scholarly journals STUDY OF THE STRUCTURE OF HIGHLY FILLED FLUOROPLAST-ALUMINUM COMPOSITES

Author(s):  
N. A. Adamenko ◽  
A. V. Kazurov ◽  
D. V. Savin ◽  
G. V. Agafonova ◽  
A. S. Ageikin

Structure formation in fluoroplastic-aluminum composites obtained by static and explosive pressing has been investigated. The concentration of dispersed aluminum was 50 and 70% vol. In fluoroplastic-aluminum composites, after static pressing, spalling of metal particles, formed during the preparation of a microsection, was found, which indicates low adhesion of the polymer and metal. The production of fluoroplastic-aluminum composites using explosive pressing leads to the formation of a monolithic material with a high adhesive interaction of the components and the formation of a metal frame.

2021 ◽  
pp. 26-32
Author(s):  
Nina Adamenko ◽  
Andrej Kazurov ◽  
Dmitry Savin ◽  
Galina Agafonova ◽  

The features of the structure formation in polytetrafluoroethylene filled with 10 and 30% (vol.) aluminum after static and explosive pressing have been studied. It was revealed that after static pressing during sintering, interphase separation occured, which is confirmed by the formation of structures of the «closed buds» type. After explosive pressing with sintering, fibrils between polytetrafluoroethylene and aluminum and a polymer layer covering metal particles were found, and there was no interfacial separation that indicates the formation of a strong adhesive bond and is confirmed by the formation of aluminum fluoride.


Author(s):  
N. Adamenko ◽  
A. Kazurov ◽  
D. Savin ◽  
G. Agafonova

The structure formation in fluoroplastic-aluminum composite materials during sintering after static pressing was studied. The concentration of dispersed aluminum was 30% vol.. After sintering, interfacial separation was observed in the fluoroplastic-aluminum composite materials, which is formed during crystallization due to shrinkage, which indicates a low adhesion of the filler to the polymer. Sintering of composite materials in a closed volume leads to the formation of a material with a lower porosity than when sintering in a free volume.


Author(s):  
N. A. Adamenko ◽  
G. V. Agafonova ◽  
D. A. An ◽  
A. V. Kazurov ◽  
V. S. Pirozhenko

To develop the technology of explosive pressing of ultrahigh molecular weight polyethylene (UHMWPE) and its powder composite mixtures with inorganic fillers, the thermomechanical properties of an unfilled polymer and a composite containing 3% coke graphite powder (KGP) after explosive pressing were studied. It was found that explosive pressing with a pressure of 0.25-1.3 gpa provides high heat resistance of UHMWPE and the studied composite (154-156 °C), and the filler restrains the thermal deformation expansion of the polymer, which is associated with increased intermolecular and adhesive interaction at the phase boundary. Thus, the method of explosive pressing can be recommended for industrial processing of UHMWPE and its composite mixture with 3 % KGP.


Author(s):  
N. A. Adamenko ◽  
G. V. Agafonova ◽  
D. A. An ◽  
A. V. Kazurov ◽  
V. S. Pirozhenko

The paper presents comparative studies of the thermomechanical properties of ultra-high molecular weight polyethylene (UHMWPE) and its composite containing 0.5% coke-graphite powder (CGP). It was found that explosive pressing with a pressure of 0.25-0.6 GPa provides high heat resistance of UHMWPE and the investigated composite (154-156 ° C). The heat resistance of the composite decreases to 143-145 ° C, but it is higher than that of a similar material after static pressing (128 ° C).


2013 ◽  
Vol 2013.51 (0) ◽  
pp. _311-1_-_311-2_
Author(s):  
Gen SASAKI ◽  
Moon Hee LEE ◽  
Kenjiro SUGIO ◽  
Yong Bum CHOI ◽  
Kazuhiro MATSUGI

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