Propagation Analysis of Crevice Corrosion on SUS304 Stainless Steel Under Potentiostatic Condition in Artificial Sea Water

Umbilicals are important tubes assembly essentially used for subsea equipment controlling functions and fluid injection. Super duplex stainless steel 2507 (UNS 32750 / EN 1.4410) has been the historical grade used for its corrosion resistance and mechanical properties. The Oil and Gas industry is gradually working on the exploration and exploitation of offshore and deep offshore resources. These operating conditions lead to new philosophy in the design of subsea umbilicals, which are evolving to answer the needs of new functionalities. Recent years development supported by O&G operators, have seen innovative super duplex stainless seam welded tube solution being used for their high mechanical characteristics (YS0.2≥ 750 MPa; UTS≥ 900 MPa), tight dimension tolerances, and their ability to generate cost saving during installation. The specific metallurgical manufacturing route for the 2507 strip together with an efficient roll forming process and NDT control allows to obtained tubes for umbilicals which push the usual boundaries of utilization of this super duplex grades. In this paper, Hydrogen Induced Stress Cracking (HISC) behavior, possible failure mode of the super duplex stainless steel tubes exposed to cathodic protection in the termination unit, was extensively studied. A stress load of 110% YS0.2 was applied using a dead weight bench and the tubes performance was characterized after 500h of exposure in synthetic sea water under cathodic protection. Crevice corrosion is also a reported failure mode for umbilical tubes. Corrosion resistance of the 2507 seam welded tubes was also assessed in natural sea water in crevice conditions at open circuit potential (OCP). No failure was observed during the HISC testing in synthetic sea water after 500hours of exposure and no micro-crack was detected on the tubes after characterization. The metallurgical microstructure of the laser weld is not preferential initiation zone for crevice corrosion.

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Influence of Chloride Concentration on Stress Corrosion Cracking and Crevice Corrosion of Austenitic Stainless Steel in Saline Environments

Materials ◽

10.3390/ma13245640 ◽

2020 ◽

Vol 13 (24) ◽

pp. 5640

Author(s):

Chun-Ping Yeh ◽

Kun-Chao Tsai ◽

Jiunn-Yuan Huang

Keyword(s):

Stainless Steel ◽

Relative Humidity ◽

Crevice Corrosion ◽

Sea Water ◽

Safety Concern ◽

Chloride Concentration ◽

Test Duration ◽

304L Stainless Steel ◽

Spent Fuel ◽

Saline Environments

Stainless steels are used as canister materials for interim storage of spent fuel. Crevice corrosion has proved to be a safety concern of 304L stainless steel spent fuel canisters, when exposed to the saline environments of coastal sites. To study the effects of chloride concentration and test duration on the crevice corrosion behavior, and the effect of relative humidity on the initiation of discrete SCC cracks, a test program was conducted on the 304L steel specimens sprayed with synthetic sea water of 3.5 wt.%. The salt-deposited specimens, wrapped up with a crevice former to form a crevice configuration, were then exposed to an environment at 45 °C with a pre-set 45%, 55%, and 70% relative humidity (RH), for 400 h and 10,000 h, respectively. The surface features and crack morphology of the tested 304L stainless-steel specimens were examined by energy-dispersive spectrometry (EDS) and electron back scatter diffraction (EBSD). For the specimens deposited with a chloride concentration of 1 g/m2, no cracks were found in the corroded regions after 400-h exposure, whereas SCC cracks were observed with the specimens tested for 10,000 h at all three pre-set relative humidity. The specimens tested at the pre-set relative humidity 45% are characterized with discrete SCC cracks, but, on the other hand, those exposed to the environments of 55% and 70% relative humidity show SCC cracks of distinct features. From the results of 10,000-h tests, it is inferred that the chloride concentration threshold for SCC initiation of 304L stainless steel at 45 °C is between 0.1 g/m2 and 1 g/m2.

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