scholarly journals Crosslinked Fluorinated Poly(arylene Ether)s with POSS: Synthesis and Conversion to High-Performance Polymers

Polymers ◽  
2021 ◽  
Vol 13 (20) ◽  
pp. 3489
Author(s):  
Yashu He ◽  
Jingting Wang ◽  
Igor S. Sirotin ◽  
Vyacheslav V. Kireev ◽  
Jianxin Mu

This study reports on a series of crosslinked poly(arylene ether)s with POSS in the main chain. The fluorinated and terminated poly(arylene ether)s were first synthesized by the nucleophilic reaction of diphenol POSS and decafluorodiphenyl monomers, including decafluorobiphenyl, decaflurobenzophenone, and decafluorodiphenyl sulfone. They were then reacted with 3-hydroxyphenyl acetylene to produce phenylacetylene-terminated poly(arylene ether)s. The polymers were of excellent processability. When heated to a high temperature, the polymers converted into a crosslinked network, exhibiting a low range of dielectric constant from 2.17 to 2.58 at 1 HMz, strong resistance against chemical solutions, low dielectric losses, and good thermal and hydrophobic properties.

2019 ◽  
Vol 10 (19) ◽  
pp. 2387-2396 ◽  
Author(s):  
Kan Zhang ◽  
Xinye Yu ◽  
Shiao-Wei Kuo

A high performance cross-linked polymer with a very low dielectric constant was achieved via a newly designed main-chain type poly(benzoxazine-co-imide-co-siloxane).


RSC Advances ◽  
2016 ◽  
Vol 6 (90) ◽  
pp. 87433-87439 ◽  
Author(s):  
Jinmeng Hao ◽  
Yanfeng Wei ◽  
Jianxin Mu

Soluble poly(arylene ether)s with perfluoro-aromatics and POSS in the main chains exhibited ultra low dielectric constants and hydrophobic properties.


RSC Advances ◽  
2015 ◽  
Vol 5 (93) ◽  
pp. 76476-76482 ◽  
Author(s):  
Zhenxun Huang ◽  
Shumei Liu ◽  
Yanchao Yuan ◽  
Jianqing Zhao

A simple strategy for preparing the low-κ FPI hybrids with enhanced properties.


2018 ◽  
Vol 135 (44) ◽  
pp. 46857 ◽  
Author(s):  
Yurong Zhang ◽  
Hao Jiang ◽  
Jie Liu ◽  
Chengji Zhao ◽  
Hui Na

2015 ◽  
Vol 46 (1) ◽  
pp. 450-453
Author(s):  
Haiwei Chen ◽  
Fenglin Peng ◽  
Shin-Tson Wu ◽  
Minggang Hu ◽  
Jian Li ◽  
...  

2014 ◽  
Vol 2 (29) ◽  
pp. 11144-11154 ◽  
Author(s):  
Ming Tian ◽  
Qin Ma ◽  
Xiaolin Li ◽  
Liqun Zhang ◽  
Toshio Nishi ◽  
...  

A novel dielectric composite with high dielectric constant (k), low dielectric loss, low elastic modulus and large actuated strain at a low electric field was prepared by a simple, low-cost and efficient method.


2020 ◽  
Vol 59 (20) ◽  
pp. 9541-9549
Author(s):  
Gang Zhang ◽  
Dongsheng Li ◽  
Guangming Yan ◽  
Han Wang ◽  
Yu Zhang ◽  
...  

2019 ◽  
Vol 162 ◽  
pp. 29-35 ◽  
Author(s):  
Aniruddha Nag ◽  
Mohammad Asif Ali ◽  
Makoto Watanabe ◽  
Maninder Singh ◽  
Kittima Amornwachirabodee ◽  
...  

2014 ◽  
Vol 4 (11) ◽  
pp. 2262 ◽  
Author(s):  
Haiwei Chen ◽  
Fenglin Peng ◽  
Zhenyue Luo ◽  
Daming Xu ◽  
Shin-Tson Wu ◽  
...  

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