scholarly journals Graphene Oxide and Carbon Nanotubes-Based Polyvinylidene Fluoride Membrane for Highly Increased Water Treatment

Nanomaterials ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 2498
Author(s):  
Jungryeong Chae ◽  
Taeuk Lim ◽  
Hao Cheng ◽  
Jie Hu ◽  
Sunghoon Kim ◽  
...  

As contaminated water increases due to environmental pollution, the need for excellent water treatment is increased, and several studies have reported the polyvinylidene fluoride (PVDF)-based water treatment membranes. However, the PVDF membrane has several problems such as low filtration performance, fouling resistance, and difficulty in precisely controlling the morphology of the pores and hydrophilicity. Therefore, we newly produced a water treatment PVDF membrane containing graphene oxide (GO) and multi-walled carbon nanotubes (MWCNTs) to improve the filtration performance. Surface properties of the fabricated membrane such as morphology, and size of pores, hydrophilicity, and water flux of the membrane were investigated. Additionally, the performance of these membrane filters was evaluated for free residual chlorine, turbidity, chromaticity, magnesium, sulfate, and particulates class 1 according to drinking water management act criteria, respectively. A performance improvement of at least 108.37% was observed compared to the Pure PVDF filter module and anti-fouling effects due to the functional groups of GO and MWCNTs. These results reveal that proposed membrane can accelerate the development of various water filtration applications.

Nanomaterials ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 2269
Author(s):  
Jungryeong Chae ◽  
Taeuk Lim ◽  
Hao Cheng ◽  
Wonsuk Jung

The effect of changes in non-solvent coagulation bath temperature on surface properties such as morphology and hydrophilicity were investigated in multi-walled carbon nanotubes (MWCNTs) and graphene oxide (GO)-based polyvinylidene fluoride (PVDF) membranes. The properties of pores (size, shape, and number) as well as membrane hydrophilicity were investigated using field emission scanning electron microscopy, Raman spectroscopy, optical microscopy, water contact angle, and water flux. Results showed that the pore size increased with an increase in coagulation temperature. The hydrophilic functional groups of the added carbon materials increased the solvent and non-solvent diffusion rate, which significantly increased the number of pores by 700% as compared to pure PVDF. Additionally, these functional groups changed the hydrophobic properties of pure PVDF into hydrophilic properties.


2013 ◽  
Vol 13 (12) ◽  
pp. 4749-4756 ◽  
Author(s):  
Xiaoyu Li ◽  
Xiangdong Chen ◽  
Yao Yao ◽  
Ning Li ◽  
Xinpeng Chen ◽  
...  

2021 ◽  
Vol 21 (7) ◽  
pp. 3711-3715
Author(s):  
Jeongdong Choi ◽  
Eun-Sik Kim

This study investigated experimental parameters to fabricate polymeric carbon nanocomposite hollow-fiber membranes with graphene oxide and multi-walled carbon nanotubes. This case was different from that of flat-sheet type membranes in that the characteristics of the hollow-fiber type membranes were affected by the structure of the spinneret, the flow rate of the injected polymer and draw solution, and the mixing ratio. The membranes were characterized in terms of mechanical strength, porosity, hydrophilicity, and permeate flux using different solutions. The results reveal a mechanical strength of the carbon nanocomposite hollow-fiber membranes that is about 47.8% higher than that of hollow-fiber membranes without carbon nanomaterials. The porosity and surface hydrophilicity changed to produce more applicable membranes for water and wastewater treatment. As for the permeate flux, the nanocomposite membrane with graphene oxide showed a higher flux compared to the multi-walled carbon nanotubes membrane, which could be influenced by structural effects of the carbon materials.


Chemosphere ◽  
2021 ◽  
Vol 263 ◽  
pp. 128043 ◽  
Author(s):  
Mahsa Masjoudi ◽  
Mitra Golgoli ◽  
Zahra Ghobadi Nejad ◽  
Sadegh Sadeghzadeh ◽  
Seyed Mehdi Borghei

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