scholarly journals Recyclable Catalysts for Alkyne Functionalization

Molecules ◽  
2021 ◽  
Vol 26 (12) ◽  
pp. 3525
Author(s):  
Leslie Trigoura ◽  
Yalan Xing ◽  
Bhanu P. S. Chauhan
Keyword(s):  
Supported Catalysts ◽  
Metal Organic Framework ◽  
Metal Nanoparticle ◽  
Homogeneous Catalyst ◽  
Catalyst Recycling ◽  
Catalytic Systems ◽  
Recyclable Catalysts ◽  
Metal Organic ◽  
Porous Organic Framework ◽  
Organic Framework

In this review, we present an assessment of recent advances in alkyne functionalization reactions, classified according to different classes of recyclable catalysts. In this work, we have incorporated and reviewed the activity and selectivity of recyclable catalytic systems such as polysiloxane-encapsulated novel metal nanoparticle-based catalysts, silica–copper-supported nanocatalysts, graphitic carbon-supported nanocatalysts, metal organic framework (MOF) catalysts, porous organic framework (POP) catalysts, bio-material-supported catalysts, and metal/solvent free recyclable catalysts. In addition, several alkyne functionalization reactions have been elucidated to demonstrate the success and efficiency of recyclable catalysts. In addition, this review also provides the fundamental knowledge required for utilization of green catalysts, which can combine the advantageous features of both homogeneous (catalyst modulation) and heterogeneous (catalyst recycling) catalysis.

An Overview of Metal-organic Frameworks-based Acid/Base Catalysts for Biofuel Synthesis

2020 ◽  
Vol 24 (16) ◽  
pp. 1876-1891
Author(s):  
Qiuyun Zhang ◽  
Yutao Zhang ◽  
Jingsong Cheng ◽  
Hu Li ◽  
Peihua Ma
Keyword(s):  
Alternative Fuels ◽  
Heterogeneous Catalysts ◽  
Supported Catalysts ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Flexible Structures ◽  
Biodiesel Production ◽  
Biodiesel Synthesis ◽  
Metal Organic ◽  
Organic Framework

Biofuel synthesis is of great significance for producing alternative fuels. Among the developed catalytic materials, the metal-organic framework-based hybrids used as acidic, basic, or supported catalysts play major roles in the biodiesel production. This paper presents a timely and comprehensive review of recent developments on the design and preparation of metal-organic frameworks-based catalysts used for biodiesel synthesis from various oil feedstocks, including MILs-based catalysts, ZIFs-based catalysts, UiO-based catalysts, Cu-BTC-based catalysts, and MOFs-derived porous catalysts. Due to their unique and flexible structures, excellent thermal and hydrothermal stability, and tunable host-guest interactions, as compared with other heterogeneous catalysts, metal-organic framework-based catalysts have good opportunities for application in the production of biodiesel at industrial scale.

A multifunctional MOF as a recyclable catalyst for the fixation of CO2 with aziridines or epoxides and as a luminescent probe of Cr(vi)

2018 ◽  
Vol 47 (13) ◽  
pp. 4545-4553 ◽  
Author(s):  
Chun-Shuai Cao ◽  
Ying Shi ◽  
Hang Xu ◽  
Bin Zhao
Keyword(s):  
Metal Organic Framework ◽  
Recyclable Catalyst ◽  
Luminescent Probe ◽  
Recyclable Catalysts ◽  
Metal Organic ◽  
Organic Framework

A multifunctional metal-organic framework (1) can serve as an efficient and recyclable catalysts for the conversion of CO2 with aziridines or epoxides. Furthermore, the material can also act as a recyclable luminescent probe for Cr(vi) species among twenty anions.

An integrated function system using metal nanoparticle@mesoporous silica@metal-organic framework hybrids

2017 ◽  
Vol 245 ◽  
pp. 104-108 ◽  
Author(s):  
Takashi Ohhashi ◽  
Takaaki Tsuruoka ◽  
Kohei Inoue ◽  
Yohei Takashima ◽  
Satoshi Horike ◽  
...  
Keyword(s):  
Mesoporous Silica ◽  
Metal Organic Framework ◽  
Metal Nanoparticle ◽  
Function System ◽  
Metal Organic ◽  
Organic Framework

Metal organic framework derived magnetic porous carbon composite supported gold and palladium nanoparticles as highly efficient and recyclable catalysts for reduction of 4-nitrophenol and hydrodechlorination of 4-chlorophenol

2014 ◽  
Vol 2 (44) ◽  
pp. 18775-18785 ◽  
Author(s):  
Zhengping Dong ◽  
Xuanduong Le ◽  
Yansheng Liu ◽  
Chunxu Dong ◽  
Jiantai Ma
Keyword(s):  
Porous Carbon ◽  
Palladium Nanoparticles ◽  
Metal Organic Framework ◽  
Catalyst Support ◽  
Carbon Composite ◽  
Highly Efficient ◽  
Recyclable Catalysts ◽  
Metal Organic ◽  
Supported Gold ◽  
Organic Framework

A magnetic porous carbon composite which has been synthesized from MOF is used as a catalyst support to fabricate Au and Pd NP based nanocatalysts.

Core–Shell Catalysts of Metal Nanoparticle Core and Metal–Organic Framework Shell

ACS Catalysis ◽  
2014 ◽  
Vol 4 (12) ◽  
pp. 4409-4419 ◽  
Author(s):  
Pan Hu ◽  
Joseph V. Morabito ◽  
Chia-Kuang Tsung
Keyword(s):  
Metal Organic Framework ◽  
Metal Nanoparticle ◽  
Core Shell ◽  
Metal Organic ◽  
Nanoparticle Core ◽  
Organic Framework

Advanced photocatalysts based on metal nanoparticle/metal-organic framework composites

Nano Research ◽  
2020 ◽  
Author(s):  
Jun Guo ◽  
Yue Wan ◽  
Yanfei Zhu ◽  
Meiting Zhao ◽  
Zhiyong Tang
Keyword(s):  
Metal Organic Framework ◽  
Metal Nanoparticle ◽  
Metal Organic ◽  
Organic Framework

A high-valent di-μ-oxo dimanganese complex covalently anchored in a metal–organic framework as a highly efficient and recoverable water oxidation catalyst

2018 ◽  
Vol 54 (33) ◽  
pp. 4188-4191 ◽  
Author(s):  
Lina Zhang ◽  
Junying Chen ◽  
Ting Fan ◽  
Kui Shen ◽  
Miao Jiang ◽  
...  
Keyword(s):  
High Activity ◽  
Water Oxidation ◽  
Oxidation Reaction ◽  
Metal Organic Framework ◽  
Oxidation Catalyst ◽  
Homogeneous Catalyst ◽  
Highly Efficient ◽  
Metal Organic ◽  
High Valent ◽  
Organic Framework

A biomimetic homogeneous catalyst is successfully anchored inside MOFs, exhibiting high activity and reliable durability in the water oxidation reaction.

Sign in / Sign up

Export Citation Format

Share Document