Influence of Surface Characteristics on the Dispersion of Modified Multi-Walled Carbon Nanotubes

2011 ◽  
Vol 236-238 ◽  
pp. 1832-1835 ◽  
Author(s):  
Yan Xuan Ma ◽  
Yu Dong Zheng ◽  
Jian Wu ◽  
Jue Tan ◽  
Wei Li ◽  
...  

In order to improve the dispersion of multi-walled carbon nanotubes (MWCNTs), MWCNTs were physically modified by the surfactant of Poly (vinyl pyrrolidone) (PVP), cetyl trimethylammonium bromide (CTAB) and sodium dodecylbenzene sulfonate (SDBS), and were chemically treated by the acid oxidation. Measuring the zeta potential of the dispersions of modified MWCNTs and surface contact angle of modified MWCNT powders, influence of acting forces on the dispersions of modified MWCNTs was analyzed. The balance of electrostatic repulsion and van der Waals forces determines the stabilization of aqueous modified MWCNT dispersions. The sufficient reactive groups, ions and long molecular chains play important roles for such balance.

2010 ◽  
Vol 195 (2) ◽  
pp. 461-465 ◽  
Author(s):  
D. Morales-Acosta ◽  
J. Ledesma-Garcia ◽  
Luis A. Godinez ◽  
H.G. Rodríguez ◽  
L. Álvarez-Contreras ◽  
...  

Author(s):  
Baoguo Han ◽  
Xun Yu ◽  
Jinping Ou

Sodium dodecyl sulfate (SDS) and sodium dodecylbenzene sulfonate (NaDDBS) are used as surfactants to improve the dispersion of multi-walled carbon nanotubes (MWNTs) in cement mortar and fabricate piezoresistive carbon-nanotube/cement mortar composite. The piezoresistivity of carbon-nanotube/cement mortar composite with different content levels of MWNTs and different surfactants were explored under repeated loading and impulsive loading. Experimental results indicate that NaDDBS has higher efficiency than SDS for the dispersion of MWNTs in cement mortar. The response of the electrical resistance of carbon-nanotube/cement mortar composite with NaDDBS to external force is more stable and sensitive than that of carbon-nanotube/cement mortar composite with SDS. These findings indicate that the use of NaDDBS is an effective way for improving the dispersion of MWNTs in cement-based composite and fabricating MWNTs filled cement-based composite with stable and strong piezoresistive response.


2019 ◽  
Vol 16 (39) ◽  
pp. 55-63
Author(s):  
Akram Sh. Ahmed

In this work we experimentally investigated SWCNTs and MWCNTs to increase their thermal conductivity and electrically functionalization process using different reagents ((nitric acid, HNO3 followed by acid treatment with H2SO4), then washed with deionized water (DW) and then treated with H2O2 via ultrasonic technique. Then repeated the steps with MWCNTs and compare their results in an effort to improve experimental conditions that efficiently differentiate the surface of the single walled carbon nanotubes (SWCNTs) and multi walled carbon nanotubesi(MWCNTs) that less nanotubes destroy and to enhance the properties of them and also to reduce aggregation in liquid. the results were prove by XRD, and infrared spectroscopy (FTIR). The FTIR spectrum shows the presence of carboxylic group after treatment with (acid oxidation and H2O2) and refers to Functionalization (SWCNTs) and (MWCNTs) on the surface wall microscopic images show surface adjustment on SWCNTs and ((MWCNTs)) structure after any treatment. AT last, a fully of SWCNTs and MWCNTSIwere obtained successfully accomplished with the reduction of the collapsed structure.


2007 ◽  
Vol 2007 ◽  
pp. 1-5
Author(s):  
Wei Chen ◽  
Xiaojun Li ◽  
Liming Dai

Quartz crystal microbalance (QCM) was used to investigate the adsorption of acid-oxidized single-walled carbon nanotubes (Ox-SWNTs) and poly(vinyl pyrrolidone), PVP. It was found for the first time that Ox-SWNTs adsorbed onto the QCM electrode can be effectively replaced by PVP chains in an aqueous solution. This replacement process was also investigated by atomic force miscroscopic (AFM) imaging, which shows good agreement with the QCM measurements. This study provides powerful tools for fundamental investigation of polymer-nanotube interactions and for controlled design/fabrication of functional polymer-nanotube surfaces for potential applications.


2008 ◽  
Vol 254 (15) ◽  
pp. 4644-4649 ◽  
Author(s):  
Hoon-Sik Jang ◽  
Sung-Oong Kang ◽  
Seung-Hoon Nahm ◽  
Bae Ho Park ◽  
Yong-Il Kim

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