Curing Characteristics and Dynamic Mechanical Behaviour of Reinforced Acrylonitrile-Butadiene/Chlorosulfonated Polyethylene Rubber Blends

Author(s):  
G. Marković ◽  
M. Marinović-Cincović ◽  
H. Valentova ◽  
M. Ilavsky ◽  
B. Radovanović ◽  
...  
2005 ◽  
Vol 494 ◽  
pp. 475-480 ◽  
Author(s):  
G. Marković ◽  
M. Marinović-Cincović ◽  
H. Valentova ◽  
M. Ilavsky ◽  
B. Radovanović ◽  
...  

This paper deals with the control of the adhesion strength in metal-elastomer joints by fillers and the use of rubber blends to produce advanced high performance adhesive systems. The curing behavior of rubber compounds and dynamic mechanical properties of crosslinked rubber composites were considered in this technologically applicable study. The effects of two types of reinforcing filler, used to increase the adhesion strength between steel and rubber matrix based on acrylonitrile-butadiene rubber (NBR) and chlorosulfonated polyethylene rubber (CSM) was investigated. Precipitated silica (with the average size of primary particle 15 nm) and diatomaceous earth (with the average size of primary particle 28 µm) were used for both rubber and its blend (NBR/CSM). The filler loading range was from 0 to 35 phr. The determination of curing characteristics was estimated by Monsanto Rheometer. The crosslink density of the rubber composites was determined by swelling measurement. Dynamic mechanical behavior was measured by mechanical spectroscopy (in a single cantilever bending mode).


Polymer ◽  
1981 ◽  
Vol 22 (1) ◽  
pp. 127-129 ◽  
Author(s):  
D.J. Hourston ◽  
I.D. Hughes

2021 ◽  
pp. 096739112110313
Author(s):  
Ahmed Abdel-Hakim ◽  
Soma A el-Mogy ◽  
Ahmed I Abou-Kandil

Blending of rubber is an important route to modify properties of individual elastomeric components in order to obtain optimum chemical, physical, and mechanical properties. In this study, a novel modification of styrene butadiene rubber (SBR) is made by employing acrylic rubber (ACM) to obtain blends of outstanding mechanical, dynamic, and oil resistance properties. In order to achieve those properties, we used a unique vulcanizing system that improves the crosslink density between both polymers and enhances the dynamic mechanical properties as well as its resistance to both motor and break oils. Static mechanical measurements, tensile strength, elongation at break, and hardness are improved together with dynamic mechanical properties investigated using dynamic mechanical analyses. We also proposed a mechanism for the improvement of crosslink density and consequently oil resistance properties. This opens new opportunities for using SBR/ACM blends in oil sealing applications that requires rigorous mechanical and dynamic mechanical properties.


Polymer ◽  
2017 ◽  
Vol 127 ◽  
pp. 129-140 ◽  
Author(s):  
I. Ivaneiko ◽  
V. Toshchevikov ◽  
K.W. Stöckelhuber ◽  
M. Saphiannikova ◽  
G. Heinrich

2010 ◽  
Vol 106 (1) ◽  
pp. 79-85 ◽  
Author(s):  
C. Perianu ◽  
B. De Ketelaere ◽  
B. Pluymers ◽  
W. Desmet ◽  
J. DeBaerdemaeker ◽  
...  

2019 ◽  
Vol 947 ◽  
pp. 195-199
Author(s):  
Zainathul Akhmar Salim Abdul Salim ◽  
Aziz Hassan ◽  
Hanafi Ismail ◽  
Nor Hafizah Che Ismail

This study highlighted the effect of incorporation of rice husk silica (RHS) on the tensile properties and dynamic mechanical behaviour of natural rubber (NR) compounds. High purity RHS was synthesised by solvent-thermal extraction method, which was inspired by TAPPI T204 cm-97 and TAPPI T264 cm-97 standards with some modifications. The extraction method had successfully produced RHS with 99.9% of silica content and surface area of 234.25 m2/g. The incorporation of RHS in NR showed increment in tensile properties compared to unfilled NR. Further improvement was recorded by surface modification of RHS with 1 wt. % bis (triethoxysilylpropyl) tetrasulfide (TESPT). The modification of RHS with TESPT increased the rubber-filler interaction between RHS and NR matrix, hence enhancing the strength-related properties. The modified RHS-NR also recorded highest storage modulus, and the presence of RHS in the NR compound had slightly shifted the glass transition temperature (Tg) to a higher value. This confirmed that the strong rubber-filler interaction had increased the rigidity of the compounds and restricted the mobility of the rubber chains.


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