scholarly journals Electron Transfer Reactions. III. The Application of Derivative Cyclic Voltammetry for the Determination of Rate Constants and alpha Values for Heterogeneous Electron Transfer Processes: the Reduction of Organic Anions.

1992 ◽  
Vol 46 ◽  
pp. 563-573 ◽  
Author(s):  
Haijiang Wang ◽  
Ole Hammerich ◽  
C. Rømming ◽  
E. Røst ◽  
Agha Zul-Quarnain Khan ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Cyclic Voltammetry ◽  
Rate Constants ◽  
Organic Anions ◽  
Transfer Reactions ◽  
Electron Transfer Reactions ◽  
Transfer Processes ◽  
Heterogeneous Electron Transfer ◽  
Electron Transfer Processes

Review Lecture - Electron transfer reactions and living polymers

1964 ◽  
Vol 279 (1377) ◽  
pp. 260-290 ◽  
Keyword(s):  
Electron Transfer ◽  
Transfer Reactions ◽  
Radical Ions ◽  
Electron Transfer Reactions ◽  
Transfer Processes ◽  
Electron Transfer Processes ◽  
Living Polymers

I propose to review here two aspects of our work concerned with the chemistry of radical-ions, electron-transfer processes and living polymers. The last topic will be described first (§§ 1 to 5) and the remaining part of the paper (§§ 6 to 9 ) will be devoted to problems of electron-transfer processes involving stable and labile radical-ions and to the discussion of some intermediates formed in these reactions.

Bimolecular photoinduced electron transfer reactions in liquids under the gaze of ultrafast spectroscopy

2014 ◽  
Vol 16 (47) ◽  
pp. 25741-25754 ◽  
Author(s):  
Arnulf Rosspeintner ◽  
Eric Vauthey
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Ultrafast Spectroscopy ◽  
Recent Progress ◽  
Transfer Reactions ◽  
Electron Transfer Reactions ◽  
The Gaze ◽  
Transfer Processes ◽  
Electron Transfer Processes

This perspective highlights the recent progress in our understanding of bimolecular photoinduced electron transfer processes that could be achieved thanks to ultrafast spectroscopy.

A novel samarium(ii) complex bearing a dianionic bis(phenolate) cyclam ligand: synthesis, structure and electron-transfer reactions

2016 ◽  
Vol 45 (9) ◽  
pp. 3778-3790 ◽  
Author(s):  
Leonor Maria ◽  
Marina Soares ◽  
Isabel C. Santos ◽  
Vânia R. Sousa ◽  
Elsa Mora ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Single Electron ◽  
Transfer Reactions ◽  
Single Electron Transfer ◽  
Electron Transfer Reactions ◽  
Transfer Processes ◽  
Highly Effective ◽  
Samarium Complex ◽  
Ligand Synthesis ◽  
Electron Transfer Processes

A novel divalent samarium complex anchored on a dianionic bis(phenolate) ligand is reported and reactivity studies demonstrate that it is highly effective in inducing single-electron transfer processes.

scholarly journals Catalytic control of electron-transfer processes

2003 ◽  
Vol 75 (5) ◽  
pp. 577-587 ◽  
Author(s):  
Shunichi Fukuzumi
Keyword(s):  
Electron Transfer ◽  
Metal Ions ◽  
Metal Ion ◽  
Photochemical Reactions ◽  
Transfer Reactions ◽  
Intramolecular Electron Transfer ◽  
Radical Anions ◽  
Electron Transfer Reactions ◽  
Transfer Processes ◽  
Electron Transfer Processes

Catalytic control of electron-transfer processes is described for a number of photoinduced and thermal electron-transfer reactions, including back electron transfer in the charge-separated state of artificial photosynthetic compounds. The intermolecular and intramolecular electron-transfer processes are accelerated by complexation of radical anions, produced in the electron transfer, with metal ions that act as Lewis acids. Quantitative measures to determine the Lewis acidity of a variety of metal ions are given in relation with the promoting effects of metal ions in the electron-transfer reactions. The mechanistic viability of metal ion catalysis in electron-transfer reactions is demonstrated by a variety of examples of both thermal and photochemical reactions that involve metal ion-promoted electron-transfer processes as the rate-determining steps, which are made possible to proceed by complexation of radical anions with metal ions.

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