scholarly journals Fluorescence spectroscopy as a tool for determination of organic matter removal efficiency at water treatment works

2010 ◽  
Vol 3 (1) ◽  
pp. 63-70 ◽  
Author(s):  
M. Z. Bieroza ◽  
J. Bridgeman ◽  
A. Baker
Keyword(s):  
Drinking Water ◽  
Organic Matter ◽  
Water Treatment ◽  
Fluorescence Spectroscopy ◽  
Removal Efficiency ◽  
Distribution System ◽  
Drinking Water Treatment ◽  
Analytical Techniques ◽  
Fluorescence Excitation

Abstract. Organic matter (OM) in drinking water treatment is a common impediment responsible for increased coagulant and disinfectant dosages, formation of carcinogenic disinfection-by products, and microbial re-growth in distribution system. The inherent heterogeneity of OM implies the utilization of advanced analytical techniques for its characterization and assessment of removal efficiency. Here, the application of simple fluorescence excitation-emission technique to OM characterization in drinking water treatment is presented. The fluorescence data of raw and clarified water was obtained from 16 drinking water treatment works. The reduction in fulvic-like fluorescence was found to significantly correlate with OM removal measured with total organic carbon (TOC). Fluorescence properties, fulvic- and tryptophan-like regions, were found to discriminate OM fractions of different removal efficiencies. The results obtained in the study show that fluorescence spectroscopy provides a rapid and accurate characterization and quantification of OM fractions and indication of their treatability in conventional water treatment.

scholarly journals Fluorescence spectroscopy as a tool for determination of organic matter removal efficiency at water treatment works

2009 ◽  
Vol 2 (2) ◽  
pp. 259-278 ◽  
Author(s):  
M. Z. Bieroza ◽  
J. Bridgeman ◽  
A. Baker
Keyword(s):  
Drinking Water ◽  
Organic Matter ◽  
Water Treatment ◽  
Fluorescence Spectroscopy ◽  
Removal Efficiency ◽  
Distribution System ◽  
Drinking Water Treatment ◽  
Analytical Techniques ◽  
Fluorescence Excitation

Abstract. Organic matter (OM) in drinking water treatment is a common impediment responsible for increased coagulant and disinfectant dosages, formation of carcinogenic disinfection-by products, and microbial re-growth in distribution system. The inherent heterogeneity of OM implies the utilization of advanced analytical techniques for its characterization and assessment of removal efficiency. Here, the application of simple fluorescence excitation-emission technique to OM characterization in drinking water treatment is presented. The fluorescence data of raw and clarified water was obtained from 16 drinking water treatment works. The reduction in fulvic-like fluorescence was found to significantly correlate with OM removal measured with total organic carbon (TOC). Fluorescence properties, fulvic- and tryptophan-like regions, were found to discriminate OM fractions of different removal efficiencies. The results obtained in the study show that fluorescence spectroscopy provides a rapid and accurate characterization and quantification of OM fractions and indication of their treatability in conventional water treatment.

Characterization of NOM in a drinking water treatment process train with no disinfectant residual

2009 ◽  
Vol 9 (4) ◽  
pp. 379-386 ◽  
Author(s):  
S. A. Baghoth ◽  
M. Dignum ◽  
A. Grefte ◽  
J. Kroesbergen ◽  
G. L. Amy
Keyword(s):  
Drinking Water ◽  
Water Treatment ◽  
Organic Carbon ◽  
Distribution System ◽  
Chemical Properties ◽  
Drinking Water Treatment ◽  
Building Blocks ◽  
Fluorescence Excitation ◽  
Water Treatment Process ◽  
Water Treatment Plants

For drinking water treatment plants that do not use disinfectant residual in the distribution system, it is important to limit availability of easily biodegradable natural organic matter (NOM) fractions which could enhance bacterial regrowth in the distribution system. This can be achieved by optimising the removal of those fractions of interest during treatment; however, this requires a better understanding of the physical and chemical properties of these NOM components. Fluorescence excitation-emission matrix (EEM) and liquid chromatography with online organic carbon detection (LC-OCD) were used to characterize NOM in water samples from one of the two water treatment plants serving Amsterdam, The Netherlands. No disinfectant residual is applied in the distribution system. Fluorescence EEM and LC-OCD were used to track NOM fractions. Whereas fluorescence EEM shows the reduction of humic-like as well as protein-like fluorescence signatures, LC-OCD was able to quantify the changes in dissolved organic carbon (DOC) concentrations of five NOM fractions: humic substances, building blocks (hydrolysates of humics), biopolymers, low molecular weight acids and neutrals.

scholarly journals On-line monitoring of organic matter concentrations and character in drinking water treatment systems using fluorescence spectroscopy

2016 ◽  
Vol 2 (4) ◽  
pp. 749-760 ◽  
Author(s):  
Y. Shutova ◽  
A. Baker ◽  
J. Bridgeman ◽  
R. K. Henderson
Keyword(s):  
Drinking Water ◽  
Organic Matter ◽  
Water Treatment ◽  
Fluorescence Spectroscopy ◽  
Drinking Water Treatment ◽  
Robust Method ◽  
On Line

There is a need for a rapid and robust method of organic matter (OM) monitoring during drinking water treatment.

scholarly journals Fouling analysis of polysulfone ultrafiltration membranes used for drinking water treatment

2011 ◽  
Vol 11 (6) ◽  
pp. 668-674 ◽  
Author(s):  
B. Q. Zhao ◽  
C. P. Huang ◽  
S. Y. Chen ◽  
D. S. Wang ◽  
T. Li ◽  
...  
Keyword(s):  
Drinking Water ◽  
Organic Matter ◽  
Water Treatment ◽  
Fulvic Acid ◽  
Humic Substances ◽  
Natural Organic Matter ◽  
Drinking Water Treatment ◽  
Ultrafiltration Membranes ◽  
Fluorescence Excitation ◽  
Hydrophobic Fraction

Natural organic matter (NOM) plays a significant role in the fouling of ultrafiltration membranes in drinking water treatment processes. For a better understanding of the interaction between fractional components of NOM and polysulfone (PS) ultrafiltration membranes used for drinking water treatment, fouling and especially the physically irreversible fouling of natural organic matter were investigated. Resin fractionation, fluorescence excitation–emission matrix (EEM) spectroscopy, fourier transform infrared spectroscopy (FTIR), contact angle and a scanning electron microscope (SEM) were employed to identify the potential foulants. The results showed that humic acid and fulvic acid of small size were likely to permeate the membrane, while the hydrophobic fraction of humic and fulvic acid and aromatic proteins tended to be rejected and retained. Organic compounds such as proteins, humic substances, and polysaccharide-like materials, were all detected in the fouling layer. The physically irreversible fouling of the PS membrane seemed to be mainly attributed to the hydrophobic fraction of humic substances.

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