Structural Investigation of the Photoinduced Spin Transition in the [Fe(PM-BiA)2(NCS)2] Compound

We investigated the thermo- and photo-induced phase transitions between low spin (LS) and high spin (HS) states of the molecular crystal of [Fe(PM-BiA)2(NCS)2] in the orthorhombic form, by using X-ray diffraction. The structure of the photoinduced HS state, generated from the LS state at low temperature, is compared to the structures of the HS and LS phases at thermal equilibrium and to the thermally trapped HS state. The preliminary results presented here show that the structural reorganization is similar in the different HS states.

Download Full-text

Low temperature x-ray diffraction study on phase transitions

Journal of Physics Conference Series ◽

10.1088/1742-6596/400/2/022118 ◽

2012 ◽

Vol 400 (2) ◽

pp. 022118

Author(s):

H Suzuki ◽

H Kaneko ◽

Y Xue ◽

N Shumsun ◽

A Savinkov ◽

...

Keyword(s):

Phase Transitions ◽

Low Temperature ◽

Diffraction Study ◽

X Ray Diffraction ◽

X Ray

Download Full-text

Low-temperature crystal structure of RS-thiocamphor

Zeitschrift für Kristallographie - Crystalline Materials ◽

10.1524/zkri.219.9.580.44038 ◽

2004 ◽

Vol 219 (9) ◽

Cited By ~ 1

Author(s):

E. Louise R. Robins ◽

Michela Brunelli ◽

Asiloé J. Mora ◽

Andrew N. Fitch

Keyword(s):

Crystal Structure ◽

Phase Transitions ◽

Low Temperature ◽

Room Temperature ◽

Cubic Phase ◽

X Ray Diffraction ◽

Orthorhombic Space Group ◽

Two Phase ◽

X Ray ◽

Low Temperature Crystal Structure

AbstractDSC and high-resolution powder X-ray diffraction measurements in the range 295 K–100 K show that RS-thiocamphor undergoes two phase transitions. The first, at around 260 K on cooling, is from the room-temperature body-centred-cubic phase to a short-lived intermediate. At 258 K the low-temperature form starts to appear. The crystal structure of the latter is orthorhombic, space group

Download Full-text

Phase transitions studied by ultra-low-temperature X-ray diffraction

Physica B Condensed Matter ◽

10.1016/j.physb.2003.11.063 ◽

2004 ◽

Vol 345 (1-4) ◽

pp. 239-242 ◽

Cited By ~ 3

Author(s):

H Suzuki ◽

Y Xue ◽

S Naher ◽

R Yamauchi ◽

S Asada ◽

...

Keyword(s):

Phase Transitions ◽

Low Temperature ◽

X Ray Diffraction ◽

X Ray

Download Full-text

Single crystal X-ray diffraction studies on [(CH3)nNH4–n]3[Sb2Cl9] (, 3) chloroantimonates(III) in their low-temperature ferroelectric phases—structures and phase transitions

Journal of Solid State Chemistry ◽

10.1016/j.jssc.2005.04.020 ◽

2005 ◽

Vol 178 (7) ◽

pp. 2237-2246 ◽

Cited By ~ 29

Author(s):

Maciej Bujak ◽

Ross J. Angel

Keyword(s):

Phase Transitions ◽

Low Temperature ◽

Single Crystal ◽

X Ray Diffraction ◽

X Ray

Download Full-text

Low-temperature structural phase transitions of TbB4 and ErB4 studied by high resolution X-ray diffraction and profile analysis

Journal of Physics and Chemistry of Solids ◽

10.1016/0022-3697(86)90078-8 ◽

1986 ◽

Vol 47 (7) ◽

pp. 651-658 ◽

Cited By ~ 19

Author(s):

Z. Heiba ◽

W. Schäfer ◽

E. Jansen ◽

G. Will

Keyword(s):

Phase Transitions ◽

High Resolution ◽

Low Temperature ◽

Profile Analysis ◽

Structural Phase ◽

Structural Phase Transitions ◽

X Ray Diffraction ◽

X Ray

Download Full-text

Low-temperature structural phase transitions of (NH4)3H(SeO4)2crystals studied by the X-ray diffraction

Phase Transitions ◽

10.1080/01411599208207742 ◽

1992 ◽

Vol 40 (1-4) ◽

pp. 95-103 ◽

Cited By ~ 5

Author(s):

R. H. Chen ◽

Shyh-Ching Chen

Keyword(s):

Phase Transitions ◽

Low Temperature ◽

Structural Phase ◽

Structural Phase Transitions ◽

X Ray Diffraction ◽

X Ray

Download Full-text

Low temperature x-ray diffraction study of the phase transitions in Sr1-xCaxTiO3 (x=0.02,0.04): Evidence for ferrielectric ordering

Applied Physics Letters ◽

10.1063/1.3273863 ◽

2009 ◽

Vol 95 (23) ◽

pp. 232910 ◽

Cited By ~ 7

Author(s):

Sanjay Kumar Mishra ◽

Dhananjai Pandey

Keyword(s):

Phase Transitions ◽

Low Temperature ◽

Diffraction Study ◽

X Ray Diffraction ◽

X Ray

Download Full-text

High pressure X-ray diffraction study on p-FeS2, m-FeS2 and MnS2 to 340 kbar: A possible high spin-low spin transition in MnS2

Journal of Physics and Chemistry of Solids ◽

10.1016/0022-3697(85)90204-5 ◽

1985 ◽

Vol 46 (1) ◽

pp. 113-116 ◽

Cited By ~ 37

Author(s):

T. Chattopadhyay ◽

H.G. von Schnering

Keyword(s):

High Pressure ◽

Diffraction Study ◽

High Spin ◽

Spin Transition ◽

X Ray Diffraction ◽

X Ray

Download Full-text

Pressure-induced phase transition in hydrogen-bonded molecular crystal acetamide: combined Raman scattering and X-ray diffraction study

RSC Advances ◽

10.1039/c5ra17223c ◽

2015 ◽

Vol 5 (103) ◽

pp. 84703-84710 ◽

Cited By ~ 5

Author(s):

Lei Kang ◽

Kai Wang ◽

Shourui Li ◽

Xiaodong Li ◽

Bo Zou

Keyword(s):

Phase Transition ◽

Phase Transitions ◽

Raman Scattering ◽

Diffraction Study ◽

Molecular Crystal ◽

Structural Phase ◽

Structural Phase Transitions ◽

X Ray Diffraction ◽

X Ray

Two structural phase transitions are observed at ∼0.9 and ∼3.2 GPa in acetamide using in situ synchrotron X-ray diffraction (XRD) and Raman scattering techniques.

Download Full-text