Preparation, Morphology and Dielectric Properties of Polyamide-6/Poly(Vinylidene Fluoride) Blends

2012 ◽  
Vol 496 ◽  
pp. 263-267
Author(s):  
Rui Li ◽  
Jian Zhong Pei ◽  
Yan Wei Li ◽  
Xin Shi ◽  
Qun Le Du

A novel all-polymeric material with high dielectric constant (k) has been developed by blending poly (vinylidene fluoride) (PVDF) with polyamide-6 (PA6). The dependence of the dielectric properties on frequency and polymer volume fraction was investigated. When the volume fraction of PA6 is 20%, the dielectric property is better than others. The SEM investigations suggest that the enhanced dielectric behavior originates from significant interfacial interactions of polymer-polymer. The XRD demonstrate that the PA6 and PVDF affect the crystalline behavior of each component. Furthermore, the stable dielectric constants of the blends could be tuned by adjusting the content of the polymers. The created high-k all-polymeric blends represent a novel type of material that are simple technology and easy to process, and is of relatively high dielectric constant, applications as flexible electronics.

e-Polymers ◽  
2011 ◽  
Vol 11 (1) ◽  
Author(s):  
Rui Li ◽  
Chuanxi Xiong ◽  
Lijie Dong

AbstractA novel all-polymeric material with high dielectric constant (k) has been developed by blending poly(vinylidene fluoride) (PVDF) with polyacrylamide (PAM). The dependence of the dielectric constant on frequency and polymer volume fraction was investigated. When the weight fraction of PAM is 1wt%, the dielectric constant of the blend could be up to 24, and the dielectric loss tanδ can be lowered to 0.06. The SEM investigations suggest that the enhanced dielectric behavior originates from significant interfacial interactions of polymer-polymer. XRD and FTIR demonstrate that blending PAM with PVDF affects the crystalline behavior of each component. Our finding suggests that the created high-k polymeric blends represent a novel type of material that are flexible and easy to process, and is of relatively high dielectric constant and high breakdown strength; moreover find applications as flexible electronics.


RSC Advances ◽  
2015 ◽  
Vol 5 (80) ◽  
pp. 65167-65174 ◽  
Author(s):  
Li Ren ◽  
Xing Meng ◽  
Jun-Wei Zha ◽  
Zhi-Min Dang

The BT@Ag particles (a) were prepared by depositing Ag nanoparticles on the surface of BT (b). The BT@Ag/PVDF composites have high dielectric constant and the direct current conductivity still keeps a low value when the filler content is high (c).


2018 ◽  
Vol 08 (03) ◽  
pp. 1850017 ◽  
Author(s):  
Srikanta Moharana ◽  
Shraddhakara Sai ◽  
Ram Naresh Mahaling

The surface hydroxylation treatment has been carried out by using hydrogen peroxide (H2O2) to modify the surface of Na[Formula: see text]Bi[Formula: see text]TiO3 (NBT) particles in a ferroelectric polymer (PVDF) via solution casting technique. The FTIR study confirms the presence of hydroxyl groups on the surface of NBT. The FE-SEM analysis reveals that h-NBT particles are dispersed homogeneously within the polymer matrix. The surface hydroxylation treatment plays an important role in high dielectric constant and also reduced loss by conducting the material surface with [Formula: see text]OH functional groups. The prepared composite with 40[Formula: see text]wt.% of h-NBT showed enhanced dielectric constant ([Formula: see text]114), negligible loss (0.22) and high AC conductivity as compared to that of the unmodified NBT. Such significant enhancement in dielectric properties may be due to the strong interaction between h-NBT particles and PVDF matrix at the interface. The percolation theory is used to explain the dielectric properties of h-NBT-PVDF composite. Furthermore, the remnant polarization of the un-poled h-NBT-PVDF composites (2[Formula: see text]Pr–1.19[Formula: see text][Formula: see text]C/cm2 for 40[Formula: see text]wt.% of h-NBT) is also improved. The present findings give an idea of high dielectric constant and relatively low loss composite materials as a promising candidate for electronic and energy storage devices.


Polymer ◽  
2021 ◽  
Vol 214 ◽  
pp. 123349
Author(s):  
N. Pereira ◽  
S. Gonçalves ◽  
J.C. Barbosa ◽  
R. Gonçalves ◽  
C.R. Tubio ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document