scholarly journals Dark Reduction Drives Evasion of Mercury From the Ocean

2021 ◽  
Vol 2 ◽  
Author(s):  
Carl H. Lamborg ◽  
Colleen M. Hansel ◽  
Katlin L. Bowman ◽  
Bettina M. Voelker ◽  
Ryan M. Marsico ◽  
...  
Keyword(s):  
Mixed Layer ◽  
Surface Waters ◽  
Redox Reactions ◽  
Hydrothermal Vents ◽  
Vertical Mixing ◽  
Reduction Rate ◽  
Elemental Mercury ◽  
Ocean Mixed Layer ◽  
Surface Ocean ◽  
Redox Agents

Much of the surface water of the ocean is supersaturated in elemental mercury (Hg0) with respect to the atmosphere, leading to sea-to-air transfer or evasion. This flux is large, and nearly balances inputs from the atmosphere, rivers and hydrothermal vents. While the photochemical production of Hg0 from ionic and methylated mercury is reasonably well-studied and can produce Hg0 at fairly high rates, there is also abundant Hg0 in aphotic waters, indicating that other important formation pathways exist. Here, we present results of gross reduction rate measurements, depth profiles and diel cycling studies to argue that dark reduction of Hg2+ is also capable of sustaining Hg0 concentrations in the open ocean mixed layer. In locations where vertical mixing is deep enough relative to the vertical penetration of UV-B and photosynthetically active radiation (the principal forms of light involved in abiotic and biotic Hg photoreduction), dark reduction will contribute the majority of Hg0 produced in the surface ocean mixed layer. Our measurements and modeling suggest that these conditions are met nearly everywhere except at high latitudes during local summer. Furthermore, the residence time of Hg0 in the mixed layer with respect to evasion is longer than that of redox, a situation that allows dark reduction-oxidation to effectively set the steady-state ratio of Hg0 to Hg2+ in surface waters. The nature of these dark redox reactions in the ocean was not resolved by this study, but our experiments suggest a likely mechanism or mechanisms involving enzymes and/or important redox agents such as reactive oxygen species and manganese (III).

scholarly journals Global surface-ocean <i>p</i><sup>CO<sub>2</sub></sup> and sea–air CO<sub>2</sub> flux variability from an observation-driven ocean mixed-layer scheme

Ocean Science ◽  
2013 ◽  
Vol 9 (2) ◽  
pp. 193-216 ◽  
Author(s):  
C. Rödenbeck ◽  
R. F. Keeling ◽  
D. C. E. Bakker ◽  
N. Metzl ◽  
A. Olsen ◽  
...  
Keyword(s):  
Partial Pressure ◽  
Mixed Layer ◽  
Co2 Flux ◽  
Companion Paper ◽  
Diagnostic Model ◽  
Ocean Mixed Layer ◽  
Co2 Partial Pressure ◽  
Surface Ocean ◽  
Flux Variability ◽  
Global Surface

Abstract. A temporally and spatially resolved estimate of the global surface-ocean CO2 partial pressure field and the sea–air CO2 flux is presented, obtained by fitting a simple data-driven diagnostic model of ocean mixed-layer biogeochemistry to surface-ocean CO2 partial pressure data from the SOCAT v1.5 database. Results include seasonal, interannual, and short-term (daily) variations. In most regions, estimated seasonality is well constrained from the data, and compares well to the widely used monthly climatology by Takahashi et al. (2009). Comparison to independent data tentatively supports the slightly higher seasonal variations in our estimates in some areas. We also fitted the diagnostic model to atmospheric CO2 data. The results of this are less robust, but in those areas where atmospheric signals are not strongly influenced by land flux variability, their seasonality is nevertheless consistent with the results based on surface-ocean data. From a comparison with an independent seasonal climatology of surface-ocean nutrient concentration, the diagnostic model is shown to capture relevant surface-ocean biogeochemical processes reasonably well. Estimated interannual variations will be presented and discussed in a companion paper.

scholarly journals Increasing vertical mixing to reduce Southern Ocean deep convection in NEMO3.4

2015 ◽  
Vol 8 (10) ◽  
pp. 3119-3130 ◽  
Author(s):  
C. Heuzé ◽  
J. K. Ridley ◽  
D. Calvert ◽  
D. P. Stevens ◽  
K. J. Heywood
Keyword(s):  
Southern Ocean ◽  
Mixed Layer ◽  
Surface Waters ◽  
Bottom Water ◽  
Climate Model ◽  
Deep Convection ◽  
Mixed Layer Depth ◽  
Vertical Mixing ◽  
Weddell Sea ◽  
Antarctic Bottom Water

Abstract. Most CMIP5 (Coupled Model Intercomparison Project Phase 5) models unrealistically form Antarctic Bottom Water by open ocean deep convection in the Weddell and Ross seas. To identify the mechanisms triggering Southern Ocean deep convection in models, we perform sensitivity experiments on the ocean model NEMO3.4 forced by prescribed atmospheric fluxes. We vary the vertical velocity scale of the Langmuir turbulence, the fraction of turbulent kinetic energy transferred below the mixed layer, and the background diffusivity and run short simulations from 1980. All experiments exhibit deep convection in the Riiser-Larsen Sea in 1987; the origin is a positive sea ice anomaly in 1985, causing a shallow anomaly in mixed layer depth, hence anomalously warm surface waters and subsequent polynya opening. Modifying the vertical mixing impacts both the climatological state and the associated surface anomalies. The experiments with enhanced mixing exhibit colder surface waters and reduced deep convection. The experiments with decreased mixing give warmer surface waters, open larger polynyas causing more saline surface waters and have deep convection across the Weddell Sea until the simulations end. Extended experiments reveal an increase in the Drake Passage transport of 4 Sv each year deep convection occurs, leading to an unrealistically large transport at the end of the simulation. North Atlantic deep convection is not significantly affected by the changes in mixing parameters. As new climate model overflow parameterisations are developed to form Antarctic Bottom Water more realistically, we argue that models would benefit from stopping Southern Ocean deep convection, for example by increasing their vertical mixing.

scholarly journals Increasing vertical mixing to reduce Southern Ocean deep convection in NEMO

2015 ◽  
Vol 8 (3) ◽  
pp. 2949-2972 ◽  
Author(s):  
C. Heuzé ◽  
J. K. Ridley ◽  
D. Calvert ◽  
D. P. Stevens ◽  
K. J. Heywood
Keyword(s):  
Southern Ocean ◽  
Mixed Layer ◽  
Surface Waters ◽  
Bottom Water ◽  
Deep Convection ◽  
Mixed Layer Depth ◽  
Vertical Mixing ◽  
Weddell Sea ◽  
Cmip5 Models ◽  
Antarctic Bottom Water

Abstract. Most CMIP5 models unrealistically form Antarctic Bottom Water by open ocean deep convection in the Weddell and Ross Seas. To identify the triggering mechanisms leading to Southern Ocean deep convection in models, we perform sensitivity experiments on the ocean model NEMO forced by prescribed atmospheric fluxes. We vary the vertical velocity scale of the Langmuir turbulence, the fraction of turbulent kinetic energy transferred below the mixed layer, and the background diffusivity and run short simulations from 1980. All experiments exhibit deep convection in the Riiser-Larsen Sea in 1987; the origin is a positive sea ice anomaly in 1985, causing a shallow anomaly in mixed layer depth, hence anomalously warm surface waters and subsequent polynya opening. Modifying the vertical mixing impacts both the climatological state and the associated surface anomalies. The experiments with enhanced mixing exhibit colder surface waters and reduced deep convection. The experiments with decreased mixing are warmer, open larger polynyas and have deep convection across the Weddell Sea until the simulations end. Extended experiments reveal an increase in the Drake Passage transport of 4 Sv each year deep convection occurs, leading to an unrealistically large transport at the end of the simulation. North Atlantic deep convection is not significantly affected by the changes in mixing parameters. As new climate model overflow parameterisations are developed to form Antarctic Bottom Water more realistically, we argue that models would benefit from stopping Southern Ocean deep convection, for example by increasing their vertical mixing.

Interannual variability of the Tropical Indian Ocean mixed layer depth

2012 ◽  
Vol 40 (3-4) ◽  
pp. 743-759 ◽  
Author(s):  
M. G. Keerthi ◽  
M. Lengaigne ◽  
J. Vialard ◽  
C. de Boyer Montégut ◽  
P. M. Muraleedharan
Keyword(s):  
Indian Ocean ◽  
Interannual Variability ◽  
Mixed Layer ◽  
Mixed Layer Depth ◽  
Tropical Indian Ocean ◽  
Ocean Mixed Layer ◽  
Layer Depth ◽  
Ocean Mixed Layer Depth

scholarly journals The Effect of Atmosphere–Ocean Coupling on the Structure and Intensity of Tropical Cyclone Bejisa in the Southwest Indian Ocean

Atmosphere ◽  
2021 ◽  
Vol 12 (6) ◽  
pp. 688
Author(s):  
Soline Bielli ◽  
Christelle Barthe ◽  
Olivier Bousquet ◽  
Pierre Tulet ◽  
Joris Pianezze
Keyword(s):  
Tropical Cyclone ◽  
Mixed Layer ◽  
Heat Fluxes ◽  
Sea Surface ◽  
Ocean Mixed Layer ◽  
Surface Cooling ◽  
Southwest Indian Ocean ◽  
Left Hand ◽  
Sea Surface Cooling ◽  
The Impact

A set of numerical simulations is relied upon to evaluate the impact of air-sea interactions on the behaviour of tropical cyclone (TC) Bejisa (2014), using various configurations of the coupled ocean-atmosphere numerical system Meso-NH-NEMO. Uncoupled (SST constant) as well as 1D (use of a 1D ocean mixed layer) and 3D (full 3D ocean) coupled experiments are conducted to evaluate the impact of the oceanic response and dynamic processes, with emphasis on the simulated structure and intensity of TC Bejisa. Although the three experiments are shown to properly capture the track of the tropical cyclone, the intensity and the spatial distribution of the sea surface cooling show strong differences from one coupled experiment to another. In the 1D experiment, sea surface cooling (∼1 ∘C) is reduced by a factor 2 with respect to observations and appears restricted to the depth of the ocean mixed layer. Cooling is maximized along the right-hand side of the TC track, in apparent disagreement with satellite-derived sea surface temperature observations. In the 3D experiment, surface cooling of up to 2.5 ∘C is simulated along the left hand side of the TC track, which shows more consistency with observations both in terms of intensity and spatial structure. In-depth cooling is also shown to extend to a much deeper depth, with a secondary maximum of nearly 1.5 ∘C simulated near 250 m. With respect to the uncoupled experiment, heat fluxes are reduced from about 20% in both 1D and 3D coupling configurations. The tropical cyclone intensity in terms of occurrence of 10-m TC wind is globally reduced in both cases by about 10%. 3D-coupling tends to asymmetrize winds aloft with little impact on intensity but rather a modification of the secondary circulation, resulting in a slight change in structure.

scholarly journals On the Nature of Near-Inertial Oscillations in the Uppermost Part of the Ocean and a Possible Route toward HF Radar Probing of Stratification

2015 ◽  
Vol 45 (10) ◽  
pp. 2660-2678 ◽  
Author(s):  
Victor I. Shrira ◽  
Philippe Forget
Keyword(s):  
Mixed Layer ◽  
Vertical Mixing ◽  
Hf Radar ◽  
Momentum Exchange ◽  
Inertial Oscillations ◽  
Weak Density ◽  
Gulf Of Lion ◽  
Vertical Heat ◽  
Northwestern Mediterranean ◽  
Vertical Localization

AbstractInertial band response of the upper ocean to changing wind is studied both theoretically and by analysis of observations in the northwestern Mediterranean. On the nontraditional f plane, because of the horizontal component of the earth’s rotation for waves of inertial band with frequencies slightly below the local inertial frequency f, there is a waveguide in the mixed layer confined from below by the pycnocline. It is argued that when the stratification is shallow these waves are most easily and strongly excited by varying winds as near-inertial oscillations (NIOs). These motions have been overlooked in previous studies because they are absent under the traditional approximation. The observations that employed buoys with thermistors, ADCPs, and two 16.3-MHz Wellen Radar (WERA) HF radars were carried out in the Gulf of Lion in April–June 2006. The observations support the theoretical picture: a pronounced inertial band response occurs only in the presence of shallow stratification and is confined to the mixed layer, and the NIO penetration below the stratified layer is weak. NIO surface magnitude and vertical localization are strongly affected by the presence of even weak density stratification in the upper 10 m. The NIO surface signatures are easily captured by HF radars. Continuous 1.8-yr HF observations near the Porquerolles Island confirm that shallow stratification is indeed the precondition for a strong NIO response. The response sensitivity to stratification provides a foundation for developing HF radar probing of stratification and, indirectly, vertical mixing, including spotting dramatic mixing events and spikes of vertical heat, mass, and momentum exchange.

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