scholarly journals Hole-Transporting Low-Dimensional Perovskite for Enhancing Photovoltaic Performance

Research ◽  
2021 ◽  
Vol 2021 ◽  
pp. 1-11
Author(s):  
Fangfang Wang ◽  
Qing Chang ◽  
Yikai Yun ◽  
Sizhou Liu ◽  
You Liu ◽  
...  

Halide perovskites with low-dimensionalities (2D or quasi-2D) have demonstrated outstanding stabilities compared to their 3D counterparts. Nevertheless, poor charge-transporting abilities of organic components in 2D perovskites lead to relatively low power conversion efficiency (PCE) and thus limit their applications in photovoltaics. Here, we report a novel hole-transporting low-dimensional (HT2D) perovskite, which can form a hole-transporting channel on the top surface of 3D perovskite due to self-assembly effects of metal halide frameworks. This HT2D perovskite can significantly reduce interface trap densities and enhance hole-extracting abilities of a heterojunction region between the 3D perovskite and hole-transporting layer. Furthermore, the posttreatment by HT2D can also reduce the crystal defects of perovskite and improve film morphology. As a result, perovskite solar cells (PSCs) can effectively suppress nonradiative recombination, leading to an increasement on photovoltage to >1.20 V and thus achieving >20% power conversion efficiency and >500 h continuous illumination stability. This work provides a pathway to overcome charge-transporting limitations in low-dimensional perovskites and delivers significant enhancements on performance of PSCs.

2016 ◽  
Vol 4 (29) ◽  
pp. 11307-11316 ◽  
Author(s):  
Minwoo Park ◽  
Joon-Suh Park ◽  
Il Ki Han ◽  
Jin Young Oh

By incorporating long P3HT nanofibrils as a hole transporting layer, high-performance, air-stable and flexible perovskite solar cells with a large active area (1 cm2) have been realized with an excellent power conversion efficiency of 13.12%.


2019 ◽  
Vol 43 (31) ◽  
pp. 12211-12214 ◽  
Author(s):  
Fatima Al-Zohbi ◽  
Youssef Jouane ◽  
Safia Benhattab ◽  
Jérôme Faure-Vincent ◽  
François Tran-Van ◽  
...  

Carbazole-based HTMs with fused benzene rings as substituents show a power conversion efficiency exceeding 17% (13.7% for Spiro-OMeTAD under the same conditions).


ChemInform ◽  
2016 ◽  
Vol 47 (11) ◽  
pp. no-no
Author(s):  
Sadia Ameen ◽  
Malik Abdul Rub ◽  
Samia A. Kosa ◽  
Khalid A. Alamry ◽  
M. Shaheer Akhtar ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (21) ◽  
pp. 17354-17359 ◽  
Author(s):  
Jiajiu Ye ◽  
Li Zhou ◽  
Liangzheng Zhu ◽  
Xuhui Zhang ◽  
Zhipeng Shao ◽  
...  

This work focuses on preparing a series of substituted bipyridine cobalt complexes as HTM dopants using a co-solvent of dichloroethane and acetylacetone as the HTM solvent, achieving an optimal power conversion efficiency of 14.91%.


2020 ◽  
Vol 8 (4) ◽  
pp. 1858-1864 ◽  
Author(s):  
Xiangyu Kong ◽  
Yue Jiang ◽  
Xiayan Wu ◽  
Cong Chen ◽  
Jiali Guo ◽  
...  

Perovskite solar cells based on dopant-free PBDT[2F]T have achieved a power conversion efficiency (17.52%), combined with an impressive stability in contrast to that with the doped spiro-OMeTAD as a HTM in ambient atmosphere and even in high humidity.


2018 ◽  
Vol 6 (47) ◽  
pp. 12912-12918 ◽  
Author(s):  
Xuepeng Liu ◽  
Xihong Ding ◽  
Yingke Ren ◽  
Yi Yang ◽  
Yong Ding ◽  
...  

A cost-effective carbazole-based hole transporting material achieved a power conversion efficiency over 18% for perovskite solar cells.


2017 ◽  
Vol 5 (48) ◽  
pp. 12752-12757 ◽  
Author(s):  
J. Zhang ◽  
L. J. Xu ◽  
P. Huang ◽  
Y. Zhou ◽  
Y. Y. Zhu ◽  
...  

Planar perovskite solar cells based on CMO as the HTM showed a high power conversion efficiency of 15.92%.


RSC Advances ◽  
2017 ◽  
Vol 7 (44) ◽  
pp. 27189-27197 ◽  
Author(s):  
Ze Yu ◽  
Yuchen Zhang ◽  
Xiaoqing Jiang ◽  
Xiaoxin Li ◽  
Jianbo Lai ◽  
...  

In this work, we have successfully demonstrated that molecularly p-doping of donor–acceptor co-polymer PCPDTBT as an efficient hole-transporting material in perovskite solar cells with a decent power conversion efficiency of 15.1%.


2017 ◽  
Vol 10 (2) ◽  
pp. 621-627 ◽  
Author(s):  
Kyung Taek Cho ◽  
Sanghyun Paek ◽  
Giulia Grancini ◽  
Cristina Roldán-Carmona ◽  
Peng Gao ◽  
...  

We demonstrate reduced charge recombination by formation of an engineered passivating layer, which leads to an enhanced power conversion efficiency of 21%.


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