scholarly journals Optimization of Pickling Solution for Improving the Phosphatability of Advanced High-Strength Steels

Materials ◽  
2021 ◽  
Vol 14 (1) ◽  
pp. 233
Author(s):  
Sangwon Cho ◽  
Sang-Jin Ko ◽  
Jin-Seok Yoo ◽  
Joong-Chul Park ◽  
Yun-Ha Yoo ◽  
...  

This study investigated the optimum pickling conditions for improving the phosphatability of advanced high-strength steel (AHSS) using surface analysis and electrochemical measurements. To remove the SiO2 that forms on the surface of AHSS, 30 wt.% NH4HF2 was added to the pickling solution, resulting in a significant reduction in the amount of SiO2 remaining on the surface of the AHSS. The phosphatability was improved remarkably using HNO3 concentrations higher than 13% in the pickling solution. Furthermore, phosphate crystals became finer after pickling with a HNO3-based solution rather than a HCl-based solution. Electrochemical impedance spectroscopy (EIS) data indicated that the corrosion resistance of AHSS subjected to HNO3-based pickling was higher than that of AHSS subjected to HCl-based pickling. Fluorine compounds, which were involved in the phosphate treatment process, were only formed on the surface of steel in HNO3-based solutions. The F compounds reacted with the phosphate solution to increase the pH of the bulk solution, which greatly improved the phosphatability. The phosphatability was better under HNO3-based conditions than a HCl-based condition due to the fineness of the phosphate structure and the increased surface roughness.

2021 ◽  
Vol 182 ◽  
pp. 106687
Author(s):  
Yu Xia ◽  
Chu Ding ◽  
Zhanjie Li ◽  
Benjamin W. Schafer ◽  
Hannah B. Blum

Metals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1136
Author(s):  
Marcel Carpio ◽  
Jessica Calvo ◽  
Omar García ◽  
Juan Pablo Pedraza ◽  
José María Cabrera

Designing a new family of advanced high-strength steels (AHSSs) to develop automotive parts that cover early industry needs is the aim of many investigations. One of the candidates in the 3rd family of AHSS are the quenching and partitioning (QP) steels. These steels display an excellent relationship between strength and formability, making them able to fulfill the requirements of safety, while reducing automobile weight to enhance the performance during service. The main attribute of QP steels is the TRIP effect that retained austenite possesses, which allows a significant energy absorption during deformation. The present study is focused on evaluating some process parameters, especially the partitioning temperature, in the microstructures and mechanical properties attained during a QP process. An experimental steel (0.2C-3.5Mn-1.5Si (wt%)) was selected and heated according to the theoretical optimum quenching temperature. For this purpose, heat treatments in a quenching dilatometry and further microstructural and mechanical characterization were carried out by SEM, XRD, EBSD, and hardness and tensile tests, respectively. The samples showed a significant increment in the retained austenite at an increasing partitioning temperature, but with strong penalization on the final ductility due to the large amount of fresh martensite obtained as well.


2004 ◽  
Vol 101 (7-8) ◽  
pp. 551-558 ◽  
Author(s):  
R. Bode ◽  
M. Meurer ◽  
T. W. Schaumann ◽  
W. Warnecke

Author(s):  
Mohammad Mehdi Kasaei ◽  
Marta C Oliveira

This work presents a new understanding on the deformation mechanics involved in the Nakajima test, which is commonly used to determine the forming limit curve of sheet metals, and is focused on the interaction between the friction conditions and the deformation behaviour of a dual phase steel. The methodology is based on the finite element analysis of the Nakajima test, considering different values of the classic Coulomb friction coefficient, including a pressure-dependent model. The validity of the finite element model is examined through a comparison with experimental data. The results show that friction affects the location and strain path of the necking point by changing the strain rate distribution in the specimen. The strain localization alters the contact status from slip to stick at a portion of the contact area from the pole to the necking zone. This leads to the sharp increase of the strain rate at the necking point, as the punch rises further. The influence of the pressure-dependent friction coefficient on the deformation behaviour is very small, due to the uniform distribution of the contact pressure in the Nakajima test. Moreover, the low contact pressure range attained cannot properly replicate real contact condition in sheet metal forming processes of advanced high strength steels.


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