Apatite-Forming Ability of Titanium Metal Enriched with Calcium Ion on its Surface

2007 ◽  
Vol 361-363 ◽  
pp. 581-584 ◽  
Author(s):  
Takashi Kizuki ◽  
Takahiro Kawai ◽  
Hiroaki Takadama ◽  
Tomiharu Matsushita ◽  
Tadashi Kokubo ◽  
...  
Keyword(s):  
Heat Treatment ◽  
Surface Layer ◽  
Calcium Ions ◽  
Calcium Ion ◽  
Titanium Metal ◽  
Exchange Method ◽  
Naoh Solution ◽  
Ion Exchange Method ◽  
Naoh Treatment ◽  
Cacl2 Treatment

In order to study method for preparing bioactive titanium metal, calcium ions were attempted to be incorporated into the surface of the titanium metal by ion exchange method. Titanium metal was soaked in 5M NaOH solution and 100mMCaCl2 solution and subjected to heat treatment. About 5 atom% of Na was incorporated into the surface of the titanium metal by the NaOH treatment This Na was completely replaced with calcium ion by the CaCl2 treatment and maintained even after the heat treatment. Critical detaching strength of the surface layer to the substrate of NaOH-treated titanium metal was a little increased by the CaCl2 treatment and remarkably increased by the heat treatment. Apatite-forming ability of the NaOH-treated titanium metal in SBF was increased by the CaCl2 treatment, but decreased by the subsequent heat treatment.

Improvement of Apatite-Forming Ability of Tantalum Metal by CaCl2 Treatment

2007 ◽  
Vol 361-363 ◽  
pp. 681-684
Author(s):  
Deepak K. Pattanayak ◽  
Tomiharu Matsushita ◽  
Hiroaki Takadama ◽  
Tadashi Kokubo ◽  
Takashi Nakamura
Keyword(s):  
Heat Treatment ◽  
Simulated Body Fluid ◽  
Body Fluid ◽  
Edx Analysis ◽  
Na Ions ◽  
Naoh Treatment ◽  
Tantalum Metal ◽  
Cacl2 Treatment ◽  
Xrd Patterns

Tantalum metal was soaked in NaOH and CaCl2 solutions, and then subjected to heat treatment at 500°C. EDX analysis showed that about 6.5 at. % of Na was incorporated into the surface of the tantalum metal by the first NaOH treatment. These Na+ ions were replaced by Ca2+ ions by the subsequent CaCl2 treatment. According to TF-XRD patterns, an amorphous sodium tantalate was seemed to be formed on the tantalum metal by the NaOH treatment and transformed into amorphous calcium tantalate by the CaCl2 treatment. This phase was crystallized into Ca2Ta2O7 by heat treatment. Critical detaching load of the surface of the CaCl2-treated tantalum metal was as low as 5mN, while as high as 42mN after the heat treatment. Apatite-forming ability of the NaOH-treated tantalum metal in a simulated body fluid (SBF) was appreciably increased by the CaCl2 treatment and maintained even after the heat treatment.

A highly efficient Fe-Ni-S/NF hybrid electrode for promoting oxygen evolution performance

2021 ◽  
Author(s):  
YuYun Chen ◽  
Yang Xu ◽  
Shuai Niu ◽  
Jun Yan ◽  
Ye-Yu Wu ◽  
...  
Keyword(s):  
Ion Exchange ◽  
Oxygen Evolution ◽  
Hierarchical Structure ◽  
Alkaline Solution ◽  
Exchange Method ◽  
Highly Efficient ◽  
Ion Exchange Method

In this study, a Fe-Ni-S/NF hybrid electrode with hierarchical structure was fabricated via a simple hydrothermal and ion exchange method, which exhibits remarkable OER performance in alkaline solution with an...

Preparation of BiOCl/Bi2S3 composites by simple ion exchange method for highly efficient photocatalytic reduction of Cr6+

2020 ◽  
Vol 506 ◽  
pp. 145000 ◽  
Author(s):  
Yun Lu ◽  
Jimei Song ◽  
Wenfang Li ◽  
Yali Pan ◽  
Huiyao Fang ◽  
...  
Keyword(s):  
Ion Exchange ◽  
Photocatalytic Reduction ◽  
Exchange Method ◽  
Highly Efficient ◽  
Ion Exchange Method

Enantioselective oxidation of sulfide to sulfoxide on Ti-containing mesoporous silica prepared by a template-ion exchange method

2001 ◽  
Vol 48 (1-3) ◽  
pp. 271-277 ◽  
Author(s):  
Masakazu Iwamoto ◽  
Yasuhiro Tanaka ◽  
Jiro Hirosumi ◽  
Nozomu Kita ◽  
Sugeng Triwahyono
Keyword(s):  
Ion Exchange ◽  
Mesoporous Silica ◽  
Exchange Method ◽  
Enantioselective Oxidation ◽  
Ion Exchange Method
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