Possible role of aluminum in stabilizing organic matter in particle size fractions of Chernozemic and solonetizic soils

2002 ◽  
Vol 82 (2) ◽  
pp. 265-268 ◽  
Author(s):  
D. Curtin

Although phyllosilicate clays, with their large surface areas, are often considered to play the leading role in stabilizing soil organic matter against microbial attack, several studies have suggested recently that oxides of Al and Fe may stabilize organic matter in some soils. The distribution of organic C and oxides in clay (< 0.2 and 0.2–2 mm) and silt fractions (2–5, 5–20, and 20–50 mm) of four Saskatchewan soils (organic C ranged from 21 to 46 g kg-1) was examined to differentiate the contributions of oxides and specific surface to organic matter retention. Carbon concentrations in the particle size fractions (separated following ultrasonic dispersion of the soils) tended to be highest in the fine silt and coarse clay fractions, not in the fine clay as would be expected if specific surface was the sole factor governing organic matter content. When data for the four soils were pooled there was a strong relationship between organic C (y) in the size fractions and Al (x) extracted by dithionite-citrate-bicarbonate [y = 33.9 x0,5 - 7.3; R2 = 0.90***], suggesting a role for A1 in determining the C storage capacity of the size fractions. The C: A1 ratio increased from an average of 12:1 in clay-sized material to 28:1 in coarse silt. Because it had less A1 per unit mass of C, organic matter in the silt separates may be more weakly bonded to mineral material than is clay-associated organic matter. This may imply that organic matter bound to silt is less stable, and thus susceptible to mineralization, than is organic matter residing in the clay fraction. Key words: Organic matter stabilization, particle size separates, extractable A1 and Fe


Soil Research ◽  
1986 ◽  
Vol 24 (2) ◽  
pp. 293 ◽  
Author(s):  
RC Dalal ◽  
RJ Mayer

Distribution of soil organic carbon in sand-, silt- and clay-size fractions during cultivation for periods ranging from 20 to 70 years was studied in six major soils used for cereal cropping in southern Queensland. Particle-size fractions were obtained by dispersion in water using cation exchange resin, sieving and sedimentation. In the soils' virgin state no single particle-size fraction was found to be consistently enriched as compared to the whole soil in organic C in all six soils, although the largest proportion (48%) of organic C was in the clay-size fraction; silt and sand-size fractions contained remaining organic C in equal amounts. Upon cultivation, the amounts of organic C declined from all particle-size fractions in most soils, although the loss rates differed considerably among different fractions and from the whole soil. The proportion of the sand-size fraction declined rapidly (from 26% to 12% overall), whereas that of the clay-size fraction increased from 48% to 61% overall. The proportion of silt-size organic C was least affected by cultivation in most soils. It was inferred, therefore, that the sand-size organic matter is rapidly lost from soil, through mineralization as well as disintegration into silt-size and clay-size fractions, and that the clay fraction provides protection for the soil organic matter against microbial and enzymic degradation.



Geoderma ◽  
2016 ◽  
Vol 264 ◽  
pp. 171-178 ◽  
Author(s):  
Oihane Fernández-Ugalde ◽  
Pierre Barré ◽  
Iñigo Virto ◽  
Fabien Hubert ◽  
Daniel Billiou ◽  
...  


2012 ◽  
Vol 63 (4) ◽  
pp. 9-15 ◽  
Author(s):  
Zygmunt Brogowski ◽  
Wojciech Kwasowski

Abstract The distribution of organic matter in the genetic horizons of lateritic soil within a 100-cm profile to the basaltic parent rock is almost except for horizon Ap. Assuming that the sum of organic matter in 100 cm of the soil profile is 100%, 25.7% of these compounds occur in horizon Ap, whereas in the remaining horizons this value varies within 18-19.2%. In all size fractions, except the clay fraction in diameter of <0.002 mm, the content of organic matter decreases to a certain depth, and increases again in the deepest horizon located directly on the solid basaltic rock. The clay fraction displays an opposite trend; the content of organic matter in them increases with depth. In the horizon at the depth of 60-80 cm, the clay fraction <0.002 mm accumulates half of the total sum of organic compounds of all the remaining fractions. Such distribution of organic matter in soil and among its particle size probably results from the character of the basaltic weathered debris, as well as climate and vegetation covering the studied area.



1995 ◽  
Vol 75 (2) ◽  
pp. 161-167 ◽  
Author(s):  
E. G. Gregorich ◽  
C. M. Monreal ◽  
B. H. Ellert

Total organic C and natural C abundance were measured in a forest soil and a soil under corn (Zea mays L.) to assess management-induced changes in the quantity and initial source of organic matter. The total mass of organic C in the cultivated soil was 19% lower than in the forest soil. It was estimated that after 25 yr of continuous corn, 100 Mg C ha−1 was returned to the soil as residues, of which only 23 Mg ha−1 remained in the soil; 88% of the remaining corn-derived C (C4-derived C) was in the plow layer. About 30% of the soil organic C in the plow layer (0–27 cm) was derived from corn. Assuming first order kinetics, the half-life of C3-derived C in the 0- to 15-cm layer was 13 yr. The half-life of C3-derived C in the 0- to 30-cm layer, which included organic C below the plow layer, was 24 yr. Mineralization of the light fraction (LF) was faster than that of organic matter associated with particle-size fractions. More than 70% of the LF had turned over since the start of corn cropping, and 45% of organic matter in the sand fraction comprised corn residue. The half-life of C3-derived C in the LF was 8 yr. The mineralization of C from native organic matter associated with the coarse silt fraction was the slowest of all particle-size fractions. Key words: Soil organic matter, carbon storage, natural 13C abundance, light fraction, particle-size fractions, mineralization



1988 ◽  
Vol 68 (2) ◽  
pp. 395-403 ◽  
Author(s):  
R. G. KACHANOSKI ◽  
R. P. VORONEY ◽  
E. G. GREGORICH

Aggregates (1–2 mm) from a soil under continuous corn management were subjected to a mild shaking treatment and ultrasonic energy levels ranging from 100 to 1500 J mL−1 water to determine the degree of aggregate disruption and dispersion. More clay- and fewer sand-size particles were recovered with greater amounts of applied energy indicating greater aggregate disruption and dispersion with higher energy levels. Most of the breakdown of sand-size aggregates occurred between energy levels of 300 and 500 J mL−1. Ultrasonic energy levels of 500 J mL−1 or greater were more effective than using 20% hydrogen peroxide plus 16 h of shaking in dispersing sand-size microaggregates. Surface area measurements of the clay indicated no severe fragmentation or alteration of primary particles had occurred. With increased applied ultrasonic energy and more complete dispersion, the amount of organic C recovered increased in the clay- and decreased in the sand-size fractions. At complete dispersion, there was no evidence of redistribution of organic matter by ultrasonification and the sand-, silt- and clay-size fractions contained 5, 30 and 60% of the soil organic C. Results of this study suggest that ultrasonic dispersion techniques can be used as a physical method to separate microaggregates from soil and thereby study the nature of organic matter within them. Key words: Ultrasonic dispersion methodology, aggregates, organic matter distribution, particle size fractions



2002 ◽  
Vol 66 (1) ◽  
pp. 129 ◽  
Author(s):  
Benny Chefetz ◽  
Jorge Tarchitzky ◽  
Ashish P. Deshmukh ◽  
Patrick G. Hatcher ◽  
Yona Chen




Revista CERES ◽  
2012 ◽  
Vol 59 (6) ◽  
pp. 867-872 ◽  
Author(s):  
Julião Soares de Souza Lima ◽  
Rone Batista de Oliveira ◽  
Samuel de Assis Silva

Information on the spatial distribution of particle size fractions is essential for use planning and management of soils. The aim of this work to was to study the spatial variability of particle size fractions of a Typic Hapludox cultivated with conilon coffee. The soil samples were collected at depths of 0-0.20 and 0.20-0.40 m in the coffee canopy projection, totaling 109 georeferentiated points. At the depth of 0.2-0.4 m the clay fraction showed average value significantly higher, while the sand fraction showed was higher in the depth of 0-0.20 m. The silt showed no significant difference between the two depths. The particle size fractions showed medium and high spatial variability. The levels of total sand and clay have positive and negative correlation, respectively, with the altitude of the sampling points, indicating the influence of landscape configuration.



Sign in / Sign up

Export Citation Format

Share Document