scholarly journals Constrained Parameter Estimation for a Mechanistic Kinetic Model of Cobalt–Hydrogen Electrochemical Competition during a Cobalt Removal Process

Entropy ◽  
2021 ◽  
Vol 23 (4) ◽  
pp. 387
Author(s):  
Yiting Liang ◽  
Yuanhua Zhang ◽  
Yonggang Li
Keyword(s):  
Parameter Estimation ◽  
Kinetic Model ◽  
Model Parameters ◽  
Hydrogen Ions ◽  
Removal Process ◽  
Cobalt Removal ◽  
Estimation Scheme ◽  
Zinc Hydrometallurgy ◽  
The Impact ◽  
Parameter Estimation Scheme

A mechanistic kinetic model of cobalt–hydrogen electrochemical competition for the cobalt removal process in zinc hydrometallurgical was proposed. In addition, to overcome the parameter estimation difficulties arising from the model nonlinearities and the lack of information on the possible value ranges of parameters to be estimated, a constrained guided parameter estimation scheme was derived based on model equations and experimental data. The proposed model and the parameter estimation scheme have two advantages: (i) The model reflected for the first time the mechanism of the electrochemical competition between cobalt and hydrogen ions in the process of cobalt removal in zinc hydrometallurgy; (ii) The proposed constrained parameter estimation scheme did not depend on the information of the possible value ranges of parameters to be estimated; (iii) the constraint conditions provided in that scheme directly linked the experimental phenomenon metrics to the model parameters thereby providing deeper insights into the model parameters for model users. Numerical experiments showed that the proposed constrained parameter estimation algorithm significantly improved the estimation efficiency. Meanwhile, the proposed cobalt–hydrogen electrochemical competition model allowed for accurate simulation of the impact of hydrogen ions on cobalt removal rate as well as simulation of the trend of hydrogen ion concentration, which would be helpful for the actual cobalt removal process in zinc hydrometallurgy.

Combined state-parameter estimation with the LETKF for convective-scale weather forecasting

2020 ◽  
Author(s):  
Yvonne Ruckstuhl ◽  
Tijana Janjic
Keyword(s):  
Parameter Estimation ◽  
Gaussian Noise ◽  
Roughness Length ◽  
Surface Wind ◽  
Model Error ◽  
Surface Fluxes ◽  
Model Parameters ◽  
State Variables ◽  
Augmented State ◽  
The Impact

<p>We investigate the feasibility of addressing model error by perturbing and  estimating uncertain static model parameters using the localized ensemble transform Kalman filter. In particular we use the augmented state approach, where parameters are updated by observations via their correlation with observed state variables. This online approach offers a flexible, yet consistent way to better fit model variables affected by the chosen parameters to observations, while ensuring feasible model states. We show in a nearly-operational convection-permitting configuration that the prediction of clouds and precipitation with the COSMO-DE model is improved if the two dimensional roughness length parameter is estimated with the augmented state approach. Here, the targeted model error is the roughness length itself and the surface fluxes, which influence the initiation of convection. At analysis time, Gaussian noise with a specified correlation matrix is added to the roughness length to regulate the parameter spread. In the northern part of the COSMO-DE domain, where the terrain is mostly flat and assimilated surface wind measurements are dense, estimating the roughness length led to improved forecasts of up to six hours of clouds and precipitation. In the southern part of the domain, the parameter estimation was detrimental unless the correlation length scale of the Gaussian noise that is added to the roughness length is increased. The impact of the parameter estimation was found to be larger when synoptic forcing is weak and the model output is more sensitive to the roughness length.</p>

Modeling and Control of Multiple Web Spans Using State Estimation

1989 ◽  
Vol 111 (3) ◽  
pp. 505-510 ◽  
Author(s):  
G. E. Young ◽  
J. J. Shelton ◽  
C. Kardamilas
Keyword(s):  
Parameter Estimation ◽  
State Estimation ◽  
Modeling And Control ◽  
Physical Constraints ◽  
Estimation Scheme ◽  
And Control ◽  
Lateral Positioning ◽  
High Processing ◽  
Parameter Estimation Scheme ◽  
The Web

Web processing systems rely on accurate lateral positioning to achieve high processing speeds and improved product quality. Due to physical constraints in some processing lines placement of the edge sensor near the web guide is not possible. As a result, large lateral oscillation and/or web instability have been observed. A new model is developed for lateral web dynamics. Experimental verification has justified the structure of the model. A parameter estimation scheme is used to tune the model for imperfections not originally incorporated. State estimation is then used to predict lateral web position on a downstream sensor. Desirable control is achieved and is further improved with the use of the feedforward sensor. Predicted and experimental results are compared.

scholarly journals Impact of Geographic-Dependent Parameter Optimization on Climate Estimation and Prediction: Simulation with an Intermediate Coupled Model

2012 ◽  
Vol 140 (12) ◽  
pp. 3956-3971 ◽  
Author(s):  
Xinrong Wu ◽  
Shaoqing Zhang ◽  
Zhengyu Liu ◽  
Anthony Rosati ◽  
Thomas L. Delworth ◽  
...  
Keyword(s):  
Parameter Estimation ◽  
Surface Temperature ◽  
Parameter Optimization ◽  
General Circulation ◽  
Coupled Model ◽  
Model Parameters ◽  
Estimation And Prediction ◽  
Dependent Parameter ◽  
The Impact ◽  
Mean Square Errors

Abstract Because of the geographic dependence of model sensitivities and observing systems, allowing optimized parameter values to vary geographically may significantly enhance the signal in parameter estimation. Using an intermediate atmosphere–ocean–land coupled model, the impact of geographic dependence of model sensitivities on parameter optimization is explored within a twin-experiment framework. The coupled model consists of a 1-layer global barotropic atmosphere model, a 1.5-layer baroclinic ocean including a slab mixed layer with simulated upwelling by a streamfunction equation, and a simple land model. The assimilation model is biased by erroneously setting the values of all model parameters. The four most sensitive parameters identified by sensitivity studies are used to perform traditional single-value parameter estimation and new geographic-dependent parameter optimization. Results show that the new parameter optimization significantly improves the quality of state estimates compared to the traditional scheme, with reductions of root-mean-square errors as 41%, 23%, 62%, and 59% for the atmospheric streamfunction, the oceanic streamfunction, sea surface temperature, and land surface temperature, respectively. Consistently, the new parameter optimization greatly improves the model predictability as a result of the improvement of initial conditions and the enhancement of observational signals in optimized parameters. These results suggest that the proposed geographic-dependent parameter optimization scheme may provide a new perspective when a coupled general circulation model is used for climate estimation and prediction.

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