Study on the Stability of all Vanadium Redox Flow Battery Electrolyte

2013 ◽  
Vol 281 ◽  
pp. 461-464
Author(s):  
Shu Di Zhang ◽  
Yu Chun Zhai

In order to study on several additives to Vanadium battery electrolyte stability, different additives were added in the electrolyte of vanadium battery electrolyte at different temperatures, precipitation time were observed, cyclic voltammetry curves were tested and ultraviolet quantitative analysis to precipitated supernatant , The results show that after adding the different additives, at 40 °C temperature, 1.8 mol / L concentration can stably exist in the electrolyte of the vanadium battery. The added amount of sodium oxalate, ammonium oxalate is equivalent 3% of the amount V4+ solution, the vanadium battery electrolyte stability can be improved without affecting its reversible reaction, it is a preferred stabilizer.

2018 ◽  
Vol 20 (36) ◽  
pp. 23664-23673 ◽  
Author(s):  
Fabio Jonas Oldenburg ◽  
Marta Bon ◽  
Daniele Perego ◽  
Daniela Polino ◽  
Teodoro Laino ◽  
...  

Phosphoric acid improves the stability of vanadium redox flow battery electrolyte and enhances the kinetics of the negative electrode.


2020 ◽  
Vol 8 (10) ◽  
pp. 2000445
Author(s):  
Nataliya V. Roznyatovskaya ◽  
Matthias Fühl ◽  
Vitaly A. Roznyatovsky ◽  
Jens Noack ◽  
Peter Fischer ◽  
...  

2019 ◽  
Vol 90 ◽  
pp. 01004 ◽  
Author(s):  
Saidatul Sophia ◽  
Ebrahim Abouzari Lotf ◽  
Arshad Ahmad ◽  
Pooria Moozarm Nia ◽  
Roshafima Rasit Ali

Graphene oxide (GO) has attracted tremendous attention in membrane-based separation field as it can filter ions and molecules. Recently, GO-based materials have emerged as excellent modifiers for vanadium redox flow battery (VRFB) application. Its high mechanical and chemical stability, nearly frictionless surface, high flexibility, and low cost make GO-based materials as proper materials for the membranes in VRFB. In VRFB, a membrane acts as the key component to determine the performance. Therefore, employing low vanadium ion permeability with excellent stability membrane in vanadium electrolytes is important to ensure high battery performance. Herein, recent progress of GO-modified membranes for VRFB is briefly reviewed. This review begins with current membranes used for VRFB, followed by the challenges faced by the membranes. In addition, the transport mechanism of vanadium ion and the stability properties of GO-modified membranes are also discussed to enlighten the role of GO in the modified membranes.


2016 ◽  
Vol 211 ◽  
pp. 926-932 ◽  
Author(s):  
Nataliya Roznyatovskaya ◽  
Jens Noack ◽  
Matthias Fühl ◽  
Karsten Pinkwart ◽  
Jens Tübke

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