy consumption, high efficiency and low volatile organic compounds (VOCs). The objective of this research is to prepare poly(lactic acid) (PLA) based UV-curable coating by using glycolyzed PLA. PLA was glycolyzed by ethylene glycol (EG) at 170°C for 90 minutes. The obtained glycolyzed PLA was reacted with methacrylic anhydride (MAAH) to provide PLA acrylate oligomer. The obtained PLA acrylate oligomer was used in coating formulations with various amounts of photoinitiator and cured under UV radiation. Physical properties of cured coating film were investigated such as pencil hardness, gloss and haze. The results showed that poly(lactic acid) (PLA) based UV-curable coating provided good physical properties.


2006 ◽  
Vol 39 (26) ◽  
pp. 9396-9401 ◽  
Author(s):  
Mark A. Even ◽  
Chunyan Chen ◽  
Jie Wang ◽  
Zhan Chen

2015 ◽  
Vol 133 (8) ◽  
pp. n/a-n/a ◽  
Author(s):  
Weraporn Pivsa-Art ◽  
Kazunori Fujii ◽  
Keiichiro Nomura ◽  
Yuji Aso ◽  
Hitomi Ohara ◽  
...  

Cellulose ◽  
2017 ◽  
Vol 24 (8) ◽  
pp. 3513-3523 ◽  
Author(s):  
Zhouyang Xiang ◽  
Qingguo Liu ◽  
Yong Chen ◽  
Fachuang Lu

2017 ◽  
Vol 50 (14) ◽  
pp. 5527-5538 ◽  
Author(s):  
Vincent E. G. Diederich ◽  
Thomas Villiger ◽  
Giuseppe Storti ◽  
Marco Lattuada

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