Abstract
The report provides data on the electrochemical modification of carbon-graphite fibers as the basis for the creation of composite materials. The results of studies of the electrodeposition of metals on pre-electrochemically modified carbon fiber materials (CFM) in order to obtain composite materials based on them are presented. The use of CFM for the creation of composite materials is associated with the possibility of deposition of metals, alloys or their compounds on the surface of their constituent fibers. Electrochemical treatment in aqueous solutions of electrolytes is a promising method for modifying the surface properties of carbon materials, including in order to improve their adhesive properties. Preliminary electrochemical modification of carbon fiber materials in indifferent solutions of electrolytes made it possible to obtain composite and nanocomposite materials with good adhesion of the electrodeposited metal to the surface of the fibers of carbon materials.When metals are deposited on carbon fiber materials, it is necessary to solve the problem of applying a uniform metal deposit or with a certain profile in the thickness of the material. In this case, it is effective to use methods of mathematical modeling of metal deposition processes in a flowing three-dimensional electrode. Depending on the selected modes of deposition of metal sediment on the CFM, some electrochemical parameters of the process and system may be dependent on both the time of the process and the thickness coordinate of the electrode. This is especially true for the value of the resistivity of the solid phase of the system, that is, carbon-graphite fibrous material. Other electrochemical parameters, such as the specific electrode surface, the exchange current and the transfer coefficient of the electrochemical reaction, the porosity of the material, etc., can also change during the electrodeposition of the metal on the CFM. It is proposed to take into account the change in the characteristic properties of modified carbon fiber materials in the mathematical modeling of the processes of electrodeposition of metals on carbon fiber materials in order to determine the technological parameters to improve the efficiency of the properties of composite materials. In order to implement mathematical models used in the calculation of electrochemical processes in the volume and on the surface of carbon fiber materials, a set of programs based on modern computational methods and programming languages has been developed.
MECHANICAL AND MATHEMATICAL MODELING OF VISCO-ELASTIC CONTINUA – CONSTITUTIVE EQUATIONS