scholarly journals Viscosity and Structural Investigation of High-Concentration Al2O3 and MgO Slag System for FeO Reduction in Electric Arc Furnace Processing

Metals ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1169
Author(s):  
Youngjae Kim ◽  
Dong-Joon Min
Keyword(s):  
Slag System ◽  
Electric Arc Furnace ◽  
Electric Arc ◽  
Slag Viscosity ◽  
Present System ◽  
Arc Furnace ◽  
High Concentration ◽  
Slag Structure ◽  
Al2o3 Concentration ◽  
Feo Reduction

In the present study, the viscosity of the CaO–SiO2–FeO–Al2O3–MgO slag system was measured for the recovery of FeO in the electric arc furnace (EAF) process using Al dross. Considering the MgO-saturated operational condition of the EAF, the viscosity was measured in the MgO-saturated composition at 1823 K with varying FeO and Al2O3 concentrations. An increase in the slag viscosity with decreasing temperature was observed. The activation energy was evaluated, and the change in the thermodynamically equilibrated phase was considered. The changes in the aluminate structure with varying FeO and Al2O3 concentrations were investigated by Fourier-transform infrared spectroscopy, which revealed an increase in the [AlO4] tetrahedral structure with increasing Al2O3 concentration. Depolymerization of the aluminate structure was observed at higher FeO concentrations. The Raman spectra showed the polymerization of the silicate network structure at higher Al2O3 concentrations. By associations between the silicate and aluminate structures, a more highly polymerized slag structure was achieved in the present system by increasing the Al2O3 concentration.

scholarly journals Coal Fly Ash–Clay Based Geopolymer-Incorporating Electric Arc Furnace Dust (EAFD): Leaching Behavior and Geochemical Modeling

2021 ◽  
Vol 11 (2) ◽  
pp. 810
Author(s):  
Eva Cifrian ◽  
Juan Dacuba ◽  
Tamara Llano ◽  
María del Carmen Díaz-Fernández ◽  
Ana Andrés
Keyword(s):  
Geochemical Modeling ◽  
Coal Fly Ash ◽  
Ph Dependence ◽  
Electric Arc Furnace ◽  
Electric Arc ◽  
Future Research ◽  
Arc Furnace ◽  
High Concentration ◽  
High Iron Content ◽  
Electric Arc Furnace Dust

The recent recovery processes of electric arc furnace dust (EAFD) include stabilization within materials with potential uses in the construction sector. The stabilization of EAFD by alkaline activation of different alumina-silicates, resulting in low-cost and environmentally friendly materials. The leaching standards within the different European regulations allow evaluating waste materials and products. This work aims to study the introduction of EAFD in FA–clay geopolymers, assessing the environmental and geochemical behavior in two different scenarios, disposal, and utilization. For it, the compliance equilibrium-based batch test (EN 12457-2) and pH dependence test (EN 14429) have been used. The dosages of EAFD in the geopolymeric matrix are 5% to 20% with curing temperatures of 75 °C and 225 °C. The introduction of EAFD favors the development of the flexural strength. From the environmental point of view, metals related to EAFD, such as Zn, Pb, or Cu, are retained in the matrix. While As or Se, comes mainly from clay, present a high concentration. Therefore, the role of clay should be analyzed in future research. As expected by the high iron content in the EAFD, the iron complexes on the surface of the material are responsible for immobilization of metals in this type of matrix.

Balance of Raw Input and Energy of Titanium Slag Smelting in Closed High Power Direct Current Electric Arc Furnace

2013 ◽  
Vol 734-737 ◽  
pp. 1516-1521
Author(s):  
Feng Xia Han ◽  
Xiu Li Sang ◽  
Jian Xin Xu
Keyword(s):  
Direct Current ◽  
High Power ◽  
Dynamic Balance ◽  
Electric Arc Furnace ◽  
Electric Arc ◽  
Slag Viscosity ◽  
Arc Furnace ◽  
High Quality ◽  
Titanium Slag ◽  
Freeze Lining

There were two controlling factors, which should be kept balance of raw input and energy during titanium slag smelting in closed high power direct current electric arc furnace, DC furnace for short. The first factor contains compositions and ratio of input raw materials. Compositions of the raw could influence the progress and technical indicators of DC furnace smelting, and on the meanwhile, it could determine the compositions of impurity and contents of TiO2 in titanium slag. On the other hand, the ratio of input infected the compositions of the slag, while too much anthracite would disadvantage to produce high quality slag because of impurity being reduced continually. Meanwhile much more low-state titanium would be generated. The second factor was an important one that energy equilibrium, which influence the production safety of DC furnace. It could keep balance of input and output energy, while the heatloss was 4.971 MVA. While the ratio of anthracite remained the same, the energy would effect slag viscosity and equilibrium of freeze lining directly. The energy input higher than smelting need would result in burnthrough of furnace wall and hearth, on the contrary, lower than smelting need would bring about slagging difficulties. Consequently, raw input and energy must be kept dynamic balance in order to achieve high quality titanium slag and protect freeze lining.

Analytical Electron Microscopy Characterization of Electric Arc Furnace Dust

1981 ◽  
Vol 39 ◽  
pp. 134-135
Author(s):  
J. R. Porter ◽  
J. I. Goldstein ◽  
D. B. Williams
Keyword(s):  
Electron Microscopy ◽  
Analytical Electron Microscopy ◽  
Electric Arc Furnace ◽  
Electric Arc ◽  
Dust Particles ◽  
Particle Analysis ◽  
Arc Furnace ◽  
Analytical Electron ◽  
Residual Elements ◽  
Industry Practice

Alloy scrap metal is increasingly being used in electric arc furnace (EAF) steelmaking and the alloying elements are also found in the resulting dust. A comprehensive characterization program of EAF dust has been undertaken in collaboration with the steel industry and AISI. Samples have been collected from the furnaces of 28 steel companies representing the broad spectrum of industry practice. The program aims to develop an understanding of the mechanisms of formation so that procedures to recover residual elements or recycle the dust can be established. The multi-phase, multi-component dust particles are amenable to individual particle analysis using modern analytical electron microscopy (AEM) methods.Particles are ultrasonically dispersed and subsequently supported on carbon coated formvar films on berylium grids for microscopy. The specimens require careful treatment to prevent agglomeration during preparation which occurs as a result of the combined effects of the fine particle size and particle magnetism. A number of approaches to inhibit agglomeration are currently being evaluated including dispersal in easily sublimable organic solids and size fractioning by centrifugation.

Monitoring the environmental and energy impacts of electric arc furnace steelmaking

2016 ◽  
Vol 104 (1) ◽  
pp. 102 ◽  
Author(s):  
Valentina Colla ◽  
Filippo Cirilli ◽  
Bernd Kleimt ◽  
Inigo Unamuno ◽  
Silvia Tosato ◽  
...  
Keyword(s):  
Electric Arc Furnace ◽  
Electric Arc ◽  
Arc Furnace
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