scholarly journals Low Salinity Water Injection with Sidr Surfactant to Recover Crude Oil from Sandstone/Carbonate Reservoir (EOR)

Author(s):  
H.A.G. Ahmed
2020 ◽  
Vol 10 (2) ◽  
pp. 17-26
Author(s):  
Gustavo Maya Toro ◽  
Luisana Cardona Rojas ◽  
Mayra Fernanda Rueda Pelayo ◽  
Farid B. Cortes Correa

Low salinity water injection has been frequently studied as an enhanced oil recovery process (EOR), mainly due to promising experimental results and because operational needs are not very different from those of the conventional water injection. However, there is no agreement on the mechanisms involved in increasing the displacement of crude oil, except for the effects of wettability changes. Water injection is the oil recovery method mostly used, and considering the characteristics of Colombian oil fields, this study analyses the effect of modifying the ionic composition of the waters involved in the process, starting from the concept of ionic strength (IS) in sandstone type rocks. The experimental plan for this research includes the evaluation of spontaneous imbibition (SI), contact angles, and displacement efficiencies in Berea core plugs. Interfacial tension and pH measurements were also carried out. The initial scenario consists in formation water (FW), with a total concentration of 9,800 ppm (TDS) (IS ~ 0.17) and a 27 °API crude oil. Magnesium and Calcium brine were also used in a first approach to assess the effect of the divalent ions. Displacement efficiency tests are performed using IS of 0.17, 0.08, and 0.05, as secondary and tertiary oil recovery and the recovery of oil increases in both scenarios. Spontaneous imbibition curves and contact angle measurements show variations as a function of the ionic strength, validating the displacement efficiencies. Interfacial tension and pH collected data evidence that fluid/fluid interactions occur due to ionic strength modifications. However, as per the conditions of this research, fluid/fluid mechanisms are not as determining as fluid/rock.


SPE Journal ◽  
2019 ◽  
Vol 24 (06) ◽  
pp. 2859-2873 ◽  
Author(s):  
Pedram Mahzari ◽  
Mehran Sohrabi ◽  
Juliana M. Façanha

Summary Efficiency of low–salinity–water injection primarily depends on oil/brine/rock interactions. Microdispersion formation (as the dominant interfacial interaction between oil and low–salinity water) is one of the mechanisms proposed for the reported additional oil recovery by low–salinity–water injection. Using similar rock and brines, here in this work, different crude–oil samples were selected to examine the relationship between crude–oil potency to form microdispersions and improved oil recovery (IOR) by low–salinity–water injection in sandstone cores. First, the potential of the crude–oil samples to form microdispersions was measured; next, coreflood tests were performed to evaluate the performance of low–salinity–water injection in tertiary mode. Sandstone core plugs taken from a whole reservoir core were used for the experiments. The tests started with spontaneous imbibition followed by forced imbibition of high–salinity brine. Low–salinity brine was then injected in tertiary mode. The oil–recovery profiles and compositions of the produced brine were measured to investigate the IOR benefits as well as the geochemical interactions. The results demonstrate that the ratio of the microdispersion quantity to bond water is the main factor controlling the effectiveness of low–salinity–water injection. In general, a monotonic trend was observed between incremental oil recovery and the microdispersion ratio of the different crude–oil samples. In addition, it can be inferred from the results that geochemical interactions (pH and ionic interactions) would be mainly controlled by the rock's initial wettability, and also that these processes could not affect the additional oil recovery by low-salinity-water injection. To further verify the observations of geochemical interactions, a novel experiment was designed and performed on a quartz substrate to investigate the ionic interactions on the film of water between an oil droplet and a flat quartz substrate, when the high–salinity brine was replaced with the low–salinity brine. The results of the flat–substrate test indicated that the water film beneath the oil could not interact with the surrounding brine, which is in line with the results of the core tests.


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