Increasing the heat resistance of cast nickel-based complex alloyed alloys due to the influence of the redistribution of alloying elements between the γ-solid solution and the strengthening intermetallic γ'-phase

2020 ◽  
pp. 67-79
Author(s):  
O.M. Gubanov ◽  
V.N. Gadalov ◽  
Yu.V. Skripkina ◽  
I.A. Makarova

The analysis of alloying of the chemical and phase composition of domestic and foreign cast heat-resistant alloys with a nickel matrix is carried out; the tendency to increase the level of heat-resistant properties of cast nickel alloys due to more complex alloying is traced. Recently, expensive rhenium, ruthenium, hafnium, and dysprosium have increasingly been used as alloying elements. The positive effect of these elements on the thermal stability of the γ-matrix and the strengthening γ'-phase is established. The above elements inhibit diffusion processes, thereby increasing the creep resistance of alloys at high temperatures and loads. The evaluation of heatresistant nickel alloys obtained by directional crystallization is given. It is established that the most significant parameters of the phase composition of the studied alloys are the distribution coefficients of alloying elements between the γ' and γ-phases (Ki). The basic principles of balanced alloying, which are used to select the optimal chemical composition of heat-resistant nickel alloys, are formulated. To achieve the maximum heat resistance parameters in the selected heat-resistant nickel alloys alloying system, the calculated value γ/γ' defined by “misfit” was used, which is calculated by the formula: Δа = (аγ-аγ')/ аγ, where аγ and аγ' are the lattice periods of γ and γʹ-phases. Thus, the calculated Δа should be positive for аγ> аγ' and at least two to three times more than for single-crystal heat-resistant nickel alloys with a traditional alloying system, for which Δа = (0.1-0.2) or more. It is shown that misfit (γ/γ') is mainly determined by those alloying elements that increase the аγ most significantly. These elements are Re, Pu, Mo, W, Nb, and Ta in ascending order of influence on the lattice period (аγ) of the phase.

Author(s):  
V.N. Gadalov ◽  
A.V. Filonovich ◽  
I.V. Vornacheva ◽  
E.A. Filatov ◽  
I.A. Makarova

The positive effect of alloying elements on the thermal stability of the γ-matrix and the strengthening γ'-phase of casting nickel alloys, and consequently, on the increase in their heat-temperature strength is established. The alloying elements inhibit diffusion processes, thereby increasing the creep resistance of alloys at high temperatures and loads. It is found that the most indicative parameters of the phase composition of the test alloys are the alloying elements distribution coefficients between the γ- and γ'-phases. The basic principles of balanced alloying are formulated, on which the choice of the optimal chemical composition of heat-temperature nickel alloys is carried out.


2021 ◽  
Vol 99 (3) ◽  
pp. 15-22
Author(s):  
O.A. Glotka ◽  
◽  
V.Yu. Olshanetskii ◽  

The aim of this work is to obtain predictive regression models, with which it is possible to adequately calculate the mechanical properties of heat-resistant nickel alloys, without prior experiments. Industrial alloys of directional crystallization of domestic and foreign production were selected for research. The values were processed by the method of least squares to obtain correlations with the receipt of mathematical equations of regression models that optimally describe these dependencies. As a result of processing of experimental data, the ratio of alloying elements which can be used for an estimation of mechanical properties taking into account complex influence of the main components of an alloy is offered for the first time. Since the dimensional mismatch of the lattice parameters is associated with the degree of concentration of solid-soluble hardening of γ- and γ'-phases, the efficiency of dispersion hardening of the alloy, creep rate and other properties, the obtained ratio allows to link these properties with multicomponent systems. Regression models are presented, with the help of which it is possible to calculate dimensional mismatch, strength, heat resistance, number of  phases and density of alloys with high accuracy. The regularities of the composition influence on the properties of heat-resistant nickel alloys of directional crystallization are established. It is shown that for multicomponent nickel systems it is possible to predict with high probability misfit, which significantly affects the strength characteristics of alloys of this class. The decrease in the value of misfit is accompanied by an increase in the solubility of the elements in the -solid solution at a value of the ratio of alloying elements of 1.5 - 1.6. However, an increase in the ratio of alloying elements greater than 2 is accompanied by an increase in misfit, because the -solid solution has reached a maximum of dissolution. The perspective and effective direction in the decision of a problem of forecasting of the basic characteristics influencing a complex of service properties of alloys both at development of new heat-resistant nickel alloys, and at perfection of structures of known industrial marks of this class is shown. Keywords: nickel-based superalloys, dimensional mismatch (γ / γ'- mismatch), strength, heat resistance.


2021 ◽  
Vol 27 (2) ◽  
pp. 68-71
Author(s):  
Alexander Glotka ◽  
Vadim Ol'shanetskii

The thermodynamic processes of phase separation are modeled, which significantly affect the temperature characteristics of heat-resistant nickel alloys of directional solidification. Using an empirical approach, new ratios of elements Kg¢ and Kg have been obtained for the first time, which take into account the combined effect of alloying elements on the temperature of multicomponent compositions of cast heat-resistant alloys. The calculated values of the critical temperatures for the Ni-6Al-9Co-8W-4Re-4Ta-1.5Nb-1Mo-0.15C system (ZhS32-VI, ZhS32B-VI, and ZhS32E-VI alloys) are in good agreement with the experimental ones. The dependences of the Kg ratio on the alloying system are constructed, and the effect of alloying on the liquidus temperature of alloys is investigated. The ratios of the content of alloying elements and regression models that can be used to predict the width of the temperature range of crystallization and the optimal temperature of homogenization for a particular alloy are presented.


2013 ◽  
Vol 372 ◽  
pp. 49-53 ◽  
Author(s):  
Aliya Amenova ◽  
Nikolay Belov ◽  
Dauletkhan Smagulov ◽  
Ainagul Toleuova

The phase composition of the AlNiMnFeSiZr system is analyzed as applied to heat resistant nikalines (aluminum alloys of a new generation based on Ni containing eutectic), which are strengthened by the Al3Zr (L12) nanoparticles. It is shown that the presence of iron and silicon considerably complicates the phase analysis when compared with the AN4Mts2 base alloy. Silicon strongly widens the crystallization range, which increases the tendency of the alloy to form hot cracks during casting. It is shown that economically doped nikaline AN2ZhMts substantially exceeds the most heat resistant cast aluminum alloys of the AM5 grade in the totality of its main characteristics (heat resistance and mechanical and production properties).


Author(s):  
Nataliya Kalinina ◽  
Vasiliy Kalinin ◽  
Ivannа Serzhenko

Welded joints with corrosion-resistant steels and heat-resistant alloys, which require different modes of heat treatment to achieve the level of mechanical properties specified in the design documentation, are used for the manufacture of parts and components of the turbo-pumping unit (TPU) and liquid rocket engine. Heat-resistant alloys are a large group of alloys on iron, nickel and cobalt bases with the addition of chromium and other alloying elements (C, V, Mo, Nb, W, Ti, Al, B, etc.), whose main feature is to maintain high strength at high and cryogenic temperatures. Heat-resistant alloys are used in the manufacture of many parts of gas turbines in rocketry and jet aircraft, stationary gas turbines, the pumping of oil and gas, hydrogenation of fuel in metallurgical furnaces and many other installations. For the doping of nickel chromium γ-solid solution, several elements are used, which differently influence the increase of heat resistance and processability. Along with the main reinforcing elements (Ti, Al), refractory elements (W, Mo, Nb) are introduced into the alloy, which increase the thermal stability of the solid solution. Heat resistant alloys are based on cobalt. Cobalt has a positive effect on the heat-resistant properties of alloys. The introduction of chromium in cobalt increases its heat resistance and hardness. In addition to chromium, alloys containing cobalt include additives of other alloying elements that improve their various properties at high temperatures. A characteristic feature of these alloys is that they have relatively low heat resistance characteristics at moderate temperatures, which, however, change a little with the temperature up to 900 ° C and therefore become quite high compared to the characteristics of other heat-resistant alloys. A significant drawback of these alloys is their high cost due to the costly cobalt. Nickel-based heat-resistant alloys typically have a complex chemical composition. It includes 12–13 components, carefully balanced to obtain the required properties. The content of impurities such as silicon (Si), phosphorus (P), sulfur (S), oxygen (O) and nitrogen (N) is also controlled. The content of elements such as selenium (Se), tellurium (Te), lead (Pb) and bismuth (Bi) should be negligible, which is provided by the selection of charge materials with low content of these elements, because it is not possible to get rid of them during melting. These alloys typically contain 10–12 % chromium (Cr), up to 8% aluminum (Al) and titanium (Ti), 5–10 % cobalt (Co), as well as small amounts of boron (B), zirconium (Zr) and carbon (C). Molybdenum (Mo), tungsten (W), niobium (Nb), tantalum (Ta) and hafnium (Hf) are sometimes added. Heat-resistant alloys are used for the production of many parts of gas turbines in rocketry and jet aircrafts, stationary gas turbines, for pumping oil and gas products, for hydrogenation of fuel in metallurgical furnaces and in many other installations. Nickel-based heat-resistant alloys are also cryogenic, i.e., they are capable of operating and retaining mechanical properties at very low temperatures (–100 °C to –269 °C). Such alloys are chromium-nickel alloys having an austenitic structure. Not only do they have good mechanical properties that do not change over a large temperature range (–200 °C to 900 °C), they can also work in corrosive environments. Nickel-based heat-resistant alloys typically have a complex chemical composition. It includes 12–13 components, carefully balanced to obtain the required properties. Welded and combined workpieces are made of separate components that are interconnected by various welding methods. Welded and combined blanks greatly simplify the creation of complex configuration designs. Improper workpiece design or incorrect welding technology can cause defects (grooves, porosity, internal stresses) that are difficult to correct by machining. Given that finding replacements with multiple materials, working them out in production, and investigating interconnectivity during thermal forces in a product can take considerable time and money, it would be best to replace one alloy. Unifying the material used would allow the structure to work as a whole, which would increase the manufacturability of the products. After examining the different replacement options, inconel 718 was selected for the study. Studies of welded specimens of inconel 718 alloy-stainless steel for resistance to the ICC have shown that it is not appropriate to use  welded  inconel  718 for the impeller, it is advisable to use material that would ensure uninterrupted operation in a corrosive environment at cryogenic temperatures. Based on the working conditions of the parts, it is most expedient to make it from heat-resistant chromium-nickel alloys, namely, from float inconel 718 which meets the necessary strength characteristics. The recommended soldering mode is heating up to 950 ± 10 oC, holding for 30 minutes from the moment of loading into the oven, cooling to 3000C with the oven, further in the air, since it has less influence on the corrosion resistance of steels in stainless steel joints. Quality control of inconel 718 alloy by GOST methods similar to that used for the control of X67MBHT type alloys showed the results similar to those obtained by the ASTM and AMS control methods.


1994 ◽  
Vol 36 (12) ◽  
pp. 638-642
Author(s):  
E. N. Kablov ◽  
G. I. Morozova ◽  
G. N. Matveeva ◽  
S. A. Budinovskii

2020 ◽  
Vol 95 (3) ◽  
pp. 25-36
Author(s):  
O. A. Glotka ◽  
◽  
S.V. Gayduk ◽  
V.Yu. Olshanetskiy ◽  
◽  
...  

2014 ◽  
Vol 782 ◽  
pp. 441-444
Author(s):  
Jitka Malcharcziková ◽  
Miroslav Kursa ◽  
Martin Pohludka

The paper deals with the characterisation of the structure and phase composition of selected types of nickel alloys. Experimental alloys were prepared by vacuum induction casting. Castings were directionally solidified in corundum tubes with specified apex angle in the two-zone crystallisation furnace. Rate of directional solidification was 100 mm/h. Observation was carried out on the samples in the as-cast and directed state. Influencing of the structure by the process of directional solidification is evident. Porosity and micro-hardness were determined in transverse and longitudinal sections of individual samples and character of the formed structures was evaluated. Microstructural characterisation of materials was performed with use of scanning electron microscope. Distribution of individual elements was captured on X-ray maps, which documented significant chemical heterogeneity of investigated samples. Matrix composition corresponds approximately to the nominal composition of the alloys. The alloys contain moreover with variable content of primary and alloying elements. In the alloys with molybdenum and zirconium the phase enriched by these alloying elements were detected. On the other hand chromium is evenly dispersed in the basic matrix and it does not accumulate in the phases.


2014 ◽  
Vol 880 ◽  
pp. 282-287
Author(s):  
Mariya B. Sedelnikova ◽  
Natalyia V. Liseenko ◽  
Yuliya I. Pautova ◽  
Valery M. Pogrebenkov

Ceramic pigments with mullite structure were obtained using waste vanadium catalyst. The ion-chromophores were introduced to the initial mixture in the quantity of 5-15 wt. % in the form of nickel, chromium, iron, and cobalt oxides. It was established that the phase composition of the obtained pigments was complex and consisted of mullite and corundum. But it does not effect on the properties of the obtained pigments, in particular, on heat resistance.


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