scholarly journals COMPARISON OF THREE TREE‐RING SAMPLING METHODS FOR TRACE METAL ANALYSIS

2010 ◽  
Vol 18 (3) ◽  
pp. 170-178 ◽  
Author(s):  
Edita Baltrėnaitė ◽  
Donatas Butkus ◽  
Colin A. Booth

Tree‐ring growth analysis can provide information about tree development for forest inventory, environmental assessment, atmospheric and soil monitoring. Metal concentrations in wood increment correlate with metal concentrations in the environment and can indicate local environmental contamination sources. One of the most important steps of tree analysis is tree‐ring sampling. To determine trace metal (TM) concentrations precisely in a separate ring, the possibility of random errors during wood sampling must be eliminated. This guides to choose a precise tree‐ring sampling method. This paper examines three tree‐ring sampling tools (common chisels, arched chisels and a plane) and compares TM concentrations (Mn, Zn, Ni, Cr, Cu, Pb,) in wood samples collected by each of the methods employed. Average values of metals in tree rings sampled with common chisels, arched chisels and plane were 17.0±0.16 mg/kg for Mn, 4.7±0.21 mg/kg for Zn, 0.49±0.20 mg/kg for Pb, 0.29±0.02 mg/kg for Cu, 0.21±0.02 mg/kg for Ni and 0.12±0.01 mg/kg for Cr and were in the range of typical concentrations in investigated region as well as for Pinus sylvestris L. The average values were calculated for the three methods used. Statistical analysis (Anderson–Darlin test, Kruskal–Wallis tests, median and percentage coefficient of variation) revealed no significant differences between metal concentrations determined in tree rings which were sampled using common chisels, arched chisels and planing. Various techniques – common chisels, arched chisels and plane – can be successfully used for tree‐ring sampling, however, an increment borer provides possibility of sampling a non‐felled tree. Santrauka Medienos metiniu rieviu analize suteikia informacijos apie medžio vystymasi, svarbios inventorizuojant miškus, vertinant aplinkos poveiki, atliekant aplinkos oro ir dirvožemio monitoringa. Sunkiuju metalu koncentracijos metinese rievese susijusios su metalu koncentracijomis aplinkoje ir gali nusakyti vietines aplinkos taršos lygi. Vienas iš svarbiu medienos analizes etapu yra metiniu rieviu eminiu emimas. Siekiant tiksliai nustatyti sunkiuju metalu koncentracija metineje rieveje svarbu išvengti atsitiktiniu paklaidu. Šiame darbe aptariami trys metiniu rieviu eminiu emimo metodai (iprastiniai kaltai, lenktieji kaltai ir obliavimas) ir lyginamos pagrindiniu sunkiuju metalu (Mn, Zn, Ni, Cu, Cr, Pb) koncentracijos eminiuose, paimtuose kiekvienu iš minetuju metodu. Vidutines sunkiuju metalu koncentracijos, nustatytos šiais metodais, sieke 17,0±0,16 mg/kg Mn, 4,7±0,21 mg/kg Zn, 0,49±0,20 mg/kg Pb, 0,29±0,02 mg/kg Cu, 0,21±0,02 mg/kg Ni ir 0,12±0,01 mg/kg Cr ir buvo panašios i koncentracijas, aptiktas Pinus sylvestris L. medienoje nagrinejamoje teritorijoje. Apskaičiuotos vidutines vertes. Atlikus statistine analize (Anderson ir Darlin testas, Kruskal ir Wallis testas, variacijos koeficientas) tebuvo tik nereikšmingas sunkiuju metalu koncentraciju metinese rievese skirtumas, eminius emus aptartais metodais. Ivairūs metodai – iprastiniai kaltai, lenktieji kaltai ir obliavimas – gali būti sekmingai taikomi metiniu rieviu eminiams imti, tačiau “amžiaus” gražtu eminius galima imti nenukertant medžio. Резюме Анализ годичных колец древесины предоставляет информацию о развитии дерева, что важно для инвентaризации леса, оценки воздействия на окружающую среду и мониторинга воздуха и почвы. Концентрации тяжелых металлов в годичных кольцах древесины зависят от их концентрации в окружающей среде и могут свидетельствовать об уровне загрязнения местности. Одним из важных этапов анализа древесины является взятие проб годичных колец. Для точного определения концентрации тяжелых металлов в годичных кольцах древесины важно избежать случайных погрешностей. В статье анализируются три метода взятия проб годичных колец древесины (дробление обычным долотом, круглым долотом и строгание) и сравниваются концентрации основных тяжелых металлов (Mn, Zn, Ni, Cu, Cr, Pb) в пробах, взятых каждым из названных методов. Средние концентрации тяжелых металлов при их измерении указанными методами достигали 1,695±0,161 мг/кг для Mn, 0,471±0,206 мг/кг для Zn, 0,487±0,202 мг/кг для Pb, 0,290±0,021 мг/кг для Cu, 0,210±0,023 мг/кг для Ni и 0,117±0,010 мг/кг для Cr. Эти концентрации тяжелых металлов аналогичны концентрациям в древесине сосны (Pinus sylvestris L) на данной исследуемой территории. При помощи статистического анализа [тест Андерсона–Дарлина (Anderson–Darlin), тест Крускаля–Валиса (Kruskal–Wallis), коэффициент вариации] выявлена лишь незначительная разница между концентрациями тяжелых металлов в годичных кольцах древесины, взятых уже названными методами. Методы дробления обычным долотом, круглым долотом и строгания могут успешно применяться для взятия проб годичных колец древесины, однако сверло „века“ предоставляет возможность взятия пробы без спиливания дерева.

Radiocarbon ◽  
2020 ◽  
pp. 1-10
Author(s):  
Marek Krąpiec ◽  
Andrzej Rakowski ◽  
Jacek Pawlyta ◽  
Damian Wiktorowski ◽  
Monika Bolka

ABSTRACT Radiocarbon (14C) analyses are commonly used to determine the absolute age of floating tree-ring chronologies. At best, with the wiggle-matching method, a precision of 10 years could be achieved. For the early Middle Ages, this situation has been markedly improved by the discovery of rapid changes in atmospheric 14C concentrations in tree-rings dated to 774/775 and 993/994 AD. These high-resolution changes can be used to secure other floating tree-ring sequences to within 1-year accuracy. While a number of studies have used the 774 even to secure floating tree-ring sequences, the less abrupt 993 event has not been so well utilized. This study dates a floating pine chronology from Ujście in Wielkopolska (Greater Poland) (NW Poland), which covers the 10th century period and is critical for studies on the beginning of the Polish State to the calendar years 859–1085 AD using the changes in single year radiocarbon around 993/4 AD.


2008 ◽  
Vol 13 (6) ◽  
pp. 347-356 ◽  
Author(s):  
Peter Kirchner ◽  
Franco Biondi ◽  
Ross Edwards ◽  
Joseph R. McConnell

2017 ◽  
Vol 44 (1) ◽  
pp. 240-255 ◽  
Author(s):  
Barbara Sensuła ◽  
Sławomir Wilczyński

Abstract The main aims of these studies were dendrochronological and mass spectrometric analysis of the impact of climate on tree rings width and stable isotopes composition in pine (Pinus sylvestris L.). The conifers were growing in the vicinity of chemical and nitrogen factories in Kędzierzyn-Koźle (Poland) in the period of time from 1920s to 2012 AD. The combined usage of tree ring width and isotopic composition data provides historic records of the environment changes. These data allows identifying the behavior adaptation of pine growing under pollution stress to climate changes. The incremental rhythm of the studied pine populations was not identical, probably due to their different sensitivities to some climatic factors. This study evidences that the isotopic records in tree-rings α-cellulose may be sensitive bio-indicators of the way that the components of air and water may be changed by the trees in response to the climate changes and anthropogenic effects. The water use efficiency may be strongly correlated with variability of the surface temperature that may be due to increase of CO2 emission.


1993 ◽  
Vol 28 (1) ◽  
pp. 83-110 ◽  
Author(s):  
Richard E. Farrell ◽  
Jae E. Yang ◽  
P. Ming Huang ◽  
Wen K. Liaw

Abstract Porewater samples from the upper Qu’Appelle River basin in Saskatchewan, Canada, were analyzed to obtain metal, inorganic ligand and amino add profiles. These data were used to compute the aqueous speciation of the metals in each porewater using the computer program GEOCHEM-PC. The porewaters were classified as slightly to moderately saline. Metal concentrations reflected both the geology of the drainage basin and the impact of anthropogenic activities. Whereas K and Na were present almost entirely as the free aquo ions, carbonate equilibria dominated the speciation of Ca. Mg and Mn (the predominant metal ligand species were of the type MCO3 (s). MCO30. and MHCO3+). Trace metal concentrations were generally within the ranges reported for non-polluted freshwater systems. Whereas the speciation of the trace metals Cr(III) and Co(II) was dominated by carbonate equilibria, Hg(II)-, Zn(II)- and Fe(II)-speciation was dominated by hydroxy-metal complexes of the type M(OH)+ and M(OH)2°. The speciation of Fe(III) was dominated by Fe(OH)3 (s). In porewaters with high chloride concentrations (> 2 mM), however, significant amounts of Hg(II) were bound as HgCl20 and HgClOH0. The aqueous speciation of Al was dominated by Al(OH)4− and Al2Si2O4(OH)6 (s). Total concentrations of dissolved free amino acids varied from 15.21 to 25.17 umole L−1. The most important metal scavenging amino acids were histidine (due to high stability constants for the metal-histidine complexes) and tryptophan (due to its relatively high concentration in the porewaters. i.e., 5.96 to 7.73 umole L−1). Secondary concentrations of various trace metal-amino add complexes were computed for all the porewaters, but metal-amino acid complexes dominated the speciation of Cu(II) in all the porewaters and Ni(II) in two of the porewaters.


2019 ◽  
Author(s):  
Alexandra Almaguer ◽  
◽  
Hilary Sanders Lackey ◽  
Kyle R. McCarty ◽  
Jade Star Lackey

2020 ◽  
Author(s):  
Christopher Mills ◽  
◽  
David C. Smith ◽  
Craig A. Stricker ◽  
John G. Schumacher ◽  
...  

2020 ◽  
Author(s):  
Moread Achek ◽  
◽  
E. Christa Farmer ◽  
Brandon Buchbinder ◽  
Joyce Bowen ◽  
...  

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