Ring-Opening Polymerization of Lactide Using Aluminum Salen-Type Initiators
2014 ◽
Vol 915-916
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pp. 713-716
Keyword(s):
In this investigation, Schiff bases aluminum complex was synthesized and used as the initiator in the polymerization of D,L-lactide. The aluminum complex was characterized by infrared spectroscopy (IR), and nuclear magnetic resonance spectroscopy (NMR). The influences of different factors, including reaction time, reaction temperature, and the ratio of D, L-lactide/Al3+ on the synthesis of polylactide were described. The results showed that Schiff bases aluminum complex could be successfully applied in the ring opening polymerization. The optimum condition of the ring opening polymerization of D,L-lactide, which included D,L-lactide/Al3+ (mol/mol) ratio of 250, reaction temperature of 120 °C, and reaction time of 16 hours.
2015 ◽
Vol 1095
◽
pp. 407-410
2014 ◽
Vol 703
◽
pp. 17-20
2020 ◽
2015 ◽
Vol 1095
◽
pp. 345-348
2000 ◽
Vol 77
(5)
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pp. 489-493
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2019 ◽
Vol 7
(1)
◽
pp. 1-9
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2011 ◽
Vol 354
(1)
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pp. 261-267
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