Shifting τf Value of (Mg0.95Co0.05)TiO3 Ceramics by Ca0.61Nd0.78/3TiO3 Addition

2013 ◽  
Vol 807-809 ◽  
pp. 2703-2706
Author(s):  
Ping Cheng Chen ◽  
Chung Long Pan ◽  
Wei Cheng Lin ◽  
Chun Hsu Shen

Modification of (Mg0.95Co0.05)TiO3ceramics by Ca0.61Nd0.78/3TiO3addition was investigated. The Ca0.61Nd0.78/3TiO3content plays a significant role in improving the dielectric properties. Microwave dielectric measurement showed an increase in dielectric constant (εr) and temperature coefficient of the resonant frequency (τf) and a decrease inQvalue with increasing Ca0.61Nd0.78/3TiO3content. By properly adjusting the Ca0.61Nd0.78/3TiO3content, zero temperature coefficient of resonate frequencyτfcan also be obtained. It becomes more promising in the application of wireless system.At 1375°C, the 0.85(Mg0.95Co0.05)TiO3-0.15Ca0.61Nd0.78/3TiO3ceramics possesses excellent microwave dielectric properties: a dielectric constant εr of 24.37, aQfvalue of 66200 ( at 7 GHz ) and a τf value of-1.4 ppm/°C.

1999 ◽  
Vol 14 (9) ◽  
pp. 3567-3570 ◽  
Author(s):  
Ji-Won Choi ◽  
Chong-Yun Kang ◽  
Seok-Jin Yoon ◽  
Hyun-Jai Kim ◽  
Hyung-Jin Jung ◽  
...  

The microwave dielectric properties of Ca[(Li1/3Nb2/3)1−xMx]O3−δ (M = Sn, Ti, 0 ≤ x ≤ 0.5) ceramics were investigated. In general, the ceramics prepared were multiphase materials. However, single-phase specimens having orthorhombic perovskite structure similar to CaTiO3 could be obtained in the vicinity of Sn = 0.2 to 0.3, and Ti = 0.2. As Sn concentration increased, the dielectric constant (εr) decreased and the quality factor (Q) significantly increased within the limited Sn concentration. As Ti concentration increased, the dielectric constant (εr) increased, the quality factor (Q) decreased, and the temperature coefficient of resonant frequency (τf) changed from a negative to positive value. The temperature coefficient of resonant frequency of 0 ppm/°C was realized at Ti = 0.2. The Q · fo value and εr for this composition were found to be 26100 GHz and 38.6, respectively.


2001 ◽  
Vol 16 (7) ◽  
pp. 2053-2056
Author(s):  
X. J. Lu ◽  
X. M. Chen

Modification of Pb0.5Ca0.5[(Mg1/3Nb2/3)0.5Ti0.5]O3 dielectric ceramics was performed by up to 20 mol% La substitution for Pb and Ca. The temperature coefficient of dielectric constant was significantly reduced by the present approach, while an increased Qf factor was achieved. Good microwave dielectric properties were obtained in a composition Pb0.425Ca0.425La0.1[(Mg1/3Nb2/3)0.5Ti0.5]O3: ε = 125; Qf = 3150 GHz; calculated temperature coefficient of resonant frequency δf = +253 ppm/°C.


2007 ◽  
Vol 336-338 ◽  
pp. 279-282
Author(s):  
In Sun Cho ◽  
Sang Gu Kang ◽  
Dong Wan Kim ◽  
Kug Sun Hong

The effects of CuO and V2O5 addition on sintering behaviors and microwave dielectric properties of 0.7Ca2P2O7-0.3TiO2 ceramics were investigated. With CuO and V2O5 addition, the sintering temperature of 0.7Ca2P2O7-0.3TiO2 can be effectively reduced from 1150 to 950oC. The dielectric constant of the low fired 0.7Ca2P2O7-0.3TiO2 ceramics was not significantly changed while the quality factor was affected by additives. The temperature coefficient of resonant frequency value was increased in negative value with the additive contents. V2O5 and CuO additives effectively improved the densification and dielectric properties of 0.7Ca2P2O7-0.3TiO2 ceramics. The correlation between the phase constituents and the dielectric properties was investigated with additive contents.


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