scholarly journals Interfacial Stabilization of a Graphene-Wrapped Cu2S Anode for High-Performance Sodium-Ion Batteries via Atomic Layer Deposition

2020 ◽  
Vol 4 (4) ◽  
pp. 184
Author(s):  
Jiyu Cai ◽  
Zonghai Chen ◽  
Xiangbo Meng

Sodium-ion batteries (SIBs) have attracted increasing attention for storing renewable clean energy, owing to their cost-effectiveness. Nonetheless, SIBs still remain significant challenges in terms of the availability of suitable anode materials with high capacities and good rate capabilities. Our previous work has developed and verified that Cu2S wrapped by nitrogen-doped graphene (i.e., Cu2S@NG composite), as an anode in SIBs, could exhibit a superior performance with ultralong cyclability and excellent rate capability, mainly due to the multifunctional roles of NG. However, the Cu2S@NG anode still suffers from continuous parasitic reactions at low potentials, causing a rapid performance deterioration. In this study, we investigated the effects of a conformal Al2O3 coating via atomic layer deposition (ALD) on the interfacial stability of the Cu2S@NG anode. As a consequence, the ALD-coated Cu2S@NG electrode can deliver a high capacity of 374 mAh g−1 at a current density of 100 mA g−1 and achieve a capacity retention of ~100% at different rates. This work verified that surface modification via ALD is a viable route for improving SIBs’ performances.

2015 ◽  
Vol 3 (48) ◽  
pp. 24281-24288 ◽  
Author(s):  
Jian Liu ◽  
Mohammad N. Banis ◽  
Biwei Xiao ◽  
Qian Sun ◽  
Andrew Lushington ◽  
...  

An atomic layer deposition technique was applied to fabricate sodium titanates as high performance anode materials for sodium-ion batteries.


2017 ◽  
Vol 5 (21) ◽  
pp. 10127-10149 ◽  
Author(s):  
Xiangbo Meng

This review summarized the research efforts using atomic layer deposition for high-performance sodium-ion batteries.


2018 ◽  
Vol 6 (5) ◽  
pp. 2302-2310 ◽  
Author(s):  
M. B. Sreedhara ◽  
Subhra Gope ◽  
Badri Vishal ◽  
Ranjan Datta ◽  
Aninda J. Bhattacharyya ◽  
...  

Nanowall network of MoS2 grown by atomic layer deposition shows single crystalline nature and epitaxial relationship with c-sapphire. The nanowall network grown directly on current collector exhibits high capacity, remarkable stability, cyclability and high rate capability over a wide range of operating currents.


ChemSusChem ◽  
2015 ◽  
Vol 8 (15) ◽  
pp. 2537-2543 ◽  
Author(s):  
Karthikeyan Kaliyappan ◽  
Jian Liu ◽  
Andrew Lushington ◽  
Ruying Li ◽  
Xueliang Sun

2019 ◽  
Vol 30 (9) ◽  
pp. 1906890 ◽  
Author(s):  
Fan Yu ◽  
Lei Du ◽  
Gaixia Zhang ◽  
Fengmei Su ◽  
Weichao Wang ◽  
...  

2016 ◽  
Vol 3 (21) ◽  
pp. 1600468 ◽  
Author(s):  
Jian Liu ◽  
Biqiong Wang ◽  
Qian Sun ◽  
Ruying Li ◽  
Tsun-Kong Sham ◽  
...  

Nano Energy ◽  
2019 ◽  
Vol 64 ◽  
pp. 103903 ◽  
Author(s):  
Haiyan Lu ◽  
Xiaoyang Chen ◽  
Yanlong Jia ◽  
Hui Chen ◽  
Yunxiao Wang ◽  
...  

2021 ◽  
Author(s):  
Francielli Genier ◽  
Shreyas Pathreeker ◽  
Robson Schuarca ◽  
Mohammad Islam ◽  
Ian Hosein

Deriving battery grade materials from natural sources is a key element to establishing sustainable energy storage technologies. In this work, we present the use of avocado peels as a sustainable source for conversion into hard carbon based anodes for sodium ion batteries. The avocado peels are simply washed and dried then proceeded to a high temperature conversion step. Materials characterization reveals conversion of the avocado peels in high purity, highly porous hard carbon powders. When prepared as anode materials they show to the capability to reversibly store and release sodium ions. The hard carbon-based electrodes exhibit excellent cycling performance, namely, a reversible capacity of 352.55 mAh/g at 0.05 A/g, rate capability up to 86 mAh/g at 3500 mA/g, capacity retention of >90%, and 99.9% coulombic efficiencies after 500 cycles. This study demonstrates avocado derived hard carbon as a sustainable source that can provide excellent electrochemical and battery performance as anodes in sodium ion batteries.


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