Radiation-Induced-Defects Localization in Single-Mode Optical Fibers

2005 ◽  
Vol 480-481 ◽  
pp. 329-332 ◽  
Author(s):  
Sylvain Girard ◽  
A. Boukenter ◽  
Y. Ouerdane ◽  
J.-P. Meunier

We studied the defects at the origins of the permanent radiation-induced attenuation in four g-rays irradiated single-mode germanosilicate optical fibers (~1 MeV; 1.2 kGy; 0.3 Gy/s) in the spectral range 400 - 1700 nm. We determined the wavelength dependence of the following cladding codopant influences: germanium (0.3 %), phosphorus (0.3 %), fluorine (0.3 %) on the germanosilicate (13 %) fiber radiation responses. We identified some of the different color centers produced by g-rays and we evaluated their localization in the fiber cross-section through the determination of the radial distribution of the radiation-induced absorption at 633 nm. We also evidenced the strong interactions between these three codopants. In particular, our results showed that the properties of the phosphorus-related color centers, which mainly determine the fiber infrared radiation sensitivity, are strongly influenced by the germanium- and fluorine-codoping.

1985 ◽  
Vol 61 ◽  
Author(s):  
J. Simpson ◽  
J. Ritger ◽  
F. DiMarcello

ABSTRACTParamagnetic color centers have been observed in germanium silicate and germanium phosphosilicate multimode optical fiber exposed to broadband ultraviolet light (2–5 eV). These centers are characterized by an ESR and optical absorption similar to 1 meV and 100 keV radiation induced defects and show an apparent saturation as the UV dose approaches 100 J/cm2. The UV induced ESR spectra are not identical to that induced by 60Co radiation however, similar Ge(2) and Ge(3) germanium defect signatures are apparent. For both compositions these centers are characterized by a rapidly increasing loss from 1.0 to 0.5 µm with an additional broad absorption peak at 1.5 µm for the phosphorus containing cores. We suggest that the UV induced optical absorptions for both compositions in the short wavelength range are due in part to the Ge(2) germanium substitutional sites and expect that the 1.5 µm absorption is due to the P1 phosphorus oxygen vacancy.


1986 ◽  
Vol 88 ◽  
Author(s):  
T. Wei ◽  
M. P. Singh ◽  
W. J. Miniscalco ◽  
J. A. Wall

ABSTRACTWe have investigated the relationship of precursor defects in as-drawn optical fiber to glass composition and processing conditions in order to understand the radiation sensitivity of doped-core optical fiber. Techniques are reported for improving the radiation hardness of graded-index multimode fibers through reducing the concentration of doping- and processing-induced defects as well as modifying the residual defects in as-drawn fiber. Significant decreases in radiation-induced loss have been observed for fibers pretreated with hydrogen. An investigation of the role of drawing-induced defects indicates that a lower draw temperature produces slightly harder fiber. A study of core/clad interfacial stress revealed that such stress does not play a major role in radiation sensitivity.Measurement techniques included in situ loss measurements at 850 nm and spectral loss measurements before and after -γ irradiation. In addition, photoluminescence proved to be an effective tool for characterizing specific defect centers. It was found for Ge/P-codoped fibers that the luminescence band at 650 nm attributed to drawing/radiation induced centers has an inverse correlation with induced loss. Previously unreported emission bands have been observed, including one at 720 nm which may be related to fluorine doping.


1991 ◽  
Vol 244 ◽  
Author(s):  
E. J. Friebele ◽  
C. G. Askins ◽  
M. A. Putnam ◽  
C. C. Harrington ◽  
M. E. Gingerich ◽  
...  

ABSTRACTThe effect of varying single mode fiber fabrication factors such as core and clad dopant concentrations, deposition conditions, and draw parameters on the recovery of the nuclear radiation-induced attenuation at 1.3 μm has been studied. Statistically significant correlations of core factors have been established with a 24 experimental design, and separate one-dimensional experiments revealed the effect of clad [Ge] and [F].


2020 ◽  
Vol 105 (7) ◽  
pp. 1051-1059
Author(s):  
José R. Toledo ◽  
Raphaela de Oliveira ◽  
Lorena N. Dias ◽  
Mário L.C. Chaves ◽  
Joachim Karfunkel ◽  
...  

Abstract Montebrasite is a lithium aluminum phosphate mineral with the chemical formula LiAlPO4(Fx,OH1–x) and considered a rare gemstone material when exhibiting good crystallinity. In general, montebrasite is colorless, sometimes pale yellow or pale blue. Many minerals that do not have colors contain hydroxyl ions in their crystal structures and can develop color centers after ionization or particle irradiation, examples of which are topaz, quartz, and tourmaline. The color centers in these minerals are often related to O− hole centers, where the color is produced by bound small polarons inducing absorption bands in the near UV to the visible spectral range. In this work, colorless montebrasite specimens from Minas Gerais state, Brazil, were investigated by electron paramagnetic resonance (EPR) for radiation-induced defects and color centers. Although γ irradiation (up to a total dose of 1 MGy) did not visibly modify color, a 10 MeV electron irradiation (80 MGy) induced a pale greenish-blue color. Using EPR, O− hole centers were identified in both γ- or electron-irradiated montebrasite samples showing superhyperfine interactions with two nearly equivalent 27Al nuclei. In addition, two different Ti3+ electron centers were also observed. From the γ irradiation dose dependency and thermal stability experiments, it is concluded that production of O− hole centers is limited by simultaneous creation of Ti3+ electron centers located between two equivalent hydroxyl groups. In contrast, the concentration of O− hole centers can be strongly increased by high-dose electron irradiation independent of the type of Ti3+ electron centers. From detailed analysis of the EPR angular rotation patterns, microscopic models for the O− hole and Ti3+ electron centers are presented, as well as their role in the formation of color centers discussed and compared to other minerals.


2014 ◽  
Author(s):  
B. Singleton ◽  
J. Petrosky ◽  
M. Pochet ◽  
N. G. Usechak ◽  
S. A. Francis

Sensors ◽  
2021 ◽  
Vol 21 (24) ◽  
pp. 8193
Author(s):  
Sohel Rana ◽  
Austin Fleming ◽  
Nirmala Kandadai ◽  
Harish Subbaraman

Neutron and gamma irradiation is known to compact silica, resulting in macroscopic changes in refractive index (RI) and geometric structure. The change in RI and linear compaction in a radiation environment is caused by three well-known mechanisms: (i) radiation-induced attenuation (RIA), (ii) radiation-induced compaction (RIC), and (iii) radiation-induced emission (RIE). These macroscopic changes induce errors in monitoring physical parameters such as temperature, pressure, and strain in optical fiber-based sensors, which limit their application in radiation environments. We present a cascaded Fabry–Perot interferometer (FPI) technique to measure macroscopic properties, such as radiation-induced change in RI and length compaction in real time to actively account for sensor drift. The proposed cascaded FPI consists of two cavities: the first cavity is an air cavity, and the second is a silica cavity. The length compaction from the air cavity is used to deduce the RI change within the silica cavity. We utilize fast Fourier transform (FFT) algorithm and two bandpass filters for the signal extraction of each cavity. Inclusion of such a simple cascaded FPI structure will enable accurate determination of physical parameters under the test.


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