scholarly journals Efficient removal of bisphenol A from wastewaters: Catalytic wet air oxidation with Pt catalysts supported on Ce and Ce–Ti mixed oxides

2019 ◽  
Vol 6 (1) ◽  
pp. 25-44
Author(s):  
Anne Heponiemi ◽  
◽  
Said Azalim ◽  
Tao Hu ◽  
Tuomas Vielma ◽  
...  



2006 ◽  
Vol 45 ◽  
pp. 2089-2095
Author(s):  
Jana Mikulová ◽  
Sylvie Rossignol ◽  
Jacques Barbier Jr. ◽  
Charles Kappenstein ◽  
Daniel Duprez

Sol-gel Zr0.1Ce0.9O2 and Zr0.1(Ce0.75Pr0.25)O2 mixed oxides and coprecipitated pure ceria CeO2 displaying the fluorine type structure have been used as platinum or ruthenium catalysts’ supports for catalytic wet air oxidation (CWAO) of aqueous solution of acetic acid (78 mmol.L-1). These catalysts were prepared by conventional impregnation (5 wt-%) from platinum and ruthenium precursor salts or by exchange (~2 wt-%) in the case of ruthenium. A screening of catalysts in CWAO at 200°C under 2 MPa was performed and reveals that the best platinum catalyst is supported on pure ceria displaying large surface. For ruthenium catalysts, the highest conversion after 3 hours of reaction has been reached by the Ru/Zr-Ce-O system.







Catalysts ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 1053 ◽  
Author(s):  
Katherine Archila ◽  
Ana María Campos ◽  
Lorena Lugo ◽  
Crispín Astolfo Celis ◽  
Sonia Moreno ◽  
...  

The catalytic oxidation of aqueous crystal violet (CV) solutions was investigated using Ni and Fe catalysts supported over Mg–Al oxides synthesized by the autocombustion method. The influence of temperature, loading, and selectivity were studied in the catalytic wet air oxidation (CWAO) of CV. The kind of metal had an important contribution in the redox process as significant differences were observed between Fe, Ni, and their mixtures. The catalysts with only Fe as active phase were more efficient for the oxidation of CV under normal conditions (T = 25 °C and atmospheric pressure) compared to those containing Ni, revealing the influence of the transition metal on catalytic properties. It was found that iron-containing materials displayed enhanced textural properties. The synthesis of Fe/MgAl catalysts by the autocombustion method led to solids with excellent catalytic behavior, 100% CV degradation in eight hours of reaction, 68% selectivity to CO2, and significant reduction of chemical oxygen demand (COD).



2020 ◽  
Vol 761 ◽  
pp. 138022 ◽  
Author(s):  
Rahma Bensouilah ◽  
Tijani Hammedi ◽  
AdbelKader Ouakouak ◽  
Abdelhamid Ghorbel ◽  
Zouhaier Ksibi


2019 ◽  
Vol 41 (25) ◽  
pp. 3272-3283 ◽  
Author(s):  
Buddhika Rathnayake ◽  
Anne Heponiemi ◽  
Marjo Huovinen ◽  
Satu Ojala ◽  
Minna Pirilä ◽  
...  




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