scholarly journals Mathematical modeling of thermal processes during "cassette" crystallization of chalcogenides

2020 ◽  
Vol 6 (1) ◽  
pp. 9-16
Author(s):  
Anatoly I. Prostomolotov ◽  
Nataliya A. Verezub

A new, relatively simple and highly efficient modification of the directional melt crystallization method in the form of a multi-cassette process has been considered. This study is based on Russian Patents and technological studies conducted at National Research and Technological University MISiS. As a result, mathematical models of a multi-cassette method have been developed for 3D radiation and conduction analysis of thermal processes in the entire volume of the heating unit and 2D analysis of convection and conduction heat exchange in a separate cassette. Parameters have been calculated on the basis of these mathematical models for clarifying the effect of heating unit component arrangement and dimensions on the formation of thermal fields in cassette units, the effect of vertical homogeneity of heat supply to the cassette unit and heating power reduction rate during crystallization on the shape of the crystallization front, as well as the effect of small asymmetry in cassette design and violation of cassette bottom cooling homogeneity on convection and asymmetrical heat transfer. Application of the conductive and radiative heat exchange model to the entire heating unit has allowed us to calculate process parameters on the basis of which we have analyzed the effect of heating unit components, their arrangement and temperature on the heat exchange conditions at the cassette unit boundaries. Application of the convective and conductive model to one growth cassette has shown that asymmetrical design and boundary thermal conditions as well as unstable vertical temperature gradient lead to the formation of convection vortices and substantial crystallization front deviation from planar shape. Calculations on the basis of the convective mass exchange model have shown that an increase in the crystallization rate by one order of magnitude greatly increases the tellurium flow into the crystal thus substantially altering the melt composition in the vicinity of the crystallization front and hence serving as a potential origin of dendrite growth. The authenticity of the calculation results has been verified in a number of tests aimed at analyzing the effect of heat and mass transport on crystallization front shape for cassette cooling rates that are typical of polycrystalline bismuth telluride growth processes.

2012 ◽  
Vol 44 (3) ◽  
pp. 281-286
Author(s):  
A.V. Aleksandrov ◽  
V.V. Aleksandrov

This article deals with the use of computer modeling to develop technical solutions to ensure better quality of alumina-containing sinter. The simulation accounted for the influence of the feed materials on the thermal processes in the furnace. The energy balance (including thermal conductivity, heat convection and radiant heat exchange) was solved assuming steady state. A good correlation was observed for the actual and calculated temperatures of the solids and gases, with less than 15% discrepancy. Using the model of the furnace investigated the possibility of lowering the temperature of sintering by removing heat from the outside of the furnace shell. To reduce the sintering temperature to 1000 ?C length of the refractory lined steel is 5 m, the height of the lining should not exceed - 0.06 m, the required rate of cold water - 54.7 m3/h


2019 ◽  
Vol 5 (3) ◽  
pp. 91-100
Author(s):  
Vladimir S. Berdnikov

This work is a brief overview of experimental study results for hydrodynamics and convective heat exchange in thermal gravity capillary convection modes for the classic Czochralski technique setup obtained at the Institute of Thermophysics, Siberian Branch of the Russian Academy of Sciences. The experiments have been carried out at test benches which simulated the physics of the Czochralski technique for 80 and 295 mm diameter crucibles. Melt simulating fluids with Prandtl numbers Pr = 0.05, 16, 45.6 and 2700 have been used. Experiments with transparent fluids have been used for comparing the evolution of flow structure from laminar mode to well-developed turbulent mode. Advanced visualization and measurement methods have been used. The regularities of local and integral convective heat exchange in the crucible/melt/crystal system have been studied. The experiments have shown that there are threshold Grashof and Marangoni numbers at which the structure of the thermal gravity capillary flow undergoes qualitative changes and hence the regularities of heat exchange in the melt change. The effect of melt hydrodynamics on the crystallization front shape has been studied for Pr = 45.6. Crystallization front shapes have been determined for the 1 × 105 to 1.9 × 105 range of Grashof numbers. We show that the crystallization front shape depends largely on the spatial flow pattern and the temperature distribution in the melt.


2020 ◽  
Vol 172 ◽  
pp. 24003
Author(s):  
Arkadiusz Witek ◽  
Barbara Pietruszka

Calculation of the heat flow through the air cavities in the EN ISO 10077-2:2017 standard for the determination of the thermal transmittance of window profiles uses models based on the equivalent thermal conductivity method. The method takes into account the radiative heat exchange in a simplified or accurate manner. In the first case, the heat exchange depends on the average temperature in cavity, in the second case - it is determined accurately by the ray tracing method. It is also of importance to differentiate emissivity of surfaces due to aging or painting what influences calculation time. In this work, the impact of the calculation method and the impact of simplifications in modelling of the untreated surfaces on the value of the thermal transmittance of aluminium profiles was analysed on the example of a real series of products. Comparing the simplified and accurate method of determining the radiation exchange in cavities, the differences in the thermal transmittances of window profiles were up to 22%. The differences between the most simplified and the most accurate modelling of the surfaces emissivity reached 23%.


2019 ◽  
Vol 11 (15) ◽  
pp. 4166 ◽  
Author(s):  
Liu ◽  
Zhu ◽  
Kim ◽  
Srebric

Computational fluid dynamics (CFD) is an effective analysis method of personalized ventilation (PV) in indoor built environments. As an increasingly important supplement to experimental and theoretical methods, the quality of CFD simulations must be maintained through an adequately controlled numerical modeling process. CFD numerical data can explain PV performance in terms of inhaled air quality, occupants’ thermal comfort, and building energy savings. Therefore, this paper presents state-of-the-art CFD analyses of PV systems in indoor built environments. The results emphasize the importance of accurate thermal boundary conditions for computational thermal manikins (CTMs) to properly analyze the heat exchange between human body and the microenvironment, including both convective and radiative heat exchange. CFD modeling performance is examined in terms of effectiveness of computational grids, convergence criteria, and validation methods. Additionally, indices of PV performance are suggested as system-performance evaluation criteria. A specific utilization of realistic PV air supply diffuser configurations remains a challenging task for further study. Overall, the adaptable airflow characteristics of a PV air supply provide an opportunity to achieve better thermal comfort with lower energy use based on CFD numerical analyses.


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