Dielectric Properties of Zr-Doped CaCu3Ti4O12 Ceramics

2008 ◽  
Vol 368-372 ◽  
pp. 129-131
Author(s):  
Yong He ◽  
Ke Pi Chen ◽  
Dong Yu Liu ◽  
Zong De Liu
Keyword(s):  
Dielectric Constant ◽  
Dielectric Properties ◽  
Solid State ◽  
Impedance Spectroscopy ◽  
Solid State Reaction ◽  
Solid State Reaction Method ◽  
Conventional Solid State Reaction ◽  
Obvious Effect ◽  
Reaction Method ◽  
Microstructure Characteristic

CaCu3(Ti1-xZrx)O12 ceramics (x = 0.02, 0.04, 0.06, 0.08) were prepared by the conventional solid-state reaction method. Phase compositions, microstructure and dielectric properties were examined by XRD, SEM and impedance spectroscopy, respectively. The experimental results indicated that there is no obvious effect on microstructure characteristic by substituting Zr4+ for Ti4+. It was found that the values of the dielectric constant for all of the samples dropped into the order of 102, which is significantly lower than the order of 105 that of normally reported in the literature. It was suggested that the presence of impurity phases played an important role for the degeneracy of dielectric properties.

Study on the Property of Bi2(Mg2/3Nb1.1833Sn0.15)O7 Dielectric Ceramics Doped with Li2CO3

2012 ◽  
Vol 549 ◽  
pp. 749-752
Author(s):  
Hai Tang Hua ◽  
Xin You Huang ◽  
Zhi Wen Zhu ◽  
Yin Qun Hua ◽  
Yan Li
Keyword(s):  
Dielectric Constant ◽  
Dielectric Properties ◽  
Solid State ◽  
Dielectric Loss ◽  
Solid State Reaction ◽  
Piezoelectric Ceramics ◽  
Solid State Reaction Method ◽  
Conventional Solid State Reaction ◽  
Reaction Method ◽  
Dielectric Ceramics

(Bi2-xLix) (Mg2/3Nb1.1833Sn0.15)O7 piezoelectric ceramics were prepared by conventional solid state reaction method. The microstructure and dielectric properties of dielectric ceramics were studied which was doped by different amount of Li2CO3. The experiment results showed that the density of the ceramics would decrease, but have little effect on the microstructure of the ceramics when the amount of the Li2CO3 doped increases. With the increasing of Li2CO3 doped, the dielectric constant(εr) and dielectric loss(tanδ) of dielectric ceramics first decreases and then increases. When tested in 1MHz frequency, the piezoelectric ceramics display the optimum properties tanδ is 0.00009, εr is 163 while Li2CO3 doped amount is 0.05 mol%.

Dielectric Properties of Ba(Mg0.2/3Zn0.8/3Nb2/3)O3 and Ba1-xSrx(Mg0.2/3Zn0.8/3Nb2/3)O3 Microwave Ceramics

2007 ◽  
Vol 336-338 ◽  
pp. 272-274
Author(s):  
S.S. Cheng ◽  
J. Luo ◽  
Zhao Xian Xiong
Keyword(s):  
Dielectric Properties ◽  
Solid State ◽  
Resonant Frequency ◽  
Solid State Reaction ◽  
Solid State Reaction Method ◽  
Zero Temperature ◽  
Microwave Ceramics ◽  
Conventional Solid State Reaction ◽  
Reaction Method ◽  
Zn Ions

Microwave ceramics of Ba(Mg0.2/3Zn0.8/3Nb2/3)O3 and Ba1-xSrx(Mg0.2/3Zn0.8/3Nb2/3)O3 were synthesized with conventional solid-state reaction method. Dielectric properties of the samples were studied as functions of compositions and sintering temperatures. Experimental results show that a higher Q×f value is reached by substituting Zn ions with Mg ions and a near-zero temperature coefficient of resonant frequency is obtained by replacing Ba ions with Sr ions.

Effects of Mg2SiO4 Addition on the Microstructure and Dielectric Properties of MgTiO3-CaTiO3 Ceramics

2013 ◽  
Vol 675 ◽  
pp. 200-204
Author(s):  
Fei Shi ◽  
Peng Cheng Du ◽  
Jing Xiao Liu ◽  
Ji Wei Wu ◽  
De Qing Chen ◽  
...  
Keyword(s):  
Dielectric Constant ◽  
Dielectric Properties ◽  
Solid State ◽  
Dielectric Loss ◽  
Solid State Reaction ◽  
Sintering Temperature ◽  
Solid State Reaction Method ◽  
Composite Ceramics ◽  
Reaction Method ◽  
Dielectric Ceramics

The Mg2SiO4-MgTiO3-CaTiO3 composite dielectric ceramics with different Mg2SiO4 addition amounts were prepared by solid state reaction method. The effects of Mg2SiO4 addition amounts on the microstructure and dielectric properties as well as sintering temperature of xMg2SiO4-(0.95-x)MgTiO3-0.05CaTiO3 (abbreviated as xMSTC, 0.25≦x≦0.75) composite ceramics were investigated. The results indicated that the sintering temperature of MgTiO3-CaTiO3 based ceramics with Mg2SiO4 addition could be lowered effectively to 1320~1340°C, and the dielectric constant decreased and dielectric loss increased gradually with the increase of Mg2SiO4 content. The 0.45MSTC ceramics containing 45 wt% Mg2SiO4 and sintered at 1340°C showed desirable dielectric properties with dielectric constant εr=13.3，dielectric loss tanδ=4.5×10-4 and temperature coefficient of relative permittivity τε =10 ppm/°C.

Structural, magnetic and dielectric properties of the Aurivillius phase Bi6Fe2−xMnxTi3O18 (0 ≤ x ≤ 0.8)

RSC Advances ◽  
2014 ◽  
Vol 4 (87) ◽  
pp. 46704-46709 ◽  
Author(s):  
Xuzhong Zuo ◽  
Jie Yang ◽  
Bin Yuan ◽  
Dongpo Song ◽  
Xianwu Tang ◽  
...  
Keyword(s):  
Dielectric Properties ◽  
Solid State ◽  
Solid State Reaction ◽  
Solid State Reaction Method ◽  
Aurivillius Phase ◽  
Conventional Solid State Reaction ◽  
Reaction Method ◽  
Magnetic And Dielectric Properties

The n = 5 Aurivillius phase ceramics Bi6Fe2−xMnxTi3O18 (BFMTO) (0 ≤ x ≤ 0.8) were synthesized with a conventional solid-state reaction method.

The Effect CuO Additive on the Microwave Dielectric Properties of Mg(Zr0.05Ti0.95)O3 Ceramics

2011 ◽  
Vol 687 ◽  
pp. 199-203 ◽  
Author(s):  
Ching Fang Tseng
Keyword(s):  
Dielectric Constant ◽  
Dielectric Properties ◽  
Solid State ◽  
Liquid Phase ◽  
Solid State Reaction ◽  
Microwave Dielectric Properties ◽  
Solid State Reaction Method ◽  
Reaction Method ◽  
Microwave Dielectric ◽  
Second Phases

The microwave dielectric properties of the Mg(Zr0.05Ti0.95)O3ceramics with CuO addition were investigated. All specimens were prepared by solid-state reaction method and sintered at 1270-1420°C for 4 h. When CuO was added, the second phases of MgTi2O5, TiO2and liquid phase were produced. For specimens with 1.5 wt% CuO sintered at 1300°C, the dielectric constant,Q´fand tfvalues are 18.2, 223000 GHz and -2 ppm/°C, respectively.

Extended dielectric constant step from −80 °C to 336 °C in the BaTiO3–BiYO3–Ba(Fe0.5Nb0.5)O3 system

RSC Advances ◽  
2016 ◽  
Vol 6 (6) ◽  
pp. 4296-4301 ◽  
Author(s):  
Yaru Wang ◽  
Yongping Pu ◽  
Hanyu Zheng ◽  
Qian Jin ◽  
Ziyan Gao
Keyword(s):  
Dielectric Constant ◽  
Solid State ◽  
Solid State Reaction ◽  
Solid State Reaction Method ◽  
Conventional Solid State Reaction ◽  
Reaction Method ◽  
System P

Polycrystalline 0.8BaTiO3–(0.2 − x)BiYO3–xBa(Fe0.5Nb0.5)O3 (0.8BT–(0.2− x)BY–xBFN) (x = 0–0.04) ceramics were fabricated via a conventional solid-state reaction method.

scholarly journals Relationship between structural and dielectric properties of Zn-substituted Ba5CaTi2−xZnxNb8O30 tetragonal tungsten bronze

CrystEngComm ◽  
2021 ◽  
Vol 23 (1) ◽  
pp. 163-173
Author(s):  
Amine Bendahhou ◽  
Pascal Marchet ◽  
Ablouh El-Houssaine ◽  
Soufian El Barkany ◽  
Mohamed Abou-Salama
Keyword(s):  
Dielectric Properties ◽  
Solid State ◽  
Solid State Reaction ◽  
Tungsten Bronze ◽  
Solid State Reaction Method ◽  
Conventional Solid State Reaction ◽  
Tetragonal Tungsten Bronze ◽  
Reaction Method

Ba5CaTi2−xZnxNb8O30 ceramics (x = 0, 0.04, and 0.08) were synthesized by a conventional solid-state reaction method at 1300 °C for 6 hours.

Effects of the Replacement of Ti by Zr on the Dielectric Properties of CaCu3Ti4012 Ceramics

2008 ◽  
Vol 368-372 ◽  
pp. 118-120 ◽  
Author(s):  
Jing Han You ◽  
Qing Dong Chen ◽  
Wei Wei Ju ◽  
Li Ben Li ◽  
Kai Chen
Keyword(s):  
Dielectric Constant ◽  
Dielectric Properties ◽  
Solid State ◽  
Dielectric Loss ◽  
Solid State Reaction ◽  
Solid State Reaction Method ◽  
Partial Replacement ◽  
Reaction Method ◽  
Two Samples ◽  
Comparison Of The Results

CaCu3Ti4O12 and CaCu3Ti3.9Zr0.1O12 ceramics were prepared by the traditional solid-state reaction method and the dielectric properties were investigated. Comparison of the results of the two samples examined indicated that the partial replacement of titanium by zirconium in the system CaCu3Ti4O12 may result in different changes of the dielectric constant and dielectric loss. For these experimental phenomena possible explanations and predictions also have been presented.

Effects of Mg2+ on Microstructure and Microwave Dielectric Properties of La2/3TiO3 Ceramics

2007 ◽  
Vol 280-283 ◽  
pp. 35-38 ◽  
Author(s):  
Ai Min Yang ◽  
Wei Chen ◽  
Lan Luo
Keyword(s):  
Dielectric Constant ◽  
Dielectric Properties ◽  
Solid State ◽  
Resonant Frequency ◽  
Microwave Dielectric Properties ◽  
Solid State Reaction Method ◽  
Conventional Solid State Reaction ◽  
Reaction Method ◽  
Microwave Dielectric ◽  
Maximum Permittivity

(1-x)La2/3TiO3-xLa(Mg1/2Ti1/2)O3 ceramics with x ranging from 0.01 to 0.3 were prepared by the conventional solid-state reaction method. Microstructure and microwave dielectric properties were studied. The perovskite compound La2/3TiO3 is stabilized when x = 0.1. The content of La2/3TiO3 increases with increasing x from 0.01 to 0.1, and thereafter decreases when x > 0.1. The same tendency was also observed on measuring the dielectric constant, temperature coefficient of resonant frequency and Q× ƒ. A maximum permittivity of 77.35 was achieved with these stabilized La2/3TiO3 ceramics. Close to zero τf value (1 ppm/°C) was obtained at x=0.3, but its Q× ƒ value was relative low.

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