Study on Wet Treatment Process of Waste Printed Circuit Boards

2012 ◽  
Vol 518-523 ◽  
pp. 3621-3626
Author(s):  
Cai Bin Wu ◽  
Gui Ming Shi ◽  
Cui Ping Yan

The dry crushing of wasted printed circuit boards (PCBs) can make secondary contamination. In this paper, a wet comminution process is put forward to solve the difficulties. For the comminution product, the distributions of particle size, liberation degree and metal grade are analyzed, and for the product below 1mm, a wet metal beneficiation process combined with shaking table and flotation is employed. The results show that the Whole PCBs could be comminuted by the MX wet impact crusher, and the cumulative yield, liberation degree, total metal content and its copper grade of the product below 1mm is 83.49%, 97%, 83.46% and 20.50%respectively, and that metal concentrates could be beneficiated by XZY wet shaking table, and the yield, total metal weight, copper grade of the metal concentrate, the recovery of total metal and copper is 34.87%, 88.99%, 50.73%,79.90% and 78.07% respectively keeping the feeding concentration at 20% and water consumption in 1100L/h. For these metals included by shaking-table middling, the separation of both flotation and shaking table is carried out, and the total metal content and its copper grade, recovery in metal concentrate 2′ is 72.07% , 31.59% and62.04% respectively, meanwhile the copper grade of tailings in flotation and shaking table are decreased to 1.26% and 2.94%. The wet treatment process can effectively concentrate these valuable metals from waste PCBs.

2021 ◽  
Vol 1 (1) ◽  
Author(s):  
Anna HOŁDA ◽  
Aldona KRAWCZYKOWSKA

Technological innovations and increased demand for electronic devices resulted in production of more and more waste with highmetal content. Worldwide, 50 million tons of WEEE (Waste from Electrical and Electronic Equipment) are generated each year. Giventhe metal content present in electrical waste (e-waste), it is considered to be an urban mine and, if properly treated, can serve as analternative secondary source of metals. Waste printed circuit boards (WPCBs) that constitute approx. 3-5% of WEEE by weight areof particular importance. They contain, on average, 30-40% of metals by weight, with higher purity than in minerals. With environmental and economic benefits in mind, increasing attention is being paid to the development of processes to recover metals and othervaluable materials from WPCBs. The research presented in the article aimed at assessing the usefulness of the biotechnological methodfor leaching of selected metals from e-waste. The results indicate that it is possible to mobilize metals from WPCBs using microorganisms such as Acidithiobacillus ferroxidans bacteria 


2014 ◽  
Vol 675-677 ◽  
pp. 698-703 ◽  
Author(s):  
Wei Liu ◽  
Chao Liang ◽  
Wen Qing Qin ◽  
Fen Jiao

Recycling of metallic fractions from waste printed circuit boards (PCBs) using gravity separation and hydrometallurgy was investigated. The obtained research fruits were listed as follows: (1) When being pulverized to finer than 0.4mm, waste PCBs could be generally dissociated from plastics. (2) Shaking table was shown to be suitable for processing pulverized PCBs. Pulverized PCBs containing 6.97% copper was enriched to 33.55% in a single operation and the copper recovery was 90.3% in the best size range of separation. (3) Pressure oxidation leaching was shown to be effective for separating copper from aluminum and tin. The leaching extraction of aluminum and tin were 86.6% and 96.3%, copper extraction was 1% or less under the optimal conditions.


Metals ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 1511
Author(s):  
Dagmar Remeteiová ◽  
Silvia Ružičková ◽  
Vladislava Mičková ◽  
Martina Laubertová ◽  
Róberta Slezáková

Metal content determination is one of the critical aspects of preparing electronic waste for metal recycling. In spite of the fact that end-of-life printed circuit boards are considered to be a secondary resource reservoir, no standard procedure exists for determining the total metal content in this heterogeneous multicomponent material containing plastics, metals, alloys and ceramics. We investigated the utilization of United States Environmental Protection Agency (US EPA) microwave acid digestion (Method 3052) and various modifications of this procedure for effective releasing of Cu, Fe, Ni, Pb and Zn from waste printed circuit boards (WPCBs) from mobile phones. The maximum contents of Cu (22.6 wt.%), Fe (5.0 wt.%), Ni (2.0 wt.%) and Zn (2.6 wt.%) were obtained using the standard (unmodified) US EPA 3052 digestion procedure, but the total digestion of PCB material was not achieved. The solid residue material after digestion by means of the US EPA 3052 method consisted predominantly of oxides (Ca, Mg and Al) and fluorides (Ca and Mg), and some particles contained minor amounts of Fe and Cu.


2014 ◽  
Vol 13 (10) ◽  
pp. 2601-2607 ◽  
Author(s):  
Jae-chun Lee ◽  
Manoj Kumar ◽  
Min-Seuk Kim ◽  
Jinki Jeong ◽  
Kyoungkeun Yoo

JOM ◽  
2020 ◽  
Author(s):  
Joona Rajahalme ◽  
Siiri Perämäki ◽  
Roshan Budhathoki ◽  
Ari Väisänen

AbstractThis study presents an optimized leaching and electrowinning process for the recovery of copper from waste printed circuit boards including studies of chemical consumption and recirculation of leachate. Optimization of leaching was performed using response surface methodology in diluted sulfuric acid and hydrogen peroxide media. Optimum leaching conditions for copper were found by using 3.6 mol L−1 sulfuric acid, 6 vol.% hydrogen peroxide, pulp density of 75 g L−1 with 186 min leaching time at 20°C resulting in complete leaching of copper followed by over 92% recovery and purity of 99.9% in the electrowinning. Study of chemical consumption showed total decomposition of hydrogen peroxide during leaching, while changes in sulfuric acid concentration were minor. During recirculation of the leachate with up to 5 cycles, copper recovery and product purity remained at high levels while acid consumption was reduced by 60%.


2021 ◽  
Vol 9 (5) ◽  
pp. 895
Author(s):  
Carlotta Alias ◽  
Daniela Bulgari ◽  
Fabjola Bilo ◽  
Laura Borgese ◽  
Alessandra Gianoncelli ◽  
...  

A low-energy paradigm was adopted for sustainable, affordable, and effective urban waste valorization. Here a new, eco-designed, solid-state fermentation process is presented to obtain some useful bio-products by recycling of different wastes. Urban food waste and scraps from trimmings were used as a substrate for the production of citric acid (CA) by solid state fermentation of Aspergillus niger NRRL 334, with a yield of 20.50 mg of CA per gram of substrate. The acid solution was used to extract metals from waste printed circuit boards (WPCBs), one of the most common electronic waste. The leaching activity of the biological solution is comparable to a commercial CA one. Sn and Fe were the most leached metals (404.09 and 67.99 mg/L, respectively), followed by Ni and Zn (4.55 and 1.92 mg/L) without any pre-treatments as usually performed. Commercial CA extracted Fe more efficiently than the organic one (123.46 vs. 67.99 mg/L); vice versa, biological organic CA recovered Ni better than commercial CA (4.55 vs. 1.54 mg/L). This is the first approach that allows the extraction of metals from WPCBs through CA produced by A. niger directly grown on waste material without any sugar supplement. This “green” process could be an alternative for the recovery of valuable metals such as Fe, Pb, and Ni from electronic waste.


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