Calculations of Iron Diffusion Coefficients - High-Temperature Oxidation in Air in a Cylindrical Geometry

2001 ◽  
Vol 194-199 ◽  
pp. 1719-1724
Author(s):  
Zbigniew Jurasz ◽  
Marek Danielewski ◽  
Robert Filipek
2012 ◽  
Vol 323-325 ◽  
pp. 289-294
Author(s):  
Patrice Berthod ◽  
Lionel Aranda

Thermogravimetry measurements associated to concentration profiles allow determining a diffusion coefficient at high temperature of the most oxidable one among the metallic elements belonging to the chemical composition of an alloy. In this work the employed method is described and applied to chromia-forming alloys essentially based on nickel but also to selected cobalt-based and iron-based alloys. More precisely DCrvalues were estimated for chromium diffusing through the carbide-free zones developed during high temperature oxidation. The effects of the base element, of the chromium carbides density and of the dendritic orientations on the chromium diffusion were evidenced.


2010 ◽  
Vol 65 ◽  
pp. 106-111
Author(s):  
Bai Cui ◽  
Rafael Sa ◽  
Daniel Doni Jayaseelan ◽  
Fawad Inam ◽  
Michael J. Reece ◽  
...  

Microstructural evolution of Ti2AlN ceramics during high-temperature oxidation in air has been revealed by X-ray diffraction (XRD), field emission gun scanning electron microscopy (FEGSEM), and energy-dispersive spectroscopy (EDS). After oxidation below 1200 °C, layered microstructures formed on Ti2AlN surfaces containing anatase, rutile, and α-Al2O3. Above 1200 °C, more complex layered microstructures formed containing Al2TiO5, rutile, α-Al2O3, and continuous void layers. With increasing temperature, anatase gradually transformed to rutile, and TiO2 reacted with α-Al2O3 to form Al2TiO5. Based on these microstructural observations, an oxidation mechanism for Ti2AlN ceramics is proposed.


2015 ◽  
Vol 465 ◽  
pp. 400-406 ◽  
Author(s):  
А.S. Kuprin ◽  
V.А. Belous ◽  
V.N. Voyevodin ◽  
V.V. Bryk ◽  
R.L. Vasilenko ◽  
...  

2006 ◽  
Vol 45 (9-10) ◽  
pp. 476-480 ◽  
Author(s):  
V. A. Lavrenko ◽  
A. I. Malyshevskaya ◽  
L. I. Kuznetsova ◽  
V. F. Litvinenko ◽  
V. N. Pavlikov

2014 ◽  
Vol 970 ◽  
pp. 248-251
Author(s):  
Ayeh Mohsenifar ◽  
Mohammad Reza Aboutalebi ◽  
S. Hossein Seyedein

Hot dip aluminizing of low carbon steel followed by high temperature oxidation in air was carried out to evaluate the dissolution rate of coated sample in molten aluminum. The microstructure of oxide and aluminide layers was investigated using scanning electron microscopy and X-ray diffraction methods. The characterization of the coating showed that Fe2Al5 has been the major phase formed on the surface of specimen before high temperature oxidation. Isothermal oxidation of the coating as resulted in the formation of Al2O3 while Fe2Al5 phase transformed into FeAl and Fe3Al phases. The coated samples were further subjected to corrosion in molten aluminum. It was proved that the oxide layer formed on the coating and developed FeAl and Fe3Al intermetallic phases play the major role in protecting the specimen from corrosion in molten aluminum.


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