scholarly journals Exergetic Performance Coefficient Analysis and Optimization of a High-Temperature Proton Exchange Membrane Fuel Cell

Membranes ◽  
2022 ◽  
Vol 12 (1) ◽  
pp. 70
Author(s):  
Dongxu Li ◽  
Yanju Li ◽  
Zheshu Ma ◽  
Meng Zheng ◽  
Zhanghao Lu

Performance of a high-temperature proton exchange membrane fuel cell (HT-PEMFC) and the influence of different parameters on HT-PEMFC is analyzed in this study. Firstly, mathematical expression for energy efficiency, power density, exergy destruction and exergetic performance coefficient (EPC) are derived. Then, the relationship between the dimensionless power density, exergy destruction rate, exergetic performance coefficient (EPC) and energy efficiency is compared. Furthermore, the effect of flow rate, doping level, inlet pressure and film thickness are considered to evaluate the performance of HT-PEMFC. Results show that EPC not only considers exergetic loss rate to minimize exergetic loss, but also considers the power density of HT-PEMFC to maximize its power density and improve its efficiency, so EPC represents a better performance criterion. In addition, increasing inlet pressure and doping level can improve EPC and energy efficiency, respectively.

Mathematics ◽  
2021 ◽  
Vol 9 (12) ◽  
pp. 1332
Author(s):  
Dongxu Li ◽  
Siwei Li ◽  
Zheshu Ma ◽  
Bing Xu ◽  
Zhanghao Lu ◽  
...  

According to finite-time thermodynamics, an irreversible high temperature proton exchange membrane fuel cell (HT-PEMFC) model is established, and the mathematical expressions of the output power, energy efficiency, exergy efficiency and ecological coefficient of performance (ECOP) of HT-PEMFC are deduced. The ECOP is a step forward in optimizing the relationship between power and power dissipation, which is more in line with the principle of ecology. Based on the established HT-PEMFC model, the maximum power density is obtained under different parameters that include operating temperature, operating pressure, phosphoric acid doping level and relative humidity. At the same time, the energy efficiency, exergy efficiency and ECOP corresponding to the maximum power density are acquired so as to determine the optimal value of each index under the maximum power density. The results show that the higher the operating temperature and the doping level, the better the performance of HT-PEMFC is. However, the increase of operating pressure and relative humidity has little effect on HT-PEMFC performance.


Membranes ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 691
Author(s):  
Yanju Li ◽  
Zheshu Ma ◽  
Meng Zheng ◽  
Dongxu Li ◽  
Zhanghao Lu ◽  
...  

In this paper, a high-temperature proton exchange membrane fuel cell (HT-PEMFC) model using the polybenzimidazole membrane doped with phosphoric acid molecules is developed based on finite time thermodynamics, considering various polarization losses and losses caused by leakage current. The mathematical expressions of the output power density and efficiency of the HT-PEMFC are deduced. The reliability of the model is verified by the experimental data. The effects of operating parameters and design parameters on the output performance of the HT-PEMFC are further analyzed. The particle swarm optimization (PSO) algorithm is used for the multi-objective optimization of the power density and efficiency of the HT-PEMFC. The results show that the output performance of the optimized HT-PEMFC is improved. Then, according to the different output performance of the low-temperature proton exchange membrane fuel cell (LT-PEMFC), HT-PEMFC, and optimized HT-PEMFC, different design schemes are provided for a fuel cell vehicle (FCV) powertrain. Simulation tests are conducted under different driving cycles, and the results show that the FCV with the optimized HT-PEMFC is more efficient and consumes less hydrogen.


2015 ◽  
Vol 3 (16) ◽  
pp. 8847-8854 ◽  
Author(s):  
Zhibin Guo ◽  
Ruijie Xiu ◽  
Shanfu Lu ◽  
Xin Xu ◽  
Shichun Yang ◽  
...  

A novel submicro-pore containing proton exchange membrane is designed and fabricated for application in high-temperature fuel cells.


2021 ◽  
Vol 7 ◽  
pp. 1374-1384 ◽  
Author(s):  
Taiming Huang ◽  
Wei Wang ◽  
Yao Yuan ◽  
Jie Huang ◽  
Xi Chen ◽  
...  

2022 ◽  
pp. 1-33
Author(s):  
Xiuqin Zhang ◽  
Wentao Cheng ◽  
Qiubao Lin ◽  
Longquan Wu ◽  
Junyi Wang ◽  
...  

Abstract Proton exchange membrane fuel cells (PEMFCs) based on syngas are a promising technology for electric vehicle applications. To increase the fuel conversion efficiency, the low-temperature waste heat from the PEMFC is absorbed by a refrigerator. The absorption refrigerator provides cool air for the interior space of the vehicle. Between finishing the steam reforming reaction and flowing into the fuel cell, the gases release heat continuously. A Brayton engine is introduced to absorb heat and provide a useful power output. A novel thermodynamic model of the integrated system of the PEMFC, refrigerator, and Brayton engine is established. Expressions for the power output and efficiency of the integrated system are derived. The effects of some key parameters are discussed in detail to attain optimum performance of the integrated system. The simulation results show that when the syngas consumption rate is 4.0 × 10−5 mol s−1cm−2, the integrated system operates in an optimum state, and the product of the efficiency and power density reaches a maximum. In this case, the efficiency and power density of the integrated system are 0.28 and 0.96 J s−1 cm−2, respectively, which are 46% higher than those of a PEMFC.


Author(s):  
Utku Gulan ◽  
Hasmet Turkoglu ◽  
Irfan Ar

In this study, the fluid flow and cell performance in cathode side of a proton exchange membrane (PEM) fuel cell were numerically analyzed. The problem domain consists of cathode gas channel, cathode gas diffusion layer, and cathode catalyst layer. The equations governing the motion of air, concentration of oxygen, and electrochemical reactions were numerically solved. A computer program was developed based on control volume method and SIMPLE algorithm. The mathematical model and program developed were tested by comparing the results of numerical simulations with the results from literature. Simulations were performed for different values of inlet Reynolds number and inlet oxygen mole fraction at different operation temperatures. Using the results of these simulations, the effects of these parameters on the flow, oxygen concentration distribution, current density and power density were analyzed. The simulations showed that the oxygen concentration in the catalyst layer increases with increasing Reynolds number and hence the current density and power density of the PEM fuel cell also increases. Analysis of the data obtained from simulations also shows that current density and power density of the PEM fuel cell increases with increasing operation temperature. It is also observed that increasing the inlet oxygen mole fraction increases the current density and power density.


2014 ◽  
Vol 246 ◽  
pp. 63-67 ◽  
Author(s):  
Huaneng Su ◽  
Ting-Chu Jao ◽  
Sivakumar Pasupathi ◽  
Bernard Jan Bladergroen ◽  
Vladimir Linkov ◽  
...  

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