scholarly journals Dimethylsulfide dynamics in first-year sea ice melt ponds in the Canadian Arctic Archipelago

Author(s):  
Margaux Gourdal ◽  
Martine Lizotte ◽  
Guillaume Massé ◽  
Michel Gosselin ◽  
Michael Scarratt ◽  
...  

Abstract. Melt pond formation is a natural seasonal pan-Arctic process. During the thawing season, melt ponds may cover up to 90 % of the Arctic first year sea ice (FYI) and 15 to 25 % of the multi-year sea ice (MYI). These pools of water lying at the surface of the sea-ice cover are habitats for microorganisms and represent a potential source of the biogenic gas dimethylsulfide (DMS) for the atmosphere. Here we report on the concentrations and dynamics of DMS in nine melt ponds sampled in July 2014 in the Eastern Canadian Arctic. DMS concentrations were under the detection limit (

2018 ◽  
Vol 15 (10) ◽  
pp. 3169-3188 ◽  
Author(s):  
Margaux Gourdal ◽  
Martine Lizotte ◽  
Guillaume Massé ◽  
Michel Gosselin ◽  
Michel Poulin ◽  
...  

Abstract. Melt pond formation is a seasonal pan-Arctic process. During the thawing season, melt ponds may cover up to 90 % of the Arctic first-year sea ice (FYI) and 15 to 25 % of the multi-year sea ice (MYI). These pools of water lying at the surface of the sea ice cover are habitats for microorganisms and represent a potential source of the biogenic gas dimethyl sulfide (DMS) for the atmosphere. Here we report on the concentrations and dynamics of DMS in nine melt ponds sampled in July 2014 in the Canadian Arctic Archipelago. DMS concentrations were under the detection limit (< 0.01 nmol L−1) in freshwater melt ponds and increased linearly with salinity (rs = 0.84, p ≤ 0.05) from ∼ 3 up to ∼ 6 nmol L−1 (avg. 3.7 ± 1.6 nmol L−1) in brackish melt ponds. This relationship suggests that the intrusion of seawater in melt ponds is a key physical mechanism responsible for the presence of DMS. Experiments were conducted with water from three melt ponds incubated for 24 h with and without the addition of two stable isotope-labelled precursors of DMS (dimethylsulfoniopropionate), (D6-DMSP) and dimethylsulfoxide (13C-DMSO). Results show that de novo biological production of DMS can take place within brackish melt ponds through bacterial DMSP uptake and cleavage. Our data suggest that FYI melt ponds could represent a reservoir of DMS available for potential flux to the atmosphere. The importance of this ice-related source of DMS for the Arctic atmosphere is expected to increase as a response to the thinning of sea ice and the areal and temporal expansion of melt ponds on Arctic FYI.


2020 ◽  
Vol 61 (82) ◽  
pp. 154-163
Author(s):  
Qing Li ◽  
Chunxia Zhou ◽  
Lei Zheng ◽  
Tingting Liu ◽  
Xiaotong Yang

AbstractThe evolution of melt ponds on Arctic sea ice in summer is one of the main factors that affect sea-ice albedo and hence the polar climate system. Due to the different spectral properties of open water, melt pond and sea ice, the melt pond fraction (MPF) can be retrieved using a fully constrained least-squares algorithm, which shows a high accuracy with root mean square error ~0.06 based on the validation experiment using WorldView-2 image. In this study, the evolution of ponds on first-year and multiyear ice in the Canadian Arctic Archipelago was compared based on Sentinel-2 and Landsat 8 images. The relationships of pond coverage with air temperature and albedo were analysed. The results show that the pond coverage on first-year ice changed dramatically with seasonal maximum of 54%, whereas that on multiyear ice changed relatively flat with only 30% during the entire melting period. During the stage of pond formation, the ponds expanded rapidly when the temperature increased to over 0°C for three consecutive days. Sea-ice albedo shows a significantly negative correlation (R = −1) with the MPF in melt season and increases gradually with the refreezing of ponds and sea ice.


2014 ◽  
Vol 11 (5) ◽  
pp. 7485-7519 ◽  
Author(s):  
N.-X. Geilfus ◽  
R. J. Galley ◽  
O. Crabeck ◽  
T. Papakyriakou ◽  
J. Landy ◽  
...  

Abstract. Melt pond formation is a common feature of the spring and summer Arctic sea ice. However, the role of the melt ponds formation and the impact of the sea ice melt on both the direction and size of CO2 flux between air and sea is still unknown. Here we describe the CO2-carbonate chemistry of melting sea ice, melt ponds and the underlying seawater associated with measurement of CO2 fluxes across first year landfast sea ice in the Resolute Passage, Nunavut, in June 2012. Early in the melt season, the increase of the ice temperature and the subsequent decrease of the bulk ice salinity promote a strong decrease of the total alkalinity (TA), total dissolved inorganic carbon (TCO2) and partial pressure of CO2 (pCO2) within the bulk sea ice and the brine. Later on, melt pond formation affects both the bulk sea ice and the brine system. As melt ponds are formed from melted snow the in situ melt pond pCO2 is low (36 μatm). The percolation of this low pCO2 melt water into the sea ice matrix dilutes the brine resulting in a strong decrease of the in situ brine pCO2 (to 20 μatm). As melt ponds reach equilibrium with the atmosphere, their in situ pCO2 increase (up to 380 μatm) and the percolation of this high concentration pCO2 melt water increase the in situ brine pCO2 within the sea ice matrix. The low in situ pCO2 observed in brine and melt ponds results in CO2 fluxes of −0.04 to −5.4 mmol m–2 d–1. As melt ponds reach equilibrium with the atmosphere, the uptake becomes less significant. However, since melt ponds are continuously supplied by melt water their in situ pCO2 still remains low, promoting a continuous but moderate uptake of CO2 (~ −1mmol m–2 d–1). The potential uptake of atmospheric CO2 by melting sea ice during the Arctic summer has been estimated from 7 to 16 Tg of C ignoring the role of melt ponds. This additional uptake of CO2 associated to Arctic sea ice needs to be further explored and considered in the estimation of the Arctic Ocean's overall CO2 budget.


2015 ◽  
Vol 12 (6) ◽  
pp. 2047-2061 ◽  
Author(s):  
N.-X. Geilfus ◽  
R. J. Galley ◽  
O. Crabeck ◽  
T. Papakyriakou ◽  
J. Landy ◽  
...  

Abstract. Melt pond formation is a common feature of spring and summer Arctic sea ice, but the role and impact of sea ice melt and pond formation on both the direction and size of CO2 fluxes between air and sea is still unknown. Here we report on the CO2–carbonate chemistry of melting sea ice, melt ponds and the underlying seawater as well as CO2 fluxes at the surface of first-year landfast sea ice in the Resolute Passage, Nunavut, in June 2012. Early in the melt season, the increase in ice temperature and the subsequent decrease in bulk ice salinity promote a strong decrease of the total alkalinity (TA), total dissolved inorganic carbon (TCO2) and partial pressure of CO2 (pCO2) within the bulk sea ice and the brine. As sea ice melt progresses, melt ponds form, mainly from melted snow, leading to a low in situ melt pond pCO2 (36 μatm). The percolation of this low salinity and low pCO2 meltwater into the sea ice matrix decreased the brine salinity, TA and TCO2, and lowered the in situ brine pCO2 (to 20 μatm). This initial low in situ pCO2 observed in brine and melt ponds results in air–ice CO2 fluxes ranging between −0.04 and −5.4 mmol m−2 day−1 (negative sign for fluxes from the atmosphere into the ocean). As melt ponds strive to reach pCO2 equilibrium with the atmosphere, their in situ pCO2 increases (up to 380 μatm) with time and the percolation of this relatively high concentration pCO2 meltwater increases the in situ brine pCO2 within the sea ice matrix as the melt season progresses. As the melt pond pCO2 increases, the uptake of atmospheric CO2 becomes less significant. However, since melt ponds are continuously supplied by meltwater, their in situ pCO2 remains undersaturated with respect to the atmosphere, promoting a continuous but moderate uptake of CO2 (~ −1 mmol m−2 day−1) into the ocean. Considering the Arctic seasonal sea ice extent during the melt period (90 days), we estimate an uptake of atmospheric CO2 of −10.4 Tg of C yr−1. This represents an additional uptake of CO2 associated with Arctic sea ice that needs to be further explored and considered in the estimation of the Arctic Ocean's overall CO2 budget.


2015 ◽  
Vol 9 (1) ◽  
pp. 255-268 ◽  
Author(s):  
D. V. Divine ◽  
M. A. Granskog ◽  
S. R. Hudson ◽  
C. A. Pedersen ◽  
T. I. Karlsen ◽  
...  

Abstract. The paper presents a case study of the regional (≈150 km) morphological and optical properties of a relatively thin, 70–90 cm modal thickness, first-year Arctic sea ice pack in an advanced stage of melt. The study combines in situ broadband albedo measurements representative of the four main surface types (bare ice, dark melt ponds, bright melt ponds and open water) and images acquired by a helicopter-borne camera system during ice-survey flights. The data were collected during the 8-day ICE12 drift experiment carried out by the Norwegian Polar Institute in the Arctic, north of Svalbard at 82.3° N, from 26 July to 3 August 2012. A set of > 10 000 classified images covering about 28 km2 revealed a homogeneous melt across the study area with melt-pond coverage of ≈ 0.29 and open-water fraction of ≈ 0.11. A decrease in pond fractions observed in the 30 km marginal ice zone (MIZ) occurred in parallel with an increase in open-water coverage. The moving block bootstrap technique applied to sequences of classified sea-ice images and albedo of the four surface types yielded a regional albedo estimate of 0.37 (0.35; 0.40) and regional sea-ice albedo of 0.44 (0.42; 0.46). Random sampling from the set of classified images allowed assessment of the aggregate scale of at least 0.7 km2 for the study area. For the current setup configuration it implies a minimum set of 300 images to process in order to gain adequate statistics on the state of the ice cover. Variance analysis also emphasized the importance of longer series of in situ albedo measurements conducted for each surface type when performing regional upscaling. The uncertainty in the mean estimates of surface type albedo from in situ measurements contributed up to 95% of the variance of the estimated regional albedo, with the remaining variance resulting from the spatial inhomogeneity of sea-ice cover.


2013 ◽  
Vol 7 (2) ◽  
pp. 1313-1358 ◽  
Author(s):  
S. E. L. Howell ◽  
T. Wohlleben ◽  
A. Komarov ◽  
L. Pizzolato ◽  
C. Derksen

Abstract. Record low mean September sea ice area in the Canadian Arctic Archipelago (CAA) was observed in 2011 (146 × 103 km2), a level that was nearly exceeded in 2012 (150 × 103 km2). These values eclipsed previous September records set in 1998 (200 × 103 km2) and 2007 (220 × 103 km2) and are ∼60% lower than the 1981–2010 mean September climatology. In this study, the driving processes contributing to the extreme light years of 2011 and 2012 were investigated, compared to previous extreme minima of 1998 and 2007, and contrasted against historic summer seasons with above average September ice area. The 2011 minimum was driven by positive July surface air temperature (SAT) anomalies that facilitated rapid melt, coupled with atmospheric circulation in July and August that restricted multi-year ice (MYI) inflow from the Arctic Ocean into the CAA. The 2012 minimum was also driven by positive July SAT anomalies (with coincident rapid melt) but further ice decline was temporarily mitigated by atmospheric circulation in August and September which drove Arctic Ocean MYI inflow into the CAA. Atmospheric circulation was comparable between 2011 and 1998 (impeding Arctic Ocean MYI inflow) and 2012 and 2007 (inducing Arctic Ocean MYI inflow). However, evidence of both preconditioned thinner Arctic Ocean MYI flowing into CAA and maximum landfast first-year ice (FYI) thickness within the CAA was more apparent leading up to 2011 and 2012 than 1998 and 2007. The rapid melt process in 2011 and 2012 was more intense than observed in 1998 and 2007 because of the thinner ice cover being more susceptible to positive SAT forcing. The thinner sea ice cover within the CAA in recent years has also helped counteract the processes that facilitate extreme heavy ice years. The recent extreme light years within the CAA are associated with a longer navigation season within the Northwest Passage.


2014 ◽  
Vol 119 (5) ◽  
pp. 3054-3075 ◽  
Author(s):  
Jack Landy ◽  
Jens Ehn ◽  
Megan Shields ◽  
David Barber

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