Study on the Effect of Recycled Coarse Aggregate on the Shrinkage Performance of Green Recycled Concrete

Shrinkage property is a significant indicator of the durability of concrete, and the shrinkage of green recycled concrete is particularly problematic. In this paper, construction waste was crushed and screened to generate simple-crushed recycled coarse aggregate (SCRCA). The SCRCA was then subjected to particle shaping to create primary particle-shaped recycled coarse aggregate (PPRCA). On this basis, the PPRCA was particle-shaped again to obtain the secondary particle-shaped recycled coarse aggregate (SPRCA). Under conditions where the dosage of cementitious material is 300 kg/m3 and the sand rate is 38%, a new high-belite sulphoaluminate cement (HBSAC) with low carbon emission and superior efficiency was used as the basic cementitious material. Taking the quality of recycled coarse aggregate (SCRCA, PPRCA, and SPRCA) and the replacement ratio (25%, 50%, 75%, and 100%) as the influencing factors to prepare the green recycled concrete, the workability and shrinkage property of the prepared concrete were analyzed. The results show that the water consumption of green recycled concrete decreases as the quality of the recycled coarse aggregate (RCA) increases and the replacement ratio decreases, provided that the green recycled concrete achieves the same workability. With the improvement of RCA quality and the decrease of replacement ratio, the shrinkage of recycled concrete decreases. The shrinkage performance of green recycled concrete configured with the SPRCA completely replacing the natural coarse aggregate (NCA) is basically the same as that of the natural aggregate concrete (NAC).

The structure-activity relationship between precursor fine structure and cathodes performance in Ni-rich layered oxide

Cathode’s primary particle structure plays a key role in the performance of lithium ion batteries, which can be controlled by the precursor synthesis. Regretfully, the relevance between primary particle structure and cathode performance is not explicitly elucidated, that is, what is the discrepancy of cathode’s primary particle size on the structural degradation? In order to elaborate the structure-activity relationship between them, we have systematically investigated the regulation of primary particle size through an in-depth analysis of the precursor growth mechanism, ammonia-stirring coupling and hydrodynamics optimization. Structural and electrochemical characterizations of LiNi0.92Co0.04Mn0.04O2 with different primary sizes (336, 447, 565 and 675 nm) and a rounded analysis of structural degradation after cycling provide insight into the correlation between precursor fine structure and cathode performance, i.e. larger cathode’s primary particle size can effectively inhibit CEI film formation, structure decay, the intragranular/intergranular cracks formation owing to the alleviation of localized stress.

A Numerical and Experimental Study of Soot Precursor and Primary Particle Size of N-Butylbenzene in Laminar Flame

The current study analyzed the soot precursor of the n-butylbenzene found in diesel and kerosene in laminar flame, and integrated the corresponding poly-aromatic hydrocarbon (PAH) growth mechanism with the popular n-butylbenzene oxidation mechanisms to improve the soot formation prediction of n-butylbenzene. The size of soot precursor was determined by the fringe length in the core of soot particle since the nanostructure of the core of soot particle is similar with that of nascent soot particle formed by soot precursor nucleation. The geometric mean fringe length in core of soot particles was measured to be 0.67 nm approximating to the size of five-ringed PAH (A5). An A5 growth mechanism was added on a popular n-butylbenzene mechanism, and the combined mechanism was further reduced. After validation by the ignition delay time in literature, the combined mechanism was then validated by the primary particle diameter in laboratory and soot volume fraction of n-propylbenzene in literature. The calculated soot precursor concentration and PAH condensation rate of the combined mechanism are smaller than that of the base mechanism. The simulated primary soot particle diameter of proposed combined mechanism agrees well with the measure primary soot particle diameter. Comparing to the simulated soot volume fraction of base n-butylbenzene mechanism, the simulated soot volume fraction of proposed combined n-butylbenzene-A5 mechanism agrees well with the measure soot volume fraction of n-propylbenzene in literature. This study provides certain support for further investigation of soot formation of n-butylbenzene and its relative fuel like diesel and kerosene.

Soot PCF: pore condensation and freezing framework for soot aggregates

Atmospheric ice formation in cirrus clouds is often initiated by aerosol particles that act as ice-nucleating particles. The aerosol–cloud interactions of soot and associated feedbacks remain uncertain, in part because a coherent understanding of the ice nucleation mechanism and activity of soot has not yet emerged. Here, we provide a new framework that predicts ice formation on soot particles via pore condensation and freezing (PCF) that, unlike previous approaches, considers soot particle properties, capturing their vastly different pore properties compared to other aerosol species such as mineral dust. During PCF, water is taken up into pores of the soot aggregates by capillary condensation. At cirrus temperatures, the pore water can freeze homogeneously and subsequently grow into a macroscopic ice crystal. In the soot-PCF framework presented here, the relative humidity conditions required for these steps are derived for different pore types as a function of temperature. The pore types considered here encompass n-membered ring pores that form between n individual spheres within the same layer of primary particles as well as pores in the form of inner cavities that form between two layers of primary particles. We treat soot primary particles as perfect spheres and use the contact angle between soot and water (θsw), the primary particle diameter (Dpp), and the degree of primary particle overlap (overlap coefficient, Cov) to characterize pore properties. We find that three-membered and four-membered ring pores are of the right size for PCF, assuming primary particle sizes typical of atmospheric soot particles. For these pore types, we derive equations that describe the conditions for all three steps of soot PCF, namely capillary condensation, ice nucleation, and ice growth. Since at typical cirrus conditions homogeneous ice nucleation can be considered immediate as soon as the water volume within the pore is large enough to host a critical ice embryo, soot PCF becomes limited by either capillary condensation or ice crystal growth. We use the soot-PCF framework to derive a new equation to parameterize ice formation on soot particles via PCF, based on soot properties that are routinely measured, including the primary particle size, overlap, and the fractal dimension. These properties, along with the number of primary particles making up an aggregate and the contact angle between water and soot, constrain the parameterization. Applying the new parameterization to previously reported laboratory data of ice formation on soot particles provides direct evidence that ice nucleation on soot aggregates takes place via PCF. We conclude that this new framework clarifies the ice formation mechanism on soot particles in cirrus conditions and provides a new perspective to represent ice formation on soot in climate models.

Properties of WCCo Composites Produced by the SPS Method Intended for Cutting Tools for Machining of Wood-Based Materials

This paper presents the possibility of using the Spark Plasma Sintering (SPS) method to obtain WCCo composite materials. Such materials are used as cutting blades for machining wood-based materials. Two series of composites, different in grain size and cobalt content, were analyzed in the paper. The produced materials were characterized using Scanning Electron Microscopy (SEM), X-ray diffraction (XRD), and tribological properties were determined. In addition, preliminary tests were carried out on the durability of the blades made of sintered WCCo composites while machining three-layer chipboard. The results of the microstructure analysis proved that the SPS method makes it possible to obtain solid composites. Phase analysis showed the occurrence of the following phases: WC, Co, and Co3W9C4. The lowest friction coefficient value was found in samples sintered using powder with an average primary particle size of 400 nm (ultrafine).

Cosmic rays at ground level; a brief introduction

<p>Galactic cosmic rays, and sporadic high energy solar energetic particles, are energetic enough to pierce the Earth’s protective magnetosphere and interact with the atmosphere. Here, a secondary particle cascade leads to enhanced radiation levels which is of importance, for instance, to aviation dosimetry and related studies. At ground level, these secondary particles can be observed (indirectly) by means of neutron monitors, and this has been done for more than 70 years, providing a valuable long-term cosmic ray record. In this talk, we introduce the different primary particle populations, discuss their acceleration and modulation, and connect this with long-term neutron monitor measurements.</p>