Synthesis and Characterization of Poly(Glycerol Sebacate)-co-Lactic Acid via Gamma Irradiation

The gamma irradiation was utilized to facilitate the synthesis of poly (glycerol sebacate)-co-lactic acid (PGS-co-LA). The effect of methyl methacrylate (MMA) crosslinker and varying dosage of irradiation to the structural composition and thermal properties of the synthesized PGS-co-LA was investigated. Compositional analyses of the polymer materials using infrared spectroscopy confirm the covalent formation of ester linkage. The use of methyl methacrylate enhances the formation of the characteristic bonds in the polymer structure. The intensity of these peaks increases with increasing irradiation dosage and high amount of crosslinker. The melting temperature of the PGS-co-LA becomes more negative with the incorporation of high amount of MMA.

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Poly(Methyl methacrylate)/Palladium Nanocomposites: Synthesis and Characterization of the Morphological, Thermomechanical, and Thermal Properties

Chemistry of Materials ◽

10.1021/cm031049h ◽

2003 ◽

Vol 15 (25) ◽

pp. 4874-4878 ◽

Cited By ~ 71

Author(s):

Cyril Aymonier ◽

Denis Bortzmeyer ◽

Ralf Thomann ◽

Rolf Mülhaupt

Keyword(s):

Thermal Properties ◽

Methyl Methacrylate ◽

Synthesis And Characterization ◽

Poly Methyl Methacrylate

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Synthesis and Characterization of Star-Shaped Polylactic Acid with Polyhedral Oligomeric Silsesquioxanes

Applied Mechanics and Materials ◽

10.4028/www.scientific.net/amm.200.397 ◽

2012 ◽

Vol 200 ◽

pp. 397-400 ◽

Cited By ~ 3

Author(s):

Xiao Hui Zhang ◽

Wen Juan Gu ◽

Hou Bin Li ◽

Yi Xiang Tang ◽

Long Qi Wu

Keyword(s):

Lactic Acid ◽

Thermal Properties ◽

Polylactic Acid ◽

Decomposition Temperature ◽

Synthesis And Characterization ◽

Dendritic Polymers ◽

The Novel ◽

Polyhedral Oligomeric Silsesquioxanes ◽

Structures And Properties

A series of star-shaped polylactic acid was synthesized using L-lactic acid (L-LA) and octa(γ-chloroammoniumpropyl) octasilsesquioxane (POSS-NH3Cl) by in the presence of stannous(II) octanoate (Sn(Otc)2) catalyst. The structures and properties of these dendritic polymers were characterized by FTIR, 1H-NMR and TGA, respectively. These results demonstrated that the chemical reaction between POSS-NH3Cl and L-LA had been taken place, and the novel star-shaped polylactic acid (POSS-g-PLLA) had been synthesized. And thermal properties, such as melting temperature and decomposition temperature, were obviously improved along with the increment of the added amount of POSS-NH3Cl. The decomposition temperature of POSS-g-PLLA was higher ca. 70°C higher than that of PLLA, also higher 65°C than that of POSS-NH3Cl/PLLA.

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The synthesis, characterization of opal-poly(methyl methacrylate) graft polymer based on ICAR-ATRP and its effect on performance of poly (lactic acid)

Polymer-Plastics Technology and Materials ◽

10.1080/25740881.2021.1876878 ◽

2021 ◽

Vol 60 (10) ◽

pp. 1051-1065

Author(s):

Dawei Luo ◽

Gaowei Lei ◽

Weijun Zhen ◽

Ling Zhao

Keyword(s):

Lactic Acid ◽

Methyl Methacrylate ◽

Poly Lactic Acid ◽

Graft Polymer ◽

Poly Methyl Methacrylate

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Synthesis and Characterization of Poly(methyl methacrylate-block-ethylene glycol-block-methyl methacrylate) Block Copolymers by Reversible Addition-Fragmentation Chain Transfer Polymerization

Journal of Macromolecular Science Part A ◽

10.1080/10601325.2011.528310 ◽

2010 ◽

Vol 48 (1) ◽

pp. 65-70 ◽

Cited By ~ 23

Author(s):

Temel Öztürk ◽

Melahat Göktaş ◽

Bakí Hazer

Keyword(s):

Block Copolymers ◽

Ethylene Glycol ◽

Methyl Methacrylate ◽

Chain Transfer ◽

Synthesis And Characterization ◽

Poly Methyl Methacrylate ◽

Reversible Addition ◽

Chain Transfer Polymerization

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Synthesis and characterization of a novel biodegradable amphiphilic MPEG-dendritic block copolymer containing (glycolic acid)-alt-(lactic acid) oligomer and glycerol

Journal of Controlled Release ◽

10.1016/j.jconrel.2011.09.053 ◽

2011 ◽

Vol 152 ◽

pp. e264-e266

Author(s):

Jianwei Jiang ◽

Li Zhang ◽

Miao Wu ◽

Xuefei Zhang

Keyword(s):

Lactic Acid ◽

Block Copolymer ◽

Glycolic Acid ◽

Synthesis And Characterization

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Synthesis and Characterization of Polyphosphazenes Modified with Hydroxyethyl Methacrylate and Lactic Acid

International Journal of Polymer Science ◽

10.1155/2013/645869 ◽

2013 ◽

Vol 2013 ◽

pp. 1-7 ◽

Cited By ~ 1

Author(s):

Evelyn Carolina Martínez Ceballos ◽

Ricardo Vera Graziano ◽

Gonzalo Martínez Barrera ◽

Oscar Olea Mejía

Keyword(s):

Lactic Acid ◽

Ring Opening ◽

Room Temperature ◽

Block Structure ◽

Ring Opening Polymerization ◽

Synthesis And Characterization ◽

Poly Lactic Acid ◽

Hydroxyethyl Methacrylate ◽

H Nmr

Poly(dichlorophosphazene) was prepared by melt ring-opening polymerization of the hexachlorocyclotriphosphazene. Poly[bis(2-hydroxyethyl-methacrylate)-phosphazene] and poly[(2-hydroxyethyl-methacrylate)-graft-poly(lactic-acid)-phosphazene] were obtained by nucleophilic condensation reactions at different concentrations of the substituents. The properties of the synthesized copolymers were assessed by FTIR,1H-NMR and31P-NMR, thermal analysis (DSC-TGA), and electron microscopy (SEM). The copolymers have a block structure and show twoTg's below room temperature. They are stable up to a temperature of 100°C. The type of the substituents attached to the PZ backbone determines the morphology of the polymers.

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