Ag Doped Zinc Tin Oxide as Cathode for Organic Photovoltaic Cells

2012 ◽  
Vol 209-211 ◽  
pp. 1719-1722
Author(s):  
Ming Guo Zhang ◽  
Nan Hai Sun

A thin Ag layer embedded between layers of zinc tin oxide (ZTO) are compared to cells using an indium tin oxide electrode was investigated for inverted organic bulk heterojunction solar cells employing a multilayer electrode. ZTO/Ag/ ZTO (ZAZ) electrode is the preparation at room temperature, a high transparency in the visible part of the spectrum, and a very low sheet resistance comparable to treated ITO without the need for any thermal post deposition treatment as it is necessary for ITO. The In-free ZAZ electrodes exhibit a favorable work function of 4.3 eV and are shown to allow for excellent electron extraction even without a further interlayer. This renders ZAZ a perfectly suited bottom electrode for inverted organic solar cells with simplified cell architecture.

2013 ◽  
Vol 1 ◽  
pp. 194308921350702 ◽  
Author(s):  
Priya A. Hoskeri ◽  
Gayathri A. G. ◽  
Ayachit N. H. ◽  
Joseph C. M.

Perylene 3,4,9,10-tetra carboxylic dianhydride (PTCDA) thin films find a lot of optoelectronic applications. In this work, thin films of PTCDA were deposited using vacuum evaporation technique onto clean glass substrates and the variation in conductivity, optical bandgap and percentage transmission due to iodine doping for different time intervals are discussed. To study the doping effects on devices, organic solar cells based on cobalt phthalocyanine (CoPc)/PTCDA as active layers on indium tin oxide–coated glass substrates were fabricated and characterized to evaluate the solar cell parameters. It was found that doping with iodine considerably increases the power conversion efficiency of the solar cells.


2014 ◽  
Vol 4 (7) ◽  
pp. 1301566 ◽  
Author(s):  
Hyunah Kwon ◽  
Juyoung Ham ◽  
Dong Yeong Kim ◽  
Seung Jae Oh ◽  
Subin Lee ◽  
...  

2010 ◽  
Vol 1270 ◽  
Author(s):  
A.A. Damitha T Adikaari ◽  
Joe Briscoe ◽  
Steve Dunn ◽  
David Carey ◽  
Ravi Silva

AbstractWe present a performance comparison of polythiophene/fullerene derivative bulk heterojunction solar cells fabricated on fluorinated tin oxide (FTO) and indium tin oxide (ITO) in the presence and absence of the commonly used poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOT:PSS) hole extraction layer. From a potential commercial perspective the performance of cheaper and more readily available FTO compares well with the more expensive ITO in terms of measured device efficiency (FTO:2.8 % and ITO:3.1%). The devices show similar fill factors (FTO:63% and ITO:64%) with the same open circuit voltage of 0.6 V. The short circuit current density is lower for FTO devices at 7.5 mA/cm2 which compares with 8.0 mA/cm2 for ITO; a behaviour that is mainly attributed to the reduced optical transmission of the FTO layer. Importantly, these devices were part fabricated and wholly characterized under atmospheric conditions. The quoted device performance is the best reported for FTO based bulk heterojunction systems in the absence of the highly acidic PEDOT:PSS hole extraction layer, which is believed to degrade conductive oxides.


2014 ◽  
Vol 2 (41) ◽  
pp. 8715-8722 ◽  
Author(s):  
Chunmei Zhang ◽  
Lei Qi ◽  
Qiang Chen ◽  
Longfeng Lv ◽  
Yu Ning ◽  
...  

With Ar plasma treatment of the indium tin oxide (ITO) cathode, we achieve efficient inverted bulk heterojunction solar cells based on poly(3-hexylthiophene):[6,6]-phenyl C61butyric acid methyl ester, which do not require electron selective layer.


2008 ◽  
Vol 1091 ◽  
Author(s):  
Daniel Tobjork ◽  
Harri Aarnio ◽  
Tapio Mäkelä ◽  
Ronald Österbacka

AbstractThe roll-to-roll reverse gravure (RG) coating technique was used to produce thin homogeneous films (∼100 nm) for organic bulk heterojunction solar cells. The conducting polymer poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) and the active layer regioregular poly(3-hexylthiophene-2,5-diyl):[6,6]-phenyl-C61-butyric acid methyl ester (P3HT:PCBM) were successfully subsequently RG coated on an ITO covered plastic substrate in ambient air. Working solar cells were achieved after annealing and thermal evaporation of the top contact. The AM1.5 power conversion efficiency (PCE) of the RG coated organic solar cells was determined to 0.74% (at 100 mW/cm2). This was very similar to the results of a reference device that was spin coated on a glass substrate in a nitrogen glove box.


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