High energy density of BaTiO3@TiO2 nanosheet/polymer composites via ping-pong-like electron area scattering and interface engineering

Dielectric substances exhibit great potential for high-power capacitors due to their high stability and fast charge–discharge; however, a long-term challenge is to enhance energy density. Here, we propose a poly(vinylidene fluoride) (PVDF) composite utilizing BaTiO3 nanoparticle@TiO2 nanosheet (BT@TO ns) 2D nanohybrids as fillers, aiming at combining the interfacial strategy of using a core–shell filler and the electron scattering of a 2D filler to improve the energy density. With 4 wt% filler, the composite possesses the largest breakdown strength (Eb) of 561.2 MV m−1, which is significantly enhanced from the 407.6 MV m−1 of PVDF, and permittivity of 12.6 at 1 kHz, which is a 23% increase from that of PVDF. A superhigh energy density of 21.3 J cm−3 with an efficiency of 61% is obtained at 550 MV m−1. The 2D BT@TO ns-filled composite exhibits a higher energy density than composites filled with core–shell 1D BT@TO nws or non-core–shell 0D BT, 1D TO, or 2D TO particles. The Eb and energy density improvements are attributed to the buffer layer-based interface engineering and enhanced area scattering of electrons caused by the 2D hybrids, an effect similar to that of a ping-pong paddle to scatter electric field-induced charge migrations in composites. Thus, an effective hybrid strategy is presented for achieving high-performance polymer composites that can be used in energy storage devices.

Improved Dielectric Properties and Energy Storage Densities of BaTiO3 Doped PVDF Composites by Heat Treatment and Surface Modification of BaTiO3

The dielectric properties of barium titanate/polyvinylidene fluoride (BT/PVDF) composites are investigated. The doped BT particles are prepared by using simple heat treatment. It is found that 1000 ℃ is the optimal temperature for the doped BT particles to improve the dielectric properties of BT/PVDF composites. Besides, we also find that the breakdown strength of the BT/PVDF composites can be significantly enhanced when the surface of the doped BT particles are pre-modified with phthalic acid or KH550. In particular, the BT/PVDF composites doped with KH550 modified BT particles have the maximum energy storage density of 4.08 J/cm3, which is 81.33 % higher than that of BT/PVDF composites doped with BT particles and without any treatment. Therefore, we can conclude that heat treatment and surface modification of doped BT particles could become new approaches to enhance the energy storage performance of the BT/PVDF composites, which has a good application prospect in the field of dielectric energy storage materials.

Diamond/GaN HEMTs: Where from and Where To?

Gallium nitride is a wide bandgap semiconductor material with high electric field strength and electron mobility that translate in a tremendous potential for radio-frequency communications and renewable energy generation, amongst other areas. However, due to the particular architecture of GaN high electron mobility transistors, the relatively low thermal conductivity of the material induces the appearance of localized hotspots that degrade the devices performance and compromise their long term reliability. On the search of effective thermal management solutions, the integration of GaN and synthetic diamond with high thermal conductivity and electric breakdown strength shows a tremendous potential. A significant effort has been made in the past few years by both academic and industrial players in the search of a technological process that allows the integration of both materials and the fabrication of high performance and high reliability hybrid devices. Different approaches have been proposed, such as the development of diamond/GaN wafers for further device fabrication or the capping of passivated GaN devices with diamond films. This paper describes in detail the potential and technical challenges of each approach and presents and discusses their advantages and disadvantages.

Probing the Use of Silane-Grafted Fumed Silica Nanoparticles to Produce Stable Transformer Oil-Based Nanofluids

In this experimental investigation, hydrophobic silane-grafted fumed nano-silica was employed in transformer oil to formulate nanofluids (NFs). A cold-air atmosphere-pressure plasma reactor working on the principle of dielectric barrier discharge was designed and utilized to functionalize the surface of these nanoparticles. A field emission scanning electron microscope (FE-SEM) coupled with energy-dispersive X-ray (EDX) module and Fourier transform infrared (FTIR) spectroscopy were used to scan surface features of new and plasma-treated nanoparticles. The study revealed considerable changes in the surface chemistry of nanoparticles, which led to good dispersibility and stability of nanofluids. The measurements of AC breakdown voltages (AC-BDV) of nanofluids so prepared were conducted according to IEC-Std 60156, and a significant improvement in the dielectric strength was achieved. A statistical analysis of these results was performed using Weibull probabilistic law. At a 5% probability of failure, modified nanofluid remarkably exhibited a 60% increase in breakdown voltage. The dielectric properties such as variation of εr and tan δ in temperature of up to 70 °C were measured and compared with untreated fluid. Results exhibit an increase in tan δ and a slight decrease in permittivity of nanofluids. The analysis also revealed that while unpolar silane coating of NPs increased the breakdown strength, the polar-amino-silane-coated NPs in oil resulted in a drastic reduction. Details of this antagonistic trend are elaborated in this paper.

Dielectric Strength of Polymeric Solid–Solid Interfaces under Dry-Mate and Wet-Mate Conditions

One of the most important causes of insulation system failure is the breakdown of the interface between two solid dielectrics; understanding the mechanisms governing this breakdown phenomenon is therefore critical. To that end, investigating and reviewing the practical limitations of the electrical breakdown strength of solid–solid interfaces present in insulating components is the primary objective of this work. The published literature from experimental and theoretical studies carried out in order to scrutinize the effects of the presence of solid–solid interfaces is investigated and discussed, considering macro, micro, and nano-scale characteristics. The reviewed literature suggests that solid–solid interfaces in accessories have non-uniform distributions of electrical fields within them in comparison to cables, where the distribution is mostly radial and symmetrical. Many agree that the elastic modulus (elasticity), radial/tangential pressure, surface smoothness/roughness, and dielectric strength of the ambient environment are the main parameters determining the tangential AC breakdown strength of solid–solid interfaces.