scholarly journals Chitosan-Based Flexible Memristors with Embedded Carbon Nanotubes for Neuromorphic Electronics

Micromachines ◽  
2021 ◽  
Vol 12 (10) ◽  
pp. 1259
Author(s):  
Jin-Gi Min ◽  
Won-Ju Cho

In this study, we propose high-performance chitosan-based flexible memristors with embedded single-walled carbon nanotubes (SWCNTs) for neuromorphic electronics. These flexible transparent memristors were applied to a polyethylene naphthalate (PEN) substrate using low-temperature solution processing. The chitosan-based flexible memristors have a bipolar resistive switching (BRS) behavior due to the cation-based electrochemical reaction between a polymeric chitosan electrolyte and mobile ions. The effect of SWCNT addition on the BRS characteristics was analyzed. It was observed that the embedded SWCNTs absorb more metal ions and trigger the conductive filament in the chitosan electrolyte, resulting in a more stable and wider BRS window compared to the device with no SWCNTs. The memory window of the chitosan nanocomposite memristors with SWCNTs was 14.98, which was approximately double that of devices without SWCNTs (6.39). Furthermore, the proposed SWCNT-embedded chitosan-based memristors had memristive properties, such as short-term and long-term plasticity via paired-pulse facilitation and spike-timing-dependent plasticity, respectively. In addition, the conductivity modulation was evaluated with 300 synaptic pulses. These findings suggest that memristors featuring SWCNT-embedded chitosan are a promising building block for future artificial synaptic electronics applications.

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Jae-Won Lee ◽  
Joon Young Cho ◽  
Mi Jeong Kim ◽  
Jung Hoon Kim ◽  
Jong Hwan Park ◽  
...  

AbstractSoft electronic devices that are bendable and stretchable require stretchable electric or electronic components. Nanostructured conducting materials or soft conducting polymers are one of the most promising fillers to achieve high performance and durability. Here, we report silver nanoparticles (AgNPs) embedded with single-walled carbon nanotubes (SWCNTs) synthesized in aqueous solutions at room temperature, using NaBH4 as a reducing agent in the presence of highly oxidized SWCNTs as efficient nucleation agents. Elastic composite films composed of the AgNPs-embedded SWCNTs, Ag flake, and polydimethylsiloxane are irradiated with radiation from a Xenon flash lamp within a time interval of one second for efficient sintering of conductive fillers. Under high irradiation energy, the stretchable electrodes are created with a maximum conductivity of 4,907 S cm−1 and a highly stretchable stability of over 10,000 cycles under a 20% strain. Moreover, under a low irradiation energy, strain sensors with a gauge factor of 76 under a 20% strain and 5.4 under a 5% strain are fabricated. For practical demonstration, the fabricated stretchable electrode and strain sensor are attached to a human finger for detecting the motions of the finger.


Nanoscale ◽  
2014 ◽  
Vol 6 (3) ◽  
pp. 1552-1559 ◽  
Author(s):  
Hongli Mao ◽  
Rong Cai ◽  
Naoki Kawazoe ◽  
Guoping Chen

Author(s):  
Yaofeng Wang ◽  
Fan Wang ◽  
Yang Kong ◽  
Lei Wang ◽  
Qinchuan Li

Abstract High-performance bioartificial muscles with low-cost, large bending deformation, low actuation voltage, and fast response time have drawn extensive attention as the development of human-friendly electronics in recent years. Here, we report a high-performance ionic bioartificial muscle based on the bacterial cellulose (BC)/ionic liquid (IL)/multi-walled carbon nanotubes (MWCNT) nanocomposite membrane and PEDOT:PSS electrode. The developed ionic actuator exhibits excellent electro-chemo-mechanical properties, which are ascribed to its high ionic conductivity, large specific capacitance, and ionically crosslinked structure resulting from the strong ionic interaction and physical crosslinking among BC, IL, and MWCNT. In particular, the proposed BC-IL-MWCNT (0.10 wt%) nanocomposite exhibited significant increments of Young's modulus up to 75% and specific capacitance up to 77%, leading to 2.5 times larger bending deformation than that of the BC-IL actuator. More interestingly, bioinspired applications containing artificial soft robotic finger and grapple robot were successfully demonstrated based on high-performance BC-IL-MWCNT actuator with excellent sensitivity and controllability. Thus, the newly proposed BC-IL-MWCNT bioartificial muscle will offer a viable pathway for developing next-generation artificial muscles, soft robotics, wearable electronic products, flexible tactile devices, and biomedical instruments.


RSC Advances ◽  
2015 ◽  
Vol 5 (51) ◽  
pp. 41179-41185 ◽  
Author(s):  
Xiaolei Wang ◽  
Ge Li ◽  
Ricky Tjandra ◽  
Xingye Fan ◽  
Xingcheng Xiao ◽  
...  

Nanocomposites of Nb2O5 NCs in situ grown on CNTs are successfully developed with excellent rate capability, leading to the successful fabrication of asymmetric supercapacitors with high energy and power density and long-term cycling stability.


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