Synthesis and Luminescent Properties of Two Zn (II) Complexes with Schiff-Base Ligand

2011 ◽  
Vol 322 ◽  
pp. 341-344 ◽  
Author(s):  
Yi Min Feng
Keyword(s):  
Schiff Base ◽  
Organic Solvents ◽  
Schiff Base Ligand ◽  
Luminescence Intensity ◽  
Zinc Acetate Dihydrate ◽  
Luminescent Properties ◽  
Luminescent Intensity ◽  
Dmso Solution ◽  
Acetate Dihydrate ◽  
Schiff Base Ligands

Two Zn (II) complexes have been prepared by reaction of zinc acetate dihydrate with Schiff-base ligands. The IR spectra of complexes were measured. The luminescence properties of the Zn (II) complexes in solid and in methanol, ethanol and DMSO solution were investigated and the effects of organic solvents on the luminescent intensity of Zn (II) complexes also were studied. The results show that the Zn (II) ions formed stable complexes. The complexes exhibited maximum fluorescence emissions in blue region and the organic solvents have effect on the luminescence intensity.

Synthesis of an Unprecedented H-stitched Binuclear Crystal Structure Based on Selective Fluorescence Recognition of Zn2+ in Newly Synthesized Schiff Base Ligand with DFT and Imaging Application in Living Cells

2021 ◽  
Author(s):  
SOUMYA SUNDAR MATI ◽  
Dr. SAUGATA KONAR ◽  
BOBY SAMAI
Keyword(s):  
Crystal Structure ◽  
Schiff Base ◽  
Elemental Analysis ◽  
Schiff Base Ligand ◽  
Binuclear Complex ◽  
Living Cells ◽  
X Ray Diffraction ◽  
Schiff Base Ligands ◽  
X Ray ◽  
Imaging Application

A zinc coordinated rare binuclear complex was synthesised and characterized by elemental analysis and single-crystal X-ray diffraction. Two mononuclear units formed by two Schiff base ligands 2-((2-(pyrimidin-2-yl)hydrazono)methyl)phenol (PHP) coordinated with...

Synthesis, Structure and Fluorescence Properties of a Trinuclear Zn(II) Complex with N,N,O-donor Schiff Base Ligands and Bridging Acetates

2009 ◽  
Vol 64 (4) ◽  
pp. 403-408 ◽  
Author(s):  
Shyamapada Shit ◽  
Joy Chakraborty ◽  
Brajagopal Samanta ◽  
Georgina M. Rosair ◽  
Samiran Mitra
Keyword(s):  
Schiff Base ◽  
Schiff Base Ligand ◽  
Fluorescence Properties ◽  
Schiff Base Ligands ◽  
Thermal Methods ◽  
Metal Centers ◽  
X Ray ◽  
Octahedral Environment ◽  
Distorted Octahedral ◽  
Ft Ir

A new centrosymmetric trinuclear Zn(II) complex [Zn3L2(CH3COO)4] (1) has been synthesized by the reaction of Zn(CH3COO)2 · 2H2O with a tridentate N,N,O-donor Schiff base ligand HL [C5H4NC(CH3)=NC6H4(OH)] and systematically characterized by elemental analysis, FT-IR, UV/Vis and thermal methods. Single crystal X-ray structure analysis reveals that three Zn(II) centers are in two different coordination environments. Two terminal Zn(II) centers adopt a distorted squarepyramidal geometry leaving the central Zn(II) in a distorted octahedral environment. Two adjacent metal centers are connected through single μ2-phenolato as well as double μ-acetato-O,O´ syn-syn bridges. Fluorescence properties of the complex as compared to the ligand indicate that the former can serve as a potential photoactive material.

Synthesis, characterization, luminescent properties and biological activities of zinc complexes with bidentate azomethine Schiff-base ligands

Polyhedron ◽  
2018 ◽  
Vol 154 ◽  
pp. 65-76 ◽  
Author(s):  
A.S. Burlov ◽  
V.G. Vlasenko ◽  
Yu.V. Koshchienko ◽  
N.I. Makarova ◽  
A.A. Zubenko ◽  
...  
Keyword(s):  
Schiff Base ◽  
Biological Activities ◽  
Luminescent Properties ◽  
Zinc Complexes ◽  
Schiff Base Ligands

scholarly journals A Chiral Bis(salicylaldiminato)zinc(II) Complex with Second-Order Nonlinear Optical and Luminescent Properties in Solution

Inorganics ◽  
2020 ◽  
Vol 8 (4) ◽  
pp. 25 ◽  
Author(s):  
Paola Matozzo ◽  
Alessia Colombo ◽  
Claudia Dragonetti ◽  
Stefania Righetto ◽  
Dominique Roberto ◽  
...  
Keyword(s):  
Schiff Base ◽  
Nonlinear Optical ◽  
Luminescent Properties ◽  
Second Order ◽  
Point Of View ◽  
Zinc Complexes ◽  
Schiff Base Ligands ◽  
Organic Hybrid ◽  
Optical And Luminescent Properties ◽  
Organic Hybrid Material

Whereas there is an increasing amount of reports on the second-order nonlinear optical (NLO) and luminescence properties of tetradentate [N2O2] Schiff base–zinc complexes, the study of zinc complexes having two bidentate [NO] Schiff-base ligands is relatively unexplored from an NLO point of view. This work puts in evidence that the known chiral bis{2-[(R)-(+)-1-phenylethyliminomethyl]phenolato-N,O}zinc(II) complex is a fascinating multifunctional molecular inorganic–organic hybrid material characterized by interesting second-order NLO and luminescent properties in solution. The emissive properties of the organic 2-(R)-(+)-1-phenylethyliminomethyl]phenol proligand are greatly enhanced upon coordination to the inorganic Zn(II) center.

Kinetics of Schiff base ligand transfer and rate enhancement by metal ions

1973 ◽  
Vol 26 (11) ◽  
pp. 2541 ◽  
Author(s):  
WW Fee ◽  
A Gaetano
Keyword(s):  
Schiff Base ◽  
Metal Ions ◽  
Schiff Base Ligand ◽  
Chain Reaction ◽  
Schiff Base Ligands ◽  
Rate Enhancement ◽  
Rate Acceleration ◽  
Ligand Transfer ◽  
Kinetics Of

The kinetics of the transfer of Schiff base ligands between their nickel(II) and zinc(II) complexes have been examined in dmso. Reactions completed in the presence of added nickel(II) and zinc(II) ions indicate the occurrence of a coordination chain reaction with rate acceleration prompted by one chain initiating and one chain propa- gating step.

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