Synthesis of [6,7]-Dihydro-[1,4]-Dioxino-[2,3-f][2,1,3]-Benzothiadiazole: A Novel Building Block for Electron-Poor Conjugated Polymers"

2011 ◽  
Vol 284-286 ◽  
pp. 601-606 ◽  
Author(s):  
Xiao Xia Sun ◽  
Xiao Xiao Zhuang ◽  
Ying Chun Li ◽  
Xi Mei Liu ◽  
Ya Zhou Lou

Heterocyclic monomers based on 2,1,3-benzothiadiazole bearing solubilizing side chains have been synthesized in high yields over four steps from readily available starting materials. A multistep synthesis of the electron-poor 6, 7-dihydro-1, 4-dioxino-[2, 3-f][2,1,3]-benzothiadiazole are presented. The new dificient acceptor has good solubility in organic aolvents to permit an appropriate coating process.

2013 ◽  
Vol 781-784 ◽  
pp. 444-447 ◽  
Author(s):  
Xiao Xia Sun ◽  
Xiao Xiao Zhuang ◽  
Yu Hu

Monomers based on 2,1,3-benzothiadiazole bearing solubilizing side chains have been synthesized in high yields over four steps from readily available starting materials. A multistep synthesis of the electron-poor 5,6-bis (heptyloxy) benzo [[1,2,thiadiazole are presented. The new deficient acceptor has good solubility in organic solvents to permit an appropriate coating process.


2013 ◽  
Vol 781-784 ◽  
pp. 440-443 ◽  
Author(s):  
Xiao Xia Sun ◽  
Xiao Long Lei ◽  
Chun Hua Qi ◽  
Yu Hu

Heterocyclic monomers based on benzo [[1,2,thiadizole bearing solubilizing side chains have been synthesized in high yields over four steps from readily available starting materials. A multistep synthesis of the electron-poor 4,7-di (thiophen-2-yl) benzo [[1,2,selenadizole are presented. The new dificient acceptor has good solubility in organic aolvents to permit an appropriate coating process.


2012 ◽  
Vol 174-177 ◽  
pp. 692-696 ◽  
Author(s):  
Xiao Xia Sun ◽  
Xiao Xiao Zhuang ◽  
Yu Hu

Heterocyclic monomers based on 2,1,3-benzothiadiazole bearing solubilizing side chains have been synthesized in high yields over four steps from readily available starting materials. The new dificient acceptor has good solubility in organic aolvents to permit an appropriate coating process. Two soluble donor-acceptor π-conjugated oligomers comprising electron-rich thiophenes the electron-deficient EDOBT have been carefully investigated.


2011 ◽  
Vol 335-336 ◽  
pp. 90-95
Author(s):  
Xiao Xia Sun ◽  
Ya Zhou Lou ◽  
Qiang Qiang Chen ◽  
Li Li ◽  
Xiao Xiao Zhuang ◽  
...  

Heterocyclic electron-poor monomer [1,2,5]thiadiazolo[3,4-c]pyridine have been synthesized in high yields over five steps from readily available starting materials. The new deficient acceptor has good solubility in organic solvents so as to permit an appropriate coating process.


2019 ◽  
Vol 10 (27) ◽  
pp. 3722-3739 ◽  
Author(s):  
Supreetha Paleyanda Ponnappa ◽  
Qian Liu ◽  
Muhammad Umer ◽  
Jennifer MacLeod ◽  
Jospeh Jickson ◽  
...  

Naphthalene flanked DPP with hexyl and octyl chain based electropolymerized conjugated polymers exhibits bio-sensing.


2012 ◽  
Vol 602-604 ◽  
pp. 1261-1264
Author(s):  
Xiao Xiao Zhuang ◽  
Xiao Long Lei ◽  
Xiao Xia Sun

Heterocyclic monomer based on 2,1,3-benzothiadiazole bearing solubilizing side chains have been synthesized in high yields over three steps from readily available starting materials. The alkyl side chain in the 4-position of both thiophene rings gives the material mononer a good solubility.


2020 ◽  
Vol 11 (36) ◽  
pp. 5750-5756 ◽  
Author(s):  
Yinghui Wang ◽  
Junhui Miao ◽  
Chuandong Dou ◽  
Jun Liu ◽  
Lixiang Wang

A new benzene-fused BODIPY unit for designing polymer donors with near-infrared absorption for organic photovoltaics.


2011 ◽  
Vol 44 (11) ◽  
pp. 4213-4221 ◽  
Author(s):  
Haifeng Wang ◽  
Qinqin Shi ◽  
Yuze Lin ◽  
Haijun Fan ◽  
Pei Cheng ◽  
...  

Synthesis ◽  
2022 ◽  
Author(s):  
Dishu Zeng ◽  
Tianbao Yang ◽  
Niu Tang ◽  
Wei Deng ◽  
Jiannan Xiang ◽  
...  

A simple, mild, green and efficient method for the synthesis of 2-aminobenzamides was highly desired in organic synthesis. Herein, we developed an efficient, one-pot strategy for the synthesis of 2-aminobenzamides with high yields irradiated by UV light. 32 examples proceeded successfully by this photo-induced protocol. The yield reached up to 92%. The gram scale was also achieved easily. This building block could be applied in the preparation of quinazolinones derivatives. Amino acid derivatives could be employed smoothly at room temperature. Finally, a plausible mechanism was proposed.


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