Plasma Enabled Fe2O3/Fe3O4 Nano-aggregates Anchored on Nitrogen-doped Graphene as Anode for Sodium-Ion Batteries

Low electrical conductivity severely limits the application of Fe2O3 in lithium- and sodium-ion batteries. In respect of this, we design and fabricate Fe2O3/Fe3O4 nano-aggregates anchored on nitrogen-doped graphene as an anode for sodium-ion batteries with the assistance of microwave plasma. The highly conductive Fe3O4 in the composite can function as a highway of electron transport, and the voids and phase boundaries in the Fe2O3/Fe3O4 heterostructure facilitate Na+ ion diffusion into the nano-aggregates. Furthermore, the Fe–O–C bonds between the nano-aggregates and graphene not only stabilize the structural integrity, but also enhance the charge transfer. Consequently, the Fe2O3/Fe3O4/NG anode exhibits specific capacity up to 362 mAh g−1 at 100 mA g−1, excellent rate capability, and stable long-term cycling performance. This multi-component-based heterostructure design can be used in anode materials for lithium- and sodium-ion batteries, and potential opens a new path for energy storage electrodes.

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Spatially controlled synthesis of superlattice-like SnS/nitrogen-doped graphene hybrid nanobelts as high-rate and durable anode materials for sodium-ion batteries

Journal of Materials Chemistry A ◽

10.1039/c9ta08945d ◽

2019 ◽

Vol 7 (48) ◽

pp. 27475-27483 ◽

Cited By ~ 9

Author(s):

Lei Wang ◽

Xiaofang Li ◽

Zhenzhen Jin ◽

Zhun Liang ◽

Xiang Peng ◽

...

Keyword(s):

Anode Materials ◽

Rate Capability ◽

Sodium Ion ◽

High Rate ◽

Controlled Synthesis ◽

Sodium Ion Batteries ◽

High Rate Capability ◽

Nitrogen Doped ◽

Nitrogen Doped Graphene ◽

Doped Graphene

Superlattice-like SnS/NG anode material prepared via spatially confined carbonization and phase-transformation exhibits excellent durability, high rate capability and large capacity.

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Understanding Na-Ion Adsorption in Nitrogen Doped Graphene Oxide Anode for Rechargeable Sodium Ion Batteries

Applied Surface Science ◽

10.1016/j.apsusc.2021.152147 ◽

2021 ◽

pp. 152147

Author(s):

Siraj Ud Daula Shamim ◽

Md Kamal Hossain ◽

Syed Mahedi Hasan ◽

Afiya Akter Piya ◽

Mohammad Sadiqur Rahman ◽

...

Keyword(s):

Graphene Oxide ◽

Sodium Ion ◽

Ion Adsorption ◽

Sodium Ion Batteries ◽

Nitrogen Doped ◽

Nitrogen Doped Graphene ◽

Doped Graphene ◽

Oxide Anode

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Nitrogen-doped graphene-wrapped Cu2S as a superior anode in sodium-ion batteries

Carbon ◽

10.1016/j.carbon.2020.08.031 ◽

2020 ◽

Vol 170 ◽

pp. 430-438 ◽

Cited By ~ 2

Author(s):

Jiyu Cai ◽

Benjamin Reinhart ◽

Peter Eng ◽

Yongqiang Liu ◽

Cheng-Jun Sun ◽

...

Keyword(s):

Sodium Ion ◽

Sodium Ion Batteries ◽

Nitrogen Doped ◽

Nitrogen Doped Graphene ◽

Doped Graphene

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V2(PO4)O encapsulated into crumpled nitrogen-doped graphene as a high-performance anode material for sodium-ion batteries

Electrochimica Acta ◽

10.1016/j.electacta.2019.03.133 ◽

2019 ◽

Vol 306 ◽

pp. 238-244 ◽

Cited By ~ 6

Author(s):

Bin Xiao ◽

Wen-hai Zhang ◽

Peng-bo Wang ◽

Lin-bo Tang ◽

Chang-sheng An ◽

...

Keyword(s):

Anode Material ◽

High Performance ◽

Sodium Ion ◽

Sodium Ion Batteries ◽

Nitrogen Doped ◽

Nitrogen Doped Graphene ◽

Doped Graphene

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The controlled construction of a ternary hybrid of monodisperse Ni3S4 nanorods/graphitic C3N4 nanosheets/nitrogen-doped graphene in van der Waals heterojunctions as a highly efficient electrocatalyst for overall water splitting and a promising anode material for sodium-ion batteries

Journal of Materials Chemistry A ◽

10.1039/c8ta07253a ◽

2019 ◽

Vol 7 (8) ◽

pp. 3714-3728 ◽

Cited By ~ 8

Author(s):

Jing Yang ◽

Shiqi Xing ◽

Jianbin Zhou ◽

Yun Cheng ◽

Lei Shi ◽

...

Keyword(s):

Water Splitting ◽

Anode Material ◽

Van Der Waals ◽

Sodium Ion ◽

Sodium Ion Batteries ◽

Nitrogen Doped ◽

Highly Efficient ◽

Overall Water Splitting ◽

Nitrogen Doped Graphene ◽

Doped Graphene

An m-Ni3S4 NRs/g-C3N4 NS/N-G hybrid with heterostructured architecture demonstrates outstanding properties for both water splitting and SIB use.

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Construction of robust coupling interface between MoS2 and nitrogen doped graphene for high performance sodium ion batteries

Journal of Energy Chemistry ◽

10.1016/j.jechem.2020.02.012 ◽

2020 ◽

Vol 48 ◽

pp. 435-442 ◽

Cited By ~ 4

Author(s):

Yun Qiao ◽

Jiawei Wu ◽

Xiaoguang Cheng ◽

Yudong Pang ◽

Zhansheng Lu ◽

...

Keyword(s):

High Performance ◽

Sodium Ion ◽

Sodium Ion Batteries ◽

Nitrogen Doped ◽

Nitrogen Doped Graphene ◽

Doped Graphene

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Custom designed ZnMn2O4/nitrogen doped graphene composite anode validated for sodium ion battery application

RSC Advances ◽

10.1039/c7ra02289a ◽

2017 ◽

Vol 7 (32) ◽

pp. 20057-20061 ◽

Cited By ~ 10

Author(s):

B. Chandra Sekhar ◽

P. Packiyalakshmi ◽

N. Kalaiselvi

Keyword(s):

Ph Control ◽

Sodium Ion ◽

Sodium Ion Battery ◽

Sodium Ion Batteries ◽

Composite Anode ◽

Nitrogen Doped ◽

Graphene Composite ◽

Nitrogen Doped Graphene ◽

Doped Graphene ◽

Battery Application

pH control synthesised ZnMn2O4 nanoparticles embedded in nitrogen doped graphene sheets demonstrate themselves to be a potential anode for sodium-ion batteries.

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Nitrogen-doped carbon coated SiO nanoparticles Co-modified with nitrogen-doped graphene as a superior anode material for lithium-ion batteries

RSC Advances ◽

10.1039/c4ra06678b ◽

2014 ◽

Vol 4 (67) ◽

pp. 35717-35725 ◽

Cited By ~ 4

Author(s):

Chenfeng Guo ◽

Jingxuan Mao ◽

Dianlong Wang

Keyword(s):

Lithium Ion Batteries ◽

Specific Capacity ◽

Rate Capability ◽

Lithium Ion ◽

Cyclic Life ◽

Nitrogen Doped ◽

Carbon Coated ◽

Nitrogen Doped Graphene ◽

Doped Graphene ◽

Nitrogen Doped Carbon

One great challenge in the development of lithium-ion batteries is to simultaneously achieve superior reversible specific capacity, cyclic life and rate capability.

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