scholarly journals Unimolecular Dissociation of H<sup>+</sup><sub style="margin-left:-6px;">2n+1</sub> Hydrogen Clusters: Measured Cross Sections and Theoretically Calculated Rate Constants

2013 ◽  
Vol 03 (04) ◽  
pp. 207-215
Author(s):  
Mohamed Tabti ◽  
Adil Eddahbi ◽  
Soufiane Assouli ◽  
Lahcen El Arroum ◽  
Said Ouaskit
Keyword(s):  
Cross Sections ◽  
Rate Constants ◽  
Unimolecular Dissociation ◽  
Hydrogen Clusters ◽  
Calculated Rate

Quantum mechanical integral cross sections and rate constants for the F+HD reactions

2000 ◽  
Vol 112 (22) ◽  
pp. 9802-9809 ◽  
Author(s):  
Dong H. Zhang ◽  
Soo-Y. Lee ◽  
Michael Baer
Keyword(s):  
Cross Sections ◽  
Rate Constants ◽  
Quantum Mechanical

Analytical Formulae for Cross Sections and Rate Constants of Elementary Processes in Gases

1985 ◽  
pp. 697-704
Author(s):  
G. V. Dubrovskiy ◽  
A. V. Bogdanov ◽  
Yu. E. Gorbachev ◽  
L. F. Vyunenko ◽  
V. A. Pavlov ◽  
...  
Keyword(s):  
Cross Sections ◽  
Rate Constants ◽  
Elementary Processes ◽  
Analytical Formulae

scholarly journals A model of tetrahydrofuran low-temperature oxidation based on theoretically calculated rate constants

2018 ◽  
Vol 191 ◽  
pp. 252-269 ◽  
Author(s):  
Yann Fenard ◽  
Adrià Gil ◽  
Guillaume Vanhove ◽  
Hans-Heinrich Carstensen ◽  
Kevin M. Van Geem ◽  
...  
Keyword(s):  
Low Temperature ◽  
Rate Constants ◽  
Low Temperature Oxidation ◽  
Temperature Oxidation ◽  
Calculated Rate

Kinetics of iron(III) hydrolysis and precipitation in aqueous glycine solutions assessed by voltammetry

2009 ◽  
Vol 74 (10) ◽  
pp. 1531-1542 ◽  
Author(s):  
Vlado Cuculić ◽  
Ivanka Pižeta
Keyword(s):  
Ionic Strength ◽  
Complex Formation ◽  
Rate Constants ◽  
Glycine Concentration ◽  
First Order ◽  
Mercury Drop Electrode ◽  
Calculated Rate ◽  
Cathodic Voltammetry ◽  
Kinetics Of ◽  
Voltammetric Measurements

The kinetics of iron(III) hydrolysis and precipitation in aqueous glycine solutions were studied by cathodic voltammetry with a mercury drop electrode. The kinetics was controlled by changing ionic strength (I), pH and glycine concentration. Voltammetric measurements clearly showed formation and dissociation of a soluble Fe(III)–glycine complex, formation of iron(III) hydroxide and its precipitation. The rate constants of iron(III) hydroxide precipitation were assessed. The precipitation is first-order with respect to dissolved inorganic iron(III). The calculated rate constants of iron(III) precipitation varied from 0.18 × 10–5 s–1 (at 0.2 M total glycine, pH 7.30, I = 0.6 mol dm–3) to 2.22 × 10–3 s–1 (at 0.1 M total glycine, pH 7.30, I = 0.2 mol dm–3). At 0.5 M total glycine and I = 0.6 mol dm–3, the iron(III) precipitation was not observed.

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