Experimental Studies of Non-Equilibrium Grain-Boundary Segregations of Phosphorus under Low Tensile Stresses

Author(s):  
Yu Dong Fu ◽  
Gang Wang ◽  
Chen Liu ◽  
Qing Fen Li
2007 ◽  
Vol 353-358 ◽  
pp. 396-399
Author(s):  
Yu Dong Fu ◽  
Gang Wang ◽  
Chen Liu ◽  
Qing Fen Li

In the present paper, the non-equilibrium grain-boundary segregation of P atom was studied in low alloy steels subjected to a low tensile stress at different temperatures. The AES (Auger electron spectroscopy) experiments and dynamic analyses were conducted to study on the non-equilibrium grain-boundary segregation of P atom. The research results show that non-equilibrium segregation of phosphorus occurred at the grain boundaries of the steels 2.25Cr1Mo and 12Cr1MoV, while the critical time reached about 0-1 hour at constant temperatures 773 and 813K. The relationship between the diffusion rate and the diffusion time for the complex and the phosphorus atom was investigated based on the experimental results. Eventually the diffusion coefficients of complex and P were calculated with using a proposed dynamic model.


2013 ◽  
Vol 577-578 ◽  
pp. 193-196
Author(s):  
Yu Dong Fu ◽  
Qing Fen Li

Experimental investigation about the grain boundary fracture behavior and segregation behavior of phosphorus under low tensile stresses in steel 2.25Cr1Mo and 12Cr1MoV was carried out in this paper. AES (Auger electron spectroscopy) experiments and dynamic analyses on the non-equilibrium grain-boundary segregation (NGS) of phosphorus and the SEM photos of grain boundary fracture in Auger specimens of both steels were obtained. The variation of phosphorus segregation level in grain boundary at different aging time was studied. Results show that the non-equilibrium segregation of phosphorus occurred at the grain boundaries in the two steels while subjected to a tensile stress of 30MPa and held at 500°C. The corresponding critical time was about 1 hour for steel 2.25Cr1Mo and 3.5hour for steel 12Cr1MoV respectively. SEM photos of grain boundary fracture in Auger specimens of the test steels show that the grain boundary fracture rate increased with increasing concentration of phosphorus, and that the fracture toughness of steel 12Cr1MoV is much lower than the one of steel 2.25Cr1Mo.


2011 ◽  
Vol 312-315 ◽  
pp. 1116-1125
Author(s):  
Vladimir V. Popov

Recent models of grain-boundary diffusion are briefly reviewed. Models of diffusion along equilibrium boundaries of recrystallization origin in coarse-grained materials and along non-equilibrium boundaries in nanocrystalline materials obtained by gas condensation and compacting or by severe plastic deformation are considered separately.


2009 ◽  
Vol 152-153 ◽  
pp. 175-181
Author(s):  
Bronislav Kashevsky ◽  
Sergei Kashevsky ◽  
Igor Prokhorov

This paper presents computational and experimental studies of two phenomena occurring in magnetic suspensions under strongly non-equilibrium conditions created by high-frequency (in comparison with the inverse characteristic time of the particle mechanical motion) magnetic fields. First is the dynamic magnetic hysteresis in a dilute suspension of highly-coercive particles subjected to linearly polarized fields. Energy absorption by particles is of great interest for cancer treatment, chemical technology, biology and smart materials science. Second is related to polymer composite technologies and represents dissipative self-organization of a system of magnetically soft particles in a drying thin layer of polymer solution set under a rotating magnetic field


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