scholarly journals Photocatalytic Alkylation of α-(Trifluoromethyl)Styrenes with Potassium Xanthogenates

Catalysts ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1555
Author(s):  
Vyacheslav I. Supranovich ◽  
Alexander D. Dilman
Keyword(s):  
Blue Light ◽  
Oxidative Desulfurization ◽  
Triethyl Phosphite ◽  
Light Irradiation ◽  
Alkyl Radicals ◽  
Reaction Proceeds ◽  
Oxygen Bond

A protocol for the coupling of potassium xanthogenates with α-(trifluoromethyl)styrenes in the presence of triethyl phosphite is reported. The reaction is carried out under blue light irradiation in the presence of organic photocatalyst 3DPAFIPN. The reaction proceeds via formation of alkyl radicals from readily available xanthogenate salts via oxidative desulfurization and cleavage of the carbon–oxygen bond assisted by triethyl phosphite.

scholarly journals Synthesis of aryl sulfides via radical–radical cross coupling of electron-rich arenes using visible light photoredox catalysis

2018 ◽  
Vol 14 ◽  
pp. 2520-2528 ◽  
Author(s):  
Amrita Das ◽  
Mitasree Maity ◽  
Simon Malcherek ◽  
Burkhard König ◽  
Julia Rehbein
Keyword(s):  
Visible Light ◽  
Experimental Evidence ◽  
Blue Light ◽  
Room Temperature ◽  
Cross Coupling ◽  
Light Irradiation ◽  
Coupling Mechanism ◽  
Photoredox Catalysis ◽  
Reaction Proceeds ◽  
Aryl Sulfides

Electron-rich arenes react with aryl and alkyl disulfides in the presence of catalytic amounts of [Ir(dF(CF3)ppy)2(dtbpy)]PF6 and (NH4)2S2O8 under blue light irradiation to yield arylthiols. The reaction proceeds at room temperature and avoids the use of prefunctionalized arenes. Experimental evidence suggests a radical–radical cross coupling mechanism.

scholarly journals Correction to “Photocatalyst-Free Singlet Oxygen-Induced Oxygenation: A Strategy for the Preparation of 5-Cyano-2-pyridones Driven by Blue-Light Irradiation”

2020 ◽  
Vol 85 (14) ◽  
pp. 9446-9446
Author(s):  
Mengmeng Zhang ◽  
Hanyang Lan ◽  
Nan Li ◽  
Qidi Zhong ◽  
Hao Zhu ◽  
...  
Keyword(s):  
Singlet Oxygen ◽  
Blue Light ◽  
Light Irradiation

Evaluation of Photobiogoverning Role of Blue Light Irradiation on Viral Replication

2021 ◽  
Author(s):  
Phil‐Sun Oh ◽  
Kyung Won Kang ◽  
Seung Rok Ryu ◽  
SeokTae Lim ◽  
Myung‐Hee Sohn ◽  
...  
Keyword(s):  
Viral Replication ◽  
Blue Light ◽  
Light Irradiation

Dehydrogenative 6π Heterocyclization under Visible Light Irradiation and Mechanistic Insights

2021 ◽  
Author(s):  
Zhao Zhang ◽  
Haohua Chen ◽  
Niklas Keller ◽  
Qin Xiong ◽  
Lei Liu ◽  
...  
Keyword(s):  
Transition Metals ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Light Irradiation ◽  
Reaction Proceeds ◽  
Visible Light Driven

A visible-light-driven oxidative 6π heterocycilization for the synthesis of structurally diverse π-conjugated polycyclic 1-aminoisoquinolines has been developed. The reaction proceeds under visible-light or sunshine, obviates photocatalyst and transition-metals, and features...

scholarly journals Effects of blue-light irradiation during dental treatment

2018 ◽  
Vol 54 (4) ◽  
pp. 160-168 ◽  
Author(s):  
Fumihiko Yoshino ◽  
Ayaka Yoshida
Keyword(s):  
Blue Light ◽  
Dental Treatment ◽  
Light Irradiation

scholarly journals Optoregulated Drug Release from an Engineered Living Hydrogel

2018 ◽  
Author(s):  
Shrikrishnan Sankaran ◽  
Judith Becker ◽  
Christoph Wittmann ◽  
Aránzazu del Campo
Keyword(s):  
Drug Release ◽  
Blue Light ◽  
Light Irradiation ◽  
E Coli ◽  
Hydrogel Matrix ◽  
Prolonged Drug Release

A living hydrogel has been developed with metabolically and optogenetically engineered E. coli encapsulated within an agarose-based hydrogel matrix to produce and release deoxyviolacein in response to blue light irradiation. Localized, tunable and prolonged drug release have been demonstrated.<br>

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