The Effect of Appending of I-，Fe2+ and MnO4- to the Electro-Oxidation of Methanol on Platinum Electrode

Three kinds of ions (I-、Fe2+and MnO4-) were appended into the methanol aqueous solution respectively as an additive and the Cyclic voltammograms of the aqueous solutions were studied. The results showed that Fe2+had obvious promotion effect for electro-oxidation of methanol and could improve the methanol anodic oxidation current by 85 percent. The promotion effect of the thulium Ions were related with the electronic distribution of these elements and their adsorption on the Pt electrode surface. I-and MnO4-could facilitate the electro-oxidation of methanol at different extent.

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The Influence of Platinum Electrode Surface on the Electroadsorption and Electro‐Oxidation of Methanol in Acid Solutions

Journal of The Electrochemical Society ◽

10.1149/1.2119943 ◽

1983 ◽

Vol 130 (6) ◽

pp. 1305-1312 ◽

Cited By ~ 24

Author(s):

E. P. M. Leiva ◽

M. C. Giordano

Keyword(s):

Electrode Surface ◽

Platinum Electrode ◽

Acid Solutions ◽

Oxidation Of Methanol ◽

Electro Oxidation

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Mechanism of electro-oxidation of methanol on the platinum electrode

Electrochimica Acta ◽

10.1016/0013-4686(67)80047-1 ◽

1967 ◽

Vol 12 (9) ◽

pp. 1323-1343 ◽

Cited By ~ 300

Author(s):

V.S. Bagotzky ◽

Yu.B. Vassilyev

Keyword(s):

Platinum Electrode ◽

Oxidation Of Methanol ◽

Electro Oxidation

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Electrochemical Properties of Lithium Titanate Synthesized by Reassembly of Nanosheets

Key Engineering Materials ◽

10.4028/www.scientific.net/kem.350.139 ◽

2007 ◽

Vol 350 ◽

pp. 139-142 ◽

Cited By ~ 1

Author(s):

Keigo Sato ◽

Shinya Suzuki ◽

Masaru Miyayama

Keyword(s):

Crystal Structure ◽

Aqueous Solution ◽

Ion Exchange ◽

Electrochemical Properties ◽

Discharge Capacity ◽

Lithium Titanate ◽

Parent Material ◽

Cyclic Voltammograms ◽

Oxidation Current ◽

Titanate Nanosheets

The electrochemical properties of titanate nanosheets and layer-structured lithium titanate obtained by restacking of titanate nanosheets were investigated in comparison with those of layer-structured lithium titanate obtained by ion-exchange. Restacked lithium titanate was synthesized by reassembling titanate nanosheets with LiOH aqueous solution. The nanosheets were 50-200 nm wide and 1.7 nm thick. The crystal structure inside the nanosheets was the same as that the of parent material. The oxidation current peaks observed in cyclic voltammograms of titanate nanosheets and restacked material were 1.6 V (Li/Li+), which was lower than that of ion-exchanged material by 0.3 V. The discharge capacity of restacked material was 96 mAh g-1, indicating that 32% of the titanium ions were reduced.

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Electro-reduction of oxygen and electro-oxidation of methanol at Pd monolayer-modified macroporous Pt electrode

Journal of Applied Electrochemistry ◽

10.1007/s10800-009-9928-9 ◽

2009 ◽

Vol 39 (12) ◽

pp. 2409-2414 ◽

Cited By ~ 7

Author(s):

Yongling Du ◽

Kangle Lv ◽

Biquan Su ◽

Nuo Zhang ◽

Chunming Wang

Keyword(s):

Pt Electrode ◽

Oxidation Of Methanol ◽

Electro Oxidation

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Size effects of platinum particles on the electro-oxidation of methanol in an aqueous solution of HClO4

Electrochemistry Communications ◽

10.1016/s1388-2481(00)00101-6 ◽

2000 ◽

Vol 2 (9) ◽

pp. 671-674 ◽

Cited By ~ 103

Author(s):

Yoshio Takasu ◽

Tomoya Iwazaki ◽

Wataru Sugimoto ◽

Yasushi Murakami

Keyword(s):

Aqueous Solution ◽

Size Effects ◽

Oxidation Of Methanol ◽

Platinum Particles ◽

Electro Oxidation

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Preparation of highly crystalline graphitic nanocarbon for the electro-oxidation of methanol

Nano Research ◽

10.1007/s12274-010-0053-1 ◽

2010 ◽

Vol 4 (1) ◽

pp. 92-102 ◽

Cited By ~ 5

Author(s):

Ji Bong Joo ◽

Nam Dong Kim ◽

Hyeong Jin Yun ◽

Pil Kim ◽

Jongheop Yi

Keyword(s):

Oxidation Of Methanol ◽

Electro Oxidation

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Electro-Oxidation of Methanol and Ethanol on Poly(3,4-Ethylenedioxythiophene) with Dispersed Pt, Pt+ Sn, and Pt+ Pb Particles

Fuel Cells ◽

10.1002/fuce.200320242 ◽

2003 ◽

Vol 3 (12) ◽

pp. 8-14 ◽

Cited By ~ 22

Author(s):

S. Biallozor ◽

A. Kupniewska ◽

V. Jasulaitene

Keyword(s):

Oxidation Of Methanol ◽

Electro Oxidation

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The influence of different co-catalysts in Pt-based ternary and quaternary electro-catalysts on the electro-oxidation of methanol and ethanol in acid media

Journal of Electroanalytical Chemistry ◽

10.1016/j.jelechem.2012.01.006 ◽

2012 ◽

Vol 668 ◽

pp. 13-25 ◽

Cited By ~ 14

Author(s):

Giancarlo R. Salazar-Banda ◽

Katlin I.B. Eguiluz ◽

Marilia M.S. Pupo ◽

Hugo B. Suffredini ◽

Marcelo L. Calegaro ◽

...

Keyword(s):

Acid Media ◽

Co Catalysts ◽

Oxidation Of Methanol ◽

Electro Oxidation

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Electro-catalysis of carbon black or titanium sub-oxide supported Pd–Gd towards formic acid electro-oxidation

RSC Advances ◽

10.1039/c6ra13097f ◽

2016 ◽

Vol 6 (73) ◽

pp. 68989-68996 ◽

Cited By ~ 13

Author(s):

Nan He ◽

Chuanguang Qin ◽

Rumin Wang ◽

Shuhui Ma ◽

Yi Wang ◽

...

Keyword(s):

Aqueous Solution ◽

Carbon Black ◽

Formic Acid ◽

Sodium Borohydride ◽

Weight Percent ◽

Reduction Reaction ◽

Simultaneous Reduction ◽

Electro Catalysis ◽

Electro Oxidation ◽

Supported Pd

Carbon black supported Pd–Gd catalysts (Pd–xGd/C, x is weight percent in catalyst) with different amounts of Gd were prepared by a simultaneous reduction reaction with sodium borohydride in aqueous solution.

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