scholarly journals Low-temperature synthesis of carbon nanotubes on indium tin oxide electrodes for organic solar cells

2012 ◽  
Vol 3 ◽  
pp. 524-532 ◽  
Author(s):  
Andrea Capasso ◽  
Luigi Salamandra ◽  
Aldo Di Carlo ◽  
John Marcus Bell ◽  
Nunzio Motta

The electrical performance of indium tin oxide (ITO) coated glass was improved by including a controlled layer of carbon nanotubes directly on top of the ITO film. Multiwall carbon nanotubes (MWCNTs) were synthesized by chemical vapor deposition, using ultrathin Fe layers as catalyst. The process parameters (temperature, gas flow and duration) were carefully refined to obtain the appropriate size and density of MWCNTs with a minimum decrease of the light harvesting in the cell. When used as anodes for organic solar cells based on poly(3-hexylthiophene) (P3HT) and phenyl-C61-butyric acid methyl ester (PCBM), the MWCNT-enhanced electrodes are found to improve the charge-carrier extraction from the photoactive blend, thanks to the additional percolation paths provided by the CNTs. The work function of as-modified ITO surfaces was measured by the Kelvin probe method to be 4.95 eV, resulting in an improved matching to the highest occupied molecular orbital level of the P3HT. This is in turn expected to increase the hole transport and collection at the anode, contributing to the significant increase of current density and open-circuit voltage observed in test cells created with such MWCNT-enhanced electrodes.

2012 ◽  
Vol 211 ◽  
pp. 33-36 ◽  
Author(s):  
Han-Ki Kim ◽  
In-Kyu You ◽  
Jae Bon Koo ◽  
Sung-Ho Kim

2014 ◽  
Vol 4 (7) ◽  
pp. 1301566 ◽  
Author(s):  
Hyunah Kwon ◽  
Juyoung Ham ◽  
Dong Yeong Kim ◽  
Seung Jae Oh ◽  
Subin Lee ◽  
...  

2017 ◽  
Vol 2 (15) ◽  
pp. 4230-4233
Author(s):  
Ganbaatar Tumen‐Ulzii ◽  
Delgerjargal Altantsetseg ◽  
Nyamjargal Ochirkhuyag ◽  
Delgertsetseg Byambasuren ◽  
Masaru Sakomura ◽  
...  

2016 ◽  
Vol 616 ◽  
pp. 419-424 ◽  
Author(s):  
Tina Wahl ◽  
Sabrina Zellmer ◽  
Jonas Hanisch ◽  
Georg Garnweitner ◽  
Erik Ahlswede

2014 ◽  
Vol 32 (5) ◽  
pp. 051507 ◽  
Author(s):  
Hyo-Joong Kim ◽  
Ki-Won Seo ◽  
Han-Ki Kim ◽  
Yong-Jin Noh ◽  
Seok-In Na

Molecules ◽  
2021 ◽  
Vol 26 (3) ◽  
pp. 763
Author(s):  
Elisa Lassi ◽  
Benedetta Maria Squeo ◽  
Roberto Sorrentino ◽  
Guido Scavia ◽  
Simona Mrakic-Sposta ◽  
...  

Conjugated polymers with ionic pendant groups (CPEs) are receiving increasing attention as solution-processed interfacial materials for organic solar cells (OSCs). Various anionic CPEs have been successfully used, on top of ITO (Indium Tin Oxide) electrodes, as solution-processed anode interlayers (AILs) for conventional devices with direct geometry. However, the development of CPE AILs for OSC devices with inverted geometry is an important topic that still needs to be addressed. Here, we have designed three anionic CPEs bearing alkyl-potassium-sulfonate side chains. Their functional behavior as anode interlayers has been investigated in P3HT:PC61BM (poly(3-hexylthiophene): [6,6]-phenyl C61 butyric acid methyl ester) devices with an inverted geometry, using a hole collecting silver electrode evaporated on top. Our results reveal that to obtain effective anode modification, the CPEs’ conjugated backbone has to be tailored to grant self-doping and to have a good energy-level match with the photoactive layer. Furthermore, the sulfonate moieties not only ensure the solubility in polar orthogonal solvents, induce self-doping via a right choice of the conjugated backbone, but also play a role in the gaining of hole selectivity of the top silver electrode.


2019 ◽  
Vol 28 (1) ◽  
pp. 66-73
Author(s):  
Ismail Borazan ◽  
Ayşe Celik Bedeloğlu ◽  
Ali Demir

In this article, the improvement in electrical performance of poly(3,4-ethylenedioxythiophene)–poly(styrenesulfonate) (PEDOT:PSS) as the transparent electrode doped with different additives (ethylene glycol (EG), isopropyl alcohol) or treatment of sulfuric acid was enhanced that organic solar cells (OSCs) were produced by using poly(3-hexylthiophene-2,5-diyl):[6,6]-phenyl C61 butyric acid methyl ester. OSCs were fabricated by the doped or treated PEDOT:PSS films as transparent electrodes. The photoelectrical measurements were carried out and the effects of doping or treatment were compared. As a result, EG-added PEDOT:PSS electrode showed the best power conversion efficiency value of 1.87% among the PEDOT:PSS anodes.


2012 ◽  
Vol 209-211 ◽  
pp. 1719-1722
Author(s):  
Ming Guo Zhang ◽  
Nan Hai Sun

A thin Ag layer embedded between layers of zinc tin oxide (ZTO) are compared to cells using an indium tin oxide electrode was investigated for inverted organic bulk heterojunction solar cells employing a multilayer electrode. ZTO/Ag/ ZTO (ZAZ) electrode is the preparation at room temperature, a high transparency in the visible part of the spectrum, and a very low sheet resistance comparable to treated ITO without the need for any thermal post deposition treatment as it is necessary for ITO. The In-free ZAZ electrodes exhibit a favorable work function of 4.3 eV and are shown to allow for excellent electron extraction even without a further interlayer. This renders ZAZ a perfectly suited bottom electrode for inverted organic solar cells with simplified cell architecture.


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