scholarly journals Preparation of Fluorine-Free Superhydrophobic Paper with Dual-Response of Temperature and pH

Coatings ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 1167
Author(s):  
Bin Du ◽  
Daodao Xue ◽  
Rubai Luo ◽  
Huailin Li ◽  
Kenan Yang ◽  
...  

Although various superhydrophobic materials have been manufactured and effectively used for oil–water separation, it is still highly desirable to explore materials which are eco-friendly, low-cost, and multifunctional. In this paper, a stable copolymer solution was prepared from the fluorine-free superhydrophobic copolymer with dual-responsiveness of temperature and pH. The functional superhydrophobic paper was prepared by immersing paper in copolymer solution by the dip-coating method. The surface element and structure analysis of the prepared superhydrophobic paper shows that the dual-responsive copolymer adheres successfully to the surface of the paper without destroying the fiber structure of the paper. At pH ≥ 7 and T > 25 °C, the paper has a good superhydrophobic performance, while under the conditions of pH < 7 and T < 25 °C, the paper comes into a hydrophilic state. Therefore, the dual-responsive superhydrophobic paper is more likely to adapt to the complicated oil-water separation environment than the single-response.

2019 ◽  
Vol 2019 ◽  
pp. 1-8 ◽  
Author(s):  
Peng Hong ◽  
Zhu Liu ◽  
Yang Gao ◽  
Yubin Chen ◽  
Mingxun Zhuang ◽  
...  

Superhydrophobic sponge as potential absorbing material for oil/water separation is attracting great attention recently. However, there are still some challenges to feasibly fabricate superhydrophobic sponge with large scale and low cost. Herein, a novel photochromic superhydrophobic melamine sponge (PDMS-SP sponge) is fabricated by facilely dip-coating and thermocuring of hydroxyl-terminated polydimethylsiloxanes mixed with photochromic spiropyran. FT-IR, EDS, and XPS results confirm the successful coating of PDMS-SP upon melamine sponge. The resultant sponge not only possesses excellent water repellency with a contact angle of 154.5° and oil-water separation efficiency with an oil absorption capacity of 48–116 folds of itself weight, but also shows photochromic phenomenon between colorless and purple when it is successively exposed to UV irradiation and visible light.


RSC Advances ◽  
2020 ◽  
Vol 10 (14) ◽  
pp. 8008-8015 ◽  
Author(s):  
Xuewei Ruan ◽  
Tiancheng Xu ◽  
Dingjiang Chen ◽  
Ziwen Ruan ◽  
Haitu Hu

Although various filtration materials with (super)wetting properties have been fabricated for effective oil/water separation, eco-friendly and low-cost materials are still highly desired.


Soft Matter ◽  
2021 ◽  
Author(s):  
Caimei Zhao ◽  
Lei Chen ◽  
Chuanming Yu ◽  
Binghua Hu ◽  
Haoxuan Huang ◽  
...  

Super-hydrophobic porous absorbent is a convenient, low-cost, efficient and environment-friendly material in the treatment of oil spills. In this work, a simple Pickering emulsion template method was employed to fabricate...


RSC Advances ◽  
2015 ◽  
Vol 5 (113) ◽  
pp. 92947-92953 ◽  
Author(s):  
Liangwei Zhou ◽  
Ping Yu ◽  
Yunhua He ◽  
Huanhuan Xia ◽  
Xinliang Guo ◽  
...  

Oil–water separation apparatus, in which the membrane was put at the bottom of the ultrafiltration cup. When the transformer oil was passed through the membrane, the water was retained above the membrane.


Coatings ◽  
2019 ◽  
Vol 9 (10) ◽  
pp. 659 ◽  
Author(s):  
Sheng Lei ◽  
Xinzuo Fang ◽  
Fajun Wang ◽  
Mingshan Xue ◽  
Junfei Ou ◽  
...  

The mixture of insoluble organics and water seriously affects human health and environmental safety. Therefore, it is important to develop an efficient material to remove oil from water. In this work, we report a superhydrophobic Cu2O mesh that can effectively separate oil and water. The superhydrophobic Cu2O surface was fabricated by a facile chemical reaction between copper mesh and hydrogen peroxide solution without any low surface reagents treatment. With the advantages of simple operation, short reaction time, and low cost, the as-synthesized superhydrophobic Cu2O mesh has excellent oil–water selectivity for many insoluble organic solvents. In addition, it could be reused for oil–water separation with a high separation ability of above 95%, which demonstrated excellent durability and reusability. We expect that this fabrication technique will have great application prospects in the application of oil–water separation.


2020 ◽  
Vol 8 ◽  
Author(s):  
Usama Zulfiqar ◽  
Andrew G. Thomas ◽  
Allan Matthews ◽  
David J. Lewis

Oil/water mixtures are a potentially major source of environmental pollution if efficient separation technology is not employed during processing. A large volume of oil/water mixtures is produced via many manufacturing operations in food, petrochemical, mining, and metal industries and can be exposed to water sources on a regular basis. To date, several techniques are used in practice to deal with industrial oil/water mixtures and oil spills such as in situ burning of oil, bioremediation, and solidifiers, which change the physical shape of oil as a result of chemical interaction. Physical separation of oil/water mixtures is in industrial practice; however, the existing technologies to do so often require either dissipation of large amounts of energy (such as in cyclones and hydrocyclones) or large residence times or inventories of fluids (such as in decanters). Recently, materials with selective wettability have gained attention for application in separation of oil/water mixtures and surfactant stabilized emulsions. For example, a superhydrophobic material is selectively wettable toward oil while having a poor affinity for the aqueous phase; therefore, a superhydrophobic porous material can easily adsorb the oil while completely rejecting the water from an oil/water mixture, thus physically separating the two components. The ease of separation, low cost, and low-energy requirements are some of the other advantages offered by these materials over existing practices of oil/water separation. The present review aims to focus on the surface engineering aspects to achieve selectively wettability in materials and its their relationship with the separation of oil/water mixtures with particular focus on emulsions, on factors contributing to their stability, and on how wettability can be helpful in their separation. Finally, the challenges in application of superwettable materials will be highlighted, and potential solutions to improve the application of these materials will be put forward.


Polymer ◽  
2020 ◽  
Vol 204 ◽  
pp. 122833
Author(s):  
Huan Yuan ◽  
Yamin Pan ◽  
Xiaolong Wang ◽  
Qiang Chen ◽  
Qian Hu ◽  
...  

2017 ◽  
Vol 224 ◽  
pp. 117-124 ◽  
Author(s):  
Chuqi Zhang ◽  
Yanmei Li ◽  
Ningning Bai ◽  
Cui Tan ◽  
Peng Cai ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (48) ◽  
pp. 38470-38478 ◽  
Author(s):  
Sudong Yang ◽  
Lin Chen ◽  
Lei Mu ◽  
Bin Hao ◽  
Peng-Cheng Ma

Ultralight, re-resistant and flexible carbon fiber aerogel is prepared by using disposable bamboo chopsticks as precursor. The aerogel can be used for oil–water separation and recycled for many times by distillation, combustion or squeeze.


2017 ◽  
Vol 5 (45) ◽  
pp. 23785-23793 ◽  
Author(s):  
A. Turco ◽  
E. Primiceri ◽  
M. Frigione ◽  
G. Maruccio ◽  
C. Malitesta

A faster, low-cost and facile soft-template approach to fabricate porous polydimethylsiloxane sponges is proposed. The sponges exhibited selective oil uptake capacity, excellent mechanical properties, and high reusability, all features that make them useful systems for plugging oil leakage.


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